File name: Pandora103s1_Downsview_20190418_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T032752.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190418_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190418 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190418T103636.0Z 7047.442083 183 1 32.01 2 89.75 75.20 92.36 269.87 0.00 1 0.00 1 0 15 3.708e-02 3.653e-02 4.182e-02 4.139e-02 1.009773e+04 2.718867e+03 6.046900e+02 -6.000000e+00 1.886332e+03 277.71 -2.00 20.00 -2.00 505.24 0.00e+00 4.375789e-03 1.095961e-03 2.240698e-04 -6.000000e+00 1.004018e-03 277.71 -2.00 20.00 -2.00 500.08 0.00e+00 3.247535e-01 8.191247e-01 9.018690e-02 -6.000000e+00 7.185314e-01 228.41 -2.00 3.57 -2.00 501.71 0.00e+00 20.253 0.162 489.00 513.00 1 9.2302e+00 6.2445e-02 3.7473e-02 -6.0000e+00 5.4731e-02 1.5368e-01 1.6360e-02 2.7268e-03 -6.0000e+00 1.4621e-02 1.0216e-05 2.6409e-03 3.0693e-03 8.5469e-05 -6.0000e+00 2.8919e-03 2.1740e-02 -1.7780e-04 12 8 8 10 0 0 0.56 15.00 4.11 0.02174 0.04006 8 1 1 4 0 4000.000 21.79 15.00 18.57 -4115 -4991 -705 -804 -6075 5613 -2133 -1243 433 -100 1233 -4013 774 2557 4084 499 6251 432 -759 -2046 -3843 762 -1854 -511 2838 989 -340 -1262 -556 4069 782 2499 -3500 2657 -67 -554 -977 3092 4582 2820 -6364 6574 -7722 4011 -47 7566 848 384 2025 1632 -4342 921 -2029 -3542 -3169 2944 4857 -2071 586 -5144 8140 3514 7621 6002 -4106 3127 -4041 -103 -5010 -2399 395 1134 -873 -1028 863 1884 -63 1873 -2326 5126 -4905 763 -5409 7507 -7278 -1048 -999 -458 765 3147 -4997 583 2577 4134 -1039 333 3275 1427 -2299 -5858 -2538 -4661 7094 1838 3329 1386 6698 -6300 111 -2190 -984 1292 1537 505 -2562 9384 113 -4980 -3175 10015 2628 4382 1147 190 -4321 311 39 -4565 2710 1335 -348 3004 4571 -6833 -874 -349 7503 -938 1920 -1425 7018 -2038 -575 -4414 -1400 -4449 -3012 626 1909 -4223 -4034 -5000 -701 -836 -6828 5731 -2398 -1403 480 -109 1307 -4414 799 2549 3968 501 5992 449 -824 -2283 -4343 823 -2050 -559 3034 1081 -374 -1397 -598 3995 768 2413 -3642 2713 -74 -614 -1073 3215 4633 2870 -7088 6516 -8919 4195 -52 7798 930 417 2132 1687 -4598 898 -2002 -3557 -3267 2978 4957 -2283 628 -5792 8036 3657 7672 6133 -4595 3207 -4350 -105 -5310 -2439 385 1096 -869 -1040 871 1871 -62 1767 -2260 4599 -4844 719 -5434 6676 -7574 -1037 -985 -446 728 2912 -5024 564 2501 3967 -1024 314 2898 1245 -2031 -5226 -2162 -4098 5770 1665 3097 1324 5998 -6276 102 -2083 -945 1236 1481 494 -2584 8441 113 -5296 -3312 9018 2484 3969 1057 178 -4288 295 37 -4544 2496 1252 -330 2686 3942 -6525 -784 -316 6481 -893 1795 -1394 6366 -2024 -565 -4513 -1388 -4511 -2951 574 1684 -3935 SO 20190418T104052.0Z 7047.445046 187 1 32.01 2 89.00 75.93 93.12 270.57 0.00 1 0.00 1 0 15 2.333e-02 2.311e-02 2.362e-02 2.350e-02 6.993105e+03 1.468698e+03 5.442128e+02 -6.000000e+00 1.186897e+03 277.71 -2.00 20.00 -2.00 505.33 0.00e+00 3.116708e-03 6.233878e-04 1.520134e-04 -6.000000e+00 6.316756e-04 277.71 -2.00 20.00 -2.00 500.38 0.00e+00 1.627435e+00 4.582919e-01 4.389645e-02 -6.000000e+00 4.518466e-01 228.41 -2.00 3.57 -2.00 501.99 0.00e+00 18.767 0.129 489.00 513.00 1 8.7806e+00 3.4904e-02 3.2364e-02 -6.0000e+00 3.4422e-02 8.0205e-02 9.1283e-03 2.0588e-03 -6.0000e+00 9.1872e-03 1.8336e-05 2.4399e-04 1.7558e-03 7.3313e-05 -6.0000e+00 1.8199e-03 8.2858e-03 -3.6195e-05 12 8 8 10 0 0 3.74 15.00 2.34 0.00829 0.00998 8 1 1 4 0 4000.000 21.79 15.00 18.58 -1799 -4749 -3650 -1445 -35 -4889 5516 -658 857 106 -2 -1264 574 553 -991 3440 -3688 -123 -71 -1460 -1528 863 955 101 -625 1251 3184 782 -1352 1233 -1938 -1536 -1183 3151 718 202 982 -1763 4744 -1762 -1758 1286 2202 182 2642 1415 564 -1112 447 -1161 1951 -419 -2814 -389 -3046 1150 -896 3286 -1813 -168 2077 2913 2183 4110 -217 1004 -2052 -1147 627 -1164 -981 1638 -3980 -1275 1852 5012 -1487 -3463 -264 -783 -882 -1027 4016 -814 4356 1252 1198 -1852 4455 1039 -3608 2444 5264 -2741 1621 -441 3435 4275 -4076 -2017 -1004 1135 -2110 2365 144 1867 -536 1199 -1109 -1251 -1214 -35 3998 -62 -78 586 4158 -4245 3638 -2537 -31 -3309 -3451 -7431 -1582 1036 4848 -1376 823 774 1552 -350 1816 -242 -655 -563 770 -1290 -1861 1448 -2468 1502 -947 1496 1431 640 -2007 761 -3861 -161 -1641 -4513 -3548 -1437 -36 -5271 5500 -707 909 112 -2 -1306 575 543 -979 3253 -3774 -125 -74 -1577 -1648 909 1005 107 -675 1334 3321 832 -1441 1226 -1922 -1517 -1182 3142 766 219 1046 -1899 4735 -1852 -1847 1322 2274 194 2795 1524 611 -1209 471 -1217 1920 -408 -2758 -373 -3080 1163 -951 3387 -1961 -178 2142 3002 2281 4214 -230 1038 -2139 -1166 621 -1155 -956 1556 -4030 -1277 1830 4788 -1477 -3416 -250 -739 -833 -980 3669 -782 4033 1207 1156 -1830 4111 989 -3602 2335 5004 -2837 1581 -426 3113 3730 -3760 -1780 -865 967 -1921 2175 141 1807 -525 1131 -1053 -1197 -1187 -34 3833 -62 -79 588 4080 -4576 3625 -2638 -31 -3322 -3426 -7743 -1577 1008 4555 -1371 799 756 1502 -337 1676 -226 -611 -532 739 -1289 -1891 1444 -2575 1512 -981 1522 1460 654 -2068 740 -3824 -153 SO 20190418T104505.0Z 7047.447975 191 1 32.01 2 88.26 76.66 93.86 271.26 0.00 1 0.00 1 0 22 1.822e-02 1.810e-02 1.203e-02 1.197e-02 1.015994e+04 7.615510e+02 6.135766e+02 -6.000000e+00 9.267444e+02 277.71 -2.00 20.00 -2.00 505.45 0.00e+00 3.681282e-03 3.190467e-04 1.851439e-04 -6.000000e+00 4.932026e-04 277.71 -2.00 20.00 -2.00 500.88 0.00e+00 1.872985e+00 2.271671e-01 9.650069e-02 -6.000000e+00 3.528837e-01 228.41 -2.00 3.57 -2.00 502.42 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