File name: Pandora103s1_Downsview_20190422_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T032703.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190422_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190422T103008.0Z 7051.437593 167 1 32.01 2 89.76 73.26 72.93 218.78 0.00 1 0.00 1 0 50 2.016e-01 1.767e-01 1.758e-01 1.630e-01 1.041116e+04 1.117889e+04 9.154329e+02 -6.000000e+00 1.027245e+04 278.17 -2.00 20.00 -2.00 505.35 0.00e+00 -1.638869e-03 4.403054e-03 5.703714e-05 -6.000000e+00 5.471675e-03 278.17 -2.00 20.00 -2.00 500.10 0.00e+00 2.637864e+00 3.257966e+00 6.609677e-02 -6.000000e+00 3.931483e+00 228.78 -2.00 3.57 -2.00 501.78 0.00e+00 20.253 0.162 489.00 513.00 1 1.0529e+01 2.5062e-01 3.6632e-02 -6.0000e+00 2.9900e-01 7.9451e-02 6.2580e-02 2.0031e-03 -6.0000e+00 8.0739e-02 2.4475e-06 3.0773e-02 1.1549e-02 5.0084e-05 -6.0000e+00 1.5757e-02 7.6774e-02 -8.1728e-04 12 8 8 10 0 0 8.57 15.00 12.38 0.07677 0.29023 8 1 1 4 0 4000.000 21.69 15.00 18.41 900000 -4885 19921 -5374 13457 -16463 -2953 -15276 4354 9135 23298 -2298 3551 -21036 -18763 19271 21185 -10450 -5445 7479 -17540 32027 -3097 28544 -4327 17770 2969 12062 -31353 12462 -1205 12273 7489 9849 23814 5709 -18809 -1158 5589 1343 20452 -2996 -7947 20216 12031 -9474 29172 17174 7658 -13497 47664 9172 49116 -7437 38692 4265 25386 -10784 -18693 14322 -11795 -3330 -3142 5698 -3157 -3278 8356 9116 -23791 7569 -21490 29289 -4183 31610 -2052 921 9348 -15561 34121 25538 31728 -9022 -1066 31478 48772 7379 8150 -24682 41561 -16130 20806 -26691 17126 -16632 32246 -6968 13251 9971 26638 -2328 20468 -38101 23666 38606 47147 14697 2593 14330 17127 2297 -5936 17169 7024 20268 -21796 62026 -28678 5527 -17960 -2122 3656 16421 37120 14156 1090 -13400 5478 12881 30541 10465 8264 -2402 10268 -14872 18730 -20090 6502 -19948 49713 9799 -16057 -5566 -12272 138 34616 -4182 19026 -4357 -11058 5787 900000 -5088 17017 -5983 12760 -21266 -3391 -19735 4588 9056 19974 -2479 3571 -26632 -23352 16939 18864 -13033 -6538 7924 -23654 26851 -3646 24978 -5175 17112 3272 11846 -44736 11458 -1271 11636 7791 10369 21906 6155 -25325 -1295 5793 1449 18488 -3417 -9624 18854 12141 -11640 24381 15817 7518 -15651 29923 8180 30219 -8140 28212 4416 21557 -12868 -23891 13321 -14193 -3707 -3485 5740 -3396 -3462 7792 8351 -29380 6842 -25787 21896 -4387 23833 -2106 894 8186 -17120 23238 18926 22396 -9453 -1045 23020 30544 6849 7466 -30799 27488 -18603 17106 -35109 14658 -19052 22337 -6783 10329 7854 17562 -2020 14649 -50249 18386 26995 30521 12790 2479 12082 14194 2232 -6306 14675 6614 16775 -27117 35233 -39315 5428 -21681 -2149 3419 13474 25314 12112 1057 -14953 5079 11085 22353 9193 7227 -2295 8652 -15987 14973 -24005 6110 -24511 31884 9275 -19600 -6188 -14611 145 26143 -4489 15901 -4469 -12114 5481 SO 20190422T103426.0Z 7051.440579 171 1 32.01 2 89.02 74.00 73.41 219.68 0.00 1 0.00 1 0 29 2.336e-02 2.269e-02 1.079e-02 1.066e-02 1.149350e+04 6.642434e+02 7.586766e+02 -6.000000e+00 1.190552e+03 278.17 -2.00 20.00 -2.00 505.46 0.00e+00 6.785895e-03 2.872744e-04 3.266114e-04 -6.000000e+00 6.331166e-04 278.17 -2.00 20.00 -2.00 501.33 0.00e+00 1.689044e+00 2.000187e-01 1.019234e-01 -6.000000e+00 4.525129e-01 228.78 -2.00 3.57 -2.00 502.74 0.00e+00 18.784 0.129 489.00 513.00 1 7.8928e+00 1.5278e-02 3.4065e-02 -6.0000e+00 3.4477e-02 -4.4764e-02 3.8836e-03 2.7975e-03 -6.0000e+00 9.2021e-03 4.1860e-05 1.8081e-03 7.9119e-04 1.3063e-04 -6.0000e+00 1.8217e-03 -8.0062e-03 5.1037e-05 12 8 8 10 0 0 18.58 15.00 8.97 -0.00801 0.00454 8 1 1 4 0 4000.000 21.69 15.00 18.41 -6465 -6863 -6002 -2974 -818 495 1666 -382 448 1252 270 140 -2946 -2738 -5379 -3423 -2847 -1148 999 1765 -271 2830 2621 1752 1335 3503 1123 3814 580 -2643 -3350 -1865 -1710 -139 2302 1311 3131 -1449 1170 -168 -88 -74 1037 1257 3753 3435 5529 3919 2847 -320 -1223 -2454 -4051 -2523 -2018 1485 2063 1633 1891 2846 1922 1939 3165 1291 133 868 -451 867 1064 -84 -2098 -2905 -344 -1330 517 12 56 -1764 -3679 -3872 -456 -3480 -1306 -1602 -817 -1603 -1223 -29 565 12 1341 1841 2782 2001 1658 2190 2157 -1334 -205 -2578 -4462 -2709 -2514 585 871 2064 325 -409 -1775 597 -440 456 1264 2022 1674 4460 4348 578 1997 751 -262 654 -11 -536 946 969 1193 1699 930 355 -138 -1229 -1652 -4145 -4033 -2616 935 -581 1420 205 404 1985 -168 1679 2580 600 -849 -2840 -4384 -4893 -5153 -5587 -5040 -2542 -707 431 1472 -350 407 1115 238 122 -2613 -2388 -4777 -2984 -2499 -1017 897 1602 -251 2538 2363 1605 1246 3231 1061 3504 540 -2430 -3010 -1656 -1546 -129 2198 1281 2971 -1423 1109 -160 -84 -72 1018 1257 3733 3465 5462 3898 2826 -322 -1202 -2375 -3925 -2421 -1996 1483 2114 1705 1970 2928 1999 2041 3325 1387 144 919 -475 889 1080 -85 -2136 -2988 -349 -1388 539 13 57 -1789 -3767 -3953 -450 -3573 -1320 -1633 -839 -1678 -1275 -30 569 12 1343 1871 2880 2106 1715 2182 2082 -1293 -192 -2422 -4213 -2544 -2452 539 837 1982 315 -393 -1711 570 -437 460 1282 2056 1717 4477 4452 628 2142 803 -278 671 -12 -558 987 1017 1259 1789 985 381 -149 -1309 -1736 -4446 -4319 -2818 1004 -645 1565 233 463 2252 -196 1935 2954 698 -985 -3267 -5008 -5619 SO 20190422T103850.0Z 7051.443634 175 1 32.01 2 88.25 74.75 73.91 220.59 0.00 1 0.00 1 0 15 3.928e-02 3.880e-02 4.496e-02 4.460e-02 6.274532e+03 2.761157e+03 3.240489e+02 -6.000000e+00 2.002246e+03 278.17 -2.00 20.00 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