File name: Pandora103s1_Downsview_20190427_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T035216.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190427_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190427 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190427T102232.0Z 7056.432315 288 1 32.01 2 89.75 70.94 67.28 155.10 0.00 1 0.00 1 0 36 1.367e-01 1.237e-01 1.116e-01 1.066e-01 1.300988e+04 7.520968e+03 5.852470e+02 -6.000000e+00 6.987855e+03 278.74 -2.00 20.00 -2.00 505.18 0.00e+00 5.134562e-03 2.877068e-03 4.518180e-04 -6.000000e+00 3.715485e-03 278.74 -2.00 20.00 -2.00 499.88 0.00e+00 2.016132e-01 2.177011e+00 7.481078e-02 -6.000000e+00 2.662465e+00 229.23 -2.00 3.57 -2.00 501.51 0.00e+00 20.224 0.161 489.00 513.00 1 1.0187e+01 1.6514e-01 3.8183e-02 -6.0000e+00 2.0264e-01 1.8076e-01 4.4525e-02 2.3302e-03 -6.0000e+00 5.4528e-02 3.8413e-06 -1.6093e-02 7.6832e-03 1.2055e-04 -6.0000e+00 1.0686e-02 -4.5756e-02 1.0638e-04 12 8 8 10 0 0 6.77 15.00 9.30 -0.04576 -0.15739 8 1 1 4 0 4000.000 21.69 15.00 18.53 900000 -625 -12942 7239 822 17064 -7601 8120 -4602 9589 1529 15884 7893 9005 -5424 18672 -5482 -2922 4591 5606 -5519 -4705 2842 10784 16004 -2711 12907 -12467 12532 -20226 -6913 -6379 22411 -18249 -2234 1673 5624 4936 22631 -3051 -3025 9262 10598 271 -21683 -4495 -5702 3133 3270 291 -15208 16931 -3729 3705 -12653 11795 -12801 46149 -13850 -14741 -12307 25062 23121 21707 8570 12547 20985 -15620 -3955 12332 -1661 33405 7680 -20332 9709 1123 1521 17 16474 1502 16410 2241 4083 -6373 10351 -1503 -2995 -12723 14029 1692 12701 -6427 -11996 2748 -12295 4475 -7830 3935 12073 -913 -7674 29204 -290 11306 -6776 8830 23868 18467 -12259 -4146 -3388 -3902 10691 -2397 -19875 -9441 35552 -10670 22757 -5371 23245 -12390 12170 -7253 14542 -18494 24708 -7283 4305 -16458 44026 -2490 9499 -8354 -16182 8130 -13824 23529 -4122 5442 -2322 7671 -155 -1156 8982 27271 8672 13292 -473 -5379 900000 -620 -14546 6894 868 15913 -9166 8578 -5579 10153 1729 15292 8071 8970 -6093 16398 -6046 -3162 4702 5867 -6565 -5550 3101 10880 15350 -3144 12958 -15961 12541 -27375 -7883 -6946 18352 -22361 -2420 1830 6041 5274 20065 -3421 -3350 9072 10346 295 -29720 -5292 -6859 3457 3562 322 -19131 15133 -3937 3563 -14159 10668 -15284 32209 -17519 -18795 -15215 21492 20308 19466 8739 12251 18605 -19306 -4289 11304 -1719 24196 7088 -24766 8955 1144 1546 17 13786 1428 13394 2086 3751 -6511 9013 -1484 -3036 -14162 11954 1604 10726 -6529 -13005 2641 -13810 4190 -7959 3438 9419 -787 -6896 18040 -239 8573 -6462 7628 18170 14716 -12907 -3962 -3219 -3805 9228 -2370 -23366 -10033 24473 -11593 18239 -5681 18394 -13499 10175 -7153 11648 -20663 18254 -7333 3878 -17980 26889 -2381 7903 -8044 -16650 6576 -13946 17007 -3959 4802 -2237 6779 -148 -1118 7896 20060 7585 10938 -432 -5007 SO 20190427T102656.0Z 7056.435370 292 1 32.01 2 89.00 71.70 66.96 156.15 0.00 1 0.00 1 0 22 7.190e-02 6.920e-02 6.858e-02 6.692e-02 1.694906e+03 3.857483e+03 1.881182e+02 -6.000000e+00 3.673305e+03 278.74 -2.00 20.00 -2.00 505.19 0.00e+00 1.613454e-03 1.781327e-03 4.233324e-05 -6.000000e+00 1.951720e-03 278.74 -2.00 20.00 -2.00 499.77 0.00e+00 2.880944e+00 1.330242e+00 7.372857e-02 -6.000000e+00 1.393695e+00 229.23 -2.00 3.57 -2.00 501.44 0.00e+00 18.733 0.128 489.00 513.00 1 9.7985e+00 1.0154e-01 3.2262e-02 -6.0000e+00 1.0619e-01 1.3568e-01 2.6773e-02 2.0245e-03 -6.0000e+00 2.8355e-02 6.2319e-06 4.9951e-03 5.0452e-03 1.3827e-05 -6.0000e+00 5.6078e-03 2.6521e-03 -4.2070e-05 12 8 8 10 0 0 -5.14 15.00 1.99 0.00265 0.03730 8 1 1 4 0 4000.000 21.79 15.00 18.54 -38 -17447 3633 -189 -4581 -1293 2946 -6088 2827 2580 -5607 -15031 4956 -5214 17613 4483 17392 -5022 2429 2200 6465 3126 -3594 188 -2305 8599 4602 -2415 2046 1230 6875 -5890 4739 2331 9091 -434 -7214 5074 3548 -1036 924 -7655 882 -3157 474 -2491 15459 -3516 -3681 -3333 2459 -16574 4431 158 -2406 4215 1814 -154 5699 6648 4329 -5062 -3499 3160 3548 7006 1556 3754 -6022 6233 -665 10019 2913 12865 6837 22851 -7698 -1793 5699 2641 -16277 404 232 -2963 -6151 2315 -2800 -2817 9758 -1832 4969 921 301 -6932 782 1549 1284 -6063 -4066 3918 21616 -6504 10558 -9446 -80 8105 -10214 5463 5217 -8264 16722 -5856 -4731 11015 4149 2136 5214 9185 -15095 94 7596 8438 -6141 103 1837 13497 2096 14575 3616 -10345 -6371 3563 289 -2765 1910 -10276 3714 -5106 1286 -7890 1960 -5020 7514 1199 -2662 -7448 3726 -316 -8923 8597 -38 -20601 3622 -204 -5281 -1470 3285 -7495 3187 2869 -6618 -19216 5131 -5857 15711 4546 15737 -5803 2697 2479 6962 3479 -4259 215 -2725 9147 5061 -2826 2234 1292 6654 -6470 4783 2514 9539 -501 -8762 5384 3766 -1135 993 -9000 965 -3635 532 -2887 14936 -4023 -4143 -3642 2450 -19253 4123 154 -2479 4231 1907 -166 5775 6615 4394 -5663 -3869 3266 3616 6772 1551 3608 -6292 5678 -638 8678 2729 11118 6346 17973 -7916 -1700 4974 2360 -17515 373 215 -2846 -6172 2155 -2734 -2737 8357 -1756 4476 875 294 -7288 751 1447 1177 -5800 -3707 3220 14825 -5934 8453 -9627 -77 7084 -10456 4695 4431 -8073 13083 -5804 -4705 9490 3831 2017 4815 8184 -16821 89 6538 7078 -5901 95 1666 10912 1893 11612 3193 -10518 -6191 3069 252 -2451 1609 -9920 3225 -4918 1177 -7978 1806 -4955 6608 1129 -2606 -7582 3322 -283 -8470 6874 SO 20190427T103115.0Z 7056.438368 296 1 32.01 2 88.26 72.44 66.65 157.17 0.00 1 0.00 1 0 8 5.843e-02 5.786e-02 5.295e-02 5.180e-02 -1.648068e+03 2.814639e+03 4.207076e+01 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