File name: Pandora103s1_Downsview_20190405_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T032634.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190405_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190405 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190405T105846.0Z 7034.457477 390 1 32.01 2 89.75 81.84 95.62 82.88 0.00 1 0.00 1 0 22 1.577e-01 1.378e-01 1.409e-01 1.332e-01 4.451341e+02 7.217543e+03 2.845048e+02 -6.000000e+00 7.971282e+03 276.23 -2.00 20.00 -2.00 505.19 0.00e+00 2.602233e-03 3.535041e-03 4.409153e-05 -6.000000e+00 4.282791e-03 276.23 -2.00 20.00 -2.00 499.82 0.00e+00 3.362191e+00 2.686067e+00 8.592610e-02 -6.000000e+00 3.106109e+00 227.36 -2.00 3.57 -2.00 501.48 0.00e+00 20.288 0.163 489.00 513.00 1 1.0245e+01 2.0283e-01 3.6936e-02 -6.0000e+00 2.3532e-01 1.2622e-01 5.4887e-02 2.3104e-03 -6.0000e+00 6.4816e-02 3.0067e-06 1.0121e-02 1.0313e-02 1.9984e-05 -6.0000e+00 1.2318e-02 1.2906e-01 -2.0075e-03 12 8 8 10 0 0 10.60 15.00 13.13 0.12906 0.19926 8 1 1 4 0 4000.000 21.69 15.00 18.54 900000 900000 16668 2616 6592 -10743 -3271 5750 631 -23831 -15187 -11573 -15619 -9498 -2864 8314 -50 27646 13500 -3145 13878 7334 -4172 3128 6854 -15793 11477 18194 9022 11387 11454 26851 13604 -2204 15384 13305 -12474 20019 12759 4433 -8307 11826 -14680 18045 -9170 10935 -24463 -3993 -9045 374 25193 11630 989 6655 -15196 -8489 18835 -766 -5748 5544 -7600 3709 46195 -9197 -3695 -2284 16149 -21620 14344 9686 5145 24602 -5489 -341 -47 4856 50279 24722 9200 8952 -1599 -6074 4976 44682 13928 4275 -13986 22454 11263 2402 -6297 -13365 15058 2004 17638 -10033 -2394 31117 -6816 2149 -6617 13160 2869 -9404 6225 -19668 22873 -4443 -11841 11030 1104 16414 -9518 -2201 3229 4286 -5824 5147 -14645 -7272 4824 20971 -25696 61483 -11963 9838 -1362 1314 12250 11545 10688 11316 19742 1151 -3242 3003 2135 -5677 -9247 -1798 -16366 11472 895 -21824 52668 3974 16257 18884 4539 -27968 900000 900000 14093 2629 6637 -13096 -3781 6222 725 -34619 -19970 -14413 -19984 -11262 -3133 8094 -52 22625 12994 -3673 13916 7810 -4957 3459 7332 -21228 11868 17553 9454 11376 10914 21476 12389 -2377 14609 13416 -16227 18717 12612 4680 -9808 11482 -18573 16823 -11264 11187 -35393 -4706 -11032 410 21185 10760 983 6149 -17349 -9375 16596 -836 -6637 5709 -8806 3841 31994 -10892 -4144 -2504 14553 -27441 12666 8852 4824 18819 -5605 -334 -47 4659 30998 18949 7988 7700 -1513 -6006 4466 27486 11521 3923 -15426 17419 9681 2238 -6381 -14544 12626 1948 14893 -10949 -2386 22073 -6781 1903 -6204 10053 2438 -9250 5507 -22962 17629 -4368 -12220 8988 996 13046 -9905 -2173 3063 4047 -6080 4864 -16802 -7699 4459 16312 -30825 31689 -12611 8497 -1309 1231 10308 9735 9140 9608 15136 1032 -2989 2582 1872 -5526 -9527 -1745 -18475 9948 859 -26200 31141 3765 13636 15150 4041 -33043 SO 20190405T110308.0Z 7034.460509 394 1 32.01 2 88.97 82.60 94.86 83.61 0.00 1 0.00 1 0 29 6.703e-02 6.551e-02 6.731e-02 6.577e-02 -2.177114e+03 3.594095e+03 9.609328e+01 -6.000000e+00 3.389147e+03 276.23 -2.00 20.00 -2.00 505.16 0.00e+00 5.721854e-03 1.750835e-03 3.572595e-04 -6.000000e+00 1.808072e-03 276.23 -2.00 20.00 -2.00 499.77 0.00e+00 2.591022e+00 1.340142e+00 8.445700e-02 -6.000000e+00 1.297235e+00 227.37 -2.00 3.57 -2.00 501.44 0.00e+00 18.705 0.127 489.00 513.00 1 9.7710e+00 1.0255e-01 3.3359e-02 -6.0000e+00 9.8788e-02 1.5769e-01 2.7228e-02 2.0680e-03 -6.0000e+00 2.6367e-02 6.2726e-06 -4.5073e-03 5.0025e-03 8.7699e-05 -6.0000e+00 5.2277e-03 6.5200e-03 -1.6402e-05 12 8 8 10 0 0 -1.82 15.00 4.06 0.00652 -0.02474 8 1 1 4 0 4000.000 21.79 15.00 18.55 2126 -6551 -2791 7067 1345 -2401 6049 2863 1083 4515 2598 -2049 7688 -2143 -3102 -7280 2769 -13036 11451 -3888 4574 -6174 11452 -2042 -10541 2309 5448 -1615 -1023 5214 -5560 1492 -2226 4630 -3089 15907 -10065 3934 240 2152 -7113 8670 -42 1414 4480 5159 5085 875 946 -7324 -2532 1356 -7808 -989 13310 -8954 9231 -4444 7747 -13513 11122 -4131 5591 -2095 1084 994 3728 -412 903 845 -10292 4899 -6853 16117 9306 9598 -5471 7844 -8560 8457 -2120 2568 -8620 6435 -9073 -4487 -1811 4718 -5466 -2871 -96 5516 1162 -1812 4889 1941 743 -1197 16168 -1701 3855 -10567 12300 -13076 9961 -4570 6522 6583 16466 10647 5894 1701 -9329 -3527 5092 -2519 -307 -3443 -2885 4318 -13388 8028 -9583 -3764 5975 -1142 -9243 4601 -1301 11548 -3602 5787 -7015 2081 10203 -2502 3467 3687 1802 4048 4611 -833 -9736 -766 817 -598 5262 2887 -7793 8388 2069 -6956 -2938 7057 1468 -2766 6551 3248 1253 4993 2859 -2319 7797 -2344 -3377 -8209 2843 -15874 11329 -4567 4939 -7371 11502 -2338 -13218 2576 5880 -1858 -1154 5310 -6024 1494 -2336 4688 -3531 15438 -12446 4172 260 2260 -8145 8575 -46 1542 4814 5555 5475 970 1031 -8483 -2712 1352 -8312 -979 11691 -10157 9055 -5053 7826 -16652 10722 -4637 5748 -2320 1157 1046 3737 -422 902 831 -11048 4506 -7103 13513 8467 8725 -5632 6897 -8694 7234 -2004 2335 -8782 5650 -9312 -4439 -1745 4242 -5392 -2759 -90 4943 1112 -1822 4614 1866 715 -1151 12726 -1542 3230 -10147 9615 -13535 8489 -4463 5592 5509 12291 8418 4983 1535 -9585 -3495 4692 -2510 -300 -3475 -2867 3921 -14182 6812 -9552 -3577 5234 -1072 -9386 4079 -1214 9554 -3460 4985 -6674 1778 7930 -2202 2953 3211 1618 3586 4076 -773 -9862 -716 756 -560 4572 2478 -7156 6486 SO 20190405T110718.0Z 7034.463403 398 1 32.01 2 88.22 83.31 94.12 84.30 0.00 1 0.00 1 0 22 3.728e-02 3.629e-02 3.921e-02 3.863e-02 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