File name: Pandora103s1_Downsview_20190621_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T042023.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190621_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190621T094254.0Z 7111.404792 137 1 32.01 2 89.78 56.83 64.86 197.31 0.00 1 0.00 1 0 15 7.060e-02 6.686e-02 6.389e-02 6.224e-02 1.284872e+04 4.433954e+03 5.597476e+02 -6.000000e+00 3.691882e+03 284.59 -2.00 20.00 -2.00 505.22 0.00e+00 1.551342e-03 1.675950e-03 1.009501e-04 -6.000000e+00 1.944525e-03 284.59 -2.00 20.00 -2.00 499.80 0.00e+00 2.791812e+00 1.253517e+00 1.416839e-01 -6.000000e+00 1.370478e+00 232.92 -2.00 3.57 -2.00 501.46 0.00e+00 20.063 0.157 489.00 513.00 1 9.5068e+00 9.5750e-02 3.7478e-02 -6.0000e+00 1.0461e-01 1.1843e-01 2.4945e-02 3.2988e-03 -6.0000e+00 2.7904e-02 6.8520e-06 5.3712e-03 4.5466e-03 5.5117e-05 -6.0000e+00 5.5080e-03 -2.3733e-02 1.2160e-04 12 8 8 10 0 0 -8.67 15.00 7.63 -0.02373 0.01352 8 1 1 4 0 4000.000 22.09 15.00 18.96 3552 4036 -3342 3318 4390 4036 4313 -4725 6537 -5204 1633 304 -5985 -1149 5695 1259 -2942 -3172 -1133 3580 -7315 881 -4864 -1441 -2009 -7139 12867 14617 5359 3593 267 -5290 6880 2956 6901 -301 -2738 5910 1462 1743 -7785 -5540 -24 -11532 -4331 3618 -6085 851 4088 13009 -2096 -5212 7036 7204 7077 -6371 4685 -1019 -2896 3169 6102 -9334 -4342 -7550 6356 -2690 -2247 -1057 12498 -2749 -3599 357 4435 9799 -256 6789 -1334 -866 12649 23108 -13740 -5996 -8610 2834 2606 -5474 2374 8299 -9756 752 -989 2731 -6174 698 -3235 2966 -14479 1259 10548 1108 -2079 -4834 12279 -685 2831 -184 7313 5217 8471 -17146 -1184 -6757 2575 10681 14806 803 8343 -7951 10133 -5815 839 5122 6367 17096 -6468 -5348 -10133 -10894 6723 18330 -1590 4473 7135 -7390 -3154 8502 -7567 554 -6913 11099 6008 -4252 650 13705 9518 -4919 -2744 -1306 -7103 4620 3305 3798 -3504 3401 4563 4289 4674 -5658 7009 -6161 1774 331 -6812 -1227 5641 1304 -3213 -3569 -1293 3952 -8944 995 -5799 -1667 -2356 -8811 13003 14439 5648 3677 275 -5769 6790 3167 7396 -348 -3188 6229 1586 1864 -9131 -6402 -27 -14468 -5122 3970 -7290 938 4294 12206 -2196 -5460 6428 6608 6708 -7150 4835 -1119 -3222 3295 6149 -11007 -4896 -8762 6378 -2891 -2353 -1076 11044 -2768 -3598 344 4150 8845 -258 6321 -1306 -823 10416 17050 -14484 -5910 -8736 2589 2424 -5554 2225 7277 -10085 699 -938 2536 -6360 668 -3113 2584 -14382 1040 7795 878 -1686 -4104 9247 -623 2593 -175 6376 4546 7050 -18481 -1114 -6801 2377 9119 12119 756 7421 -8424 8980 -5907 779 4440 5387 13181 -6332 -5181 -10315 -11132 5762 14116 -1473 3804 5820 -6909 -2832 6973 -7468 512 -6958 9526 5466 -4296 630 11722 8466 -4997 -2676 -1220 -6877 3992 SO 20190621T094722.0Z 7111.407894 141 1 32.01 2 89.10 57.59 65.09 198.42 0.00 1 0.00 1 0 22 5.810e-02 5.564e-02 5.069e-02 4.955e-02 8.635573e+03 3.403530e+03 4.094225e+02 -6.000000e+00 3.037638e+03 284.59 -2.00 20.00 -2.00 505.24 0.00e+00 2.612484e-03 1.337507e-03 8.173850e-05 -6.000000e+00 1.601036e-03 284.59 -2.00 20.00 -2.00 499.81 0.00e+00 2.976995e+00 9.995358e-01 6.182402e-02 -6.000000e+00 1.131860e+00 232.92 -2.00 3.57 -2.00 501.47 0.00e+00 18.811 0.130 489.00 513.00 1 9.4275e+00 7.6343e-02 3.2457e-02 -6.0000e+00 8.6307e-02 1.1869e-01 1.9873e-02 2.1765e-03 -6.0000e+00 2.3184e-02 8.6701e-06 1.0735e-02 3.6618e-03 4.8311e-05 -6.0000e+00 4.5408e-03 -1.1812e-02 -4.4582e-05 12 8 8 10 0 0 14.14 14.99 4.40 -0.01181 0.06265 8 1 1 4 0 4000.000 22.09 14.99 18.96 900000 573 -5813 -4010 -2971 -4802 -5741 -1397 -971 -7233 6810 -2605 4639 -3197 5039 5566 7426 3361 -333 3335 -1361 1365 -1917 10468 1891 -2092 -940 2310 -672 4022 -6017 -3751 791 9102 3275 -2601 -6506 3696 1985 -469 1181 -6589 784 -1472 -2022 -2143 14127 -7667 5882 4928 -4310 6019 5193 -13246 -358 1253 4484 273 3601 447 807 5023 2235 -1832 1835 6201 -5791 4397 238 5849 837 736 11994 8635 -26 -3433 -7091 6613 -8549 3933 2326 1495 -1161 -5822 5386 -9357 -1287 -2399 4446 -5530 -2305 -6730 6254 -4181 8329 -3503 6050 -8432 14005 -6312 7841 3593 3577 -3166 -8609 5560 -6307 3963 -1951 8024 14238 12539 -3694 10099 6992 -2213 -5635 3235 -6955 6181 8017 -1942 1139 3059 5030 -11425 -2181 -3126 3457 -1864 7844 -7209 -4371 -3505 11573 -9259 5931 -7603 7419 -2793 1845 -7643 6388 -351 -452 1642 9885 -10258 -2721 703 900000 566 -6353 -4480 -3357 -5631 -6936 -1632 -1125 -8739 7047 -2918 4760 -3484 5033 5548 7373 3577 -378 3685 -1568 1533 -2217 10786 2134 -2454 -1086 2563 -743 4058 -6566 -4028 832 9255 3639 -3054 -7806 3954 2129 -511 1268 -7693 863 -1678 -2341 -2484 13862 -9153 6045 4968 -4583 5629 4827 -14900 -368 1315 4650 296 3757 477 857 5163 2366 -2009 1918 6084 -6251 4238 236 5386 800 707 10428 7886 -26 -3501 -7273 5806 -8615 3484 2098 1370 -1094 -5779 4860 -9793 -1240 -2315 3980 -5444 -2212 -6861 5716 -4196 7191 -3288 5011 -7804 10172 -5458 5883 2869 2990 -2985 -8791 4928 -6168 3432 -1773 6716 11450 10390 -3614 8670 6186 -2152 -5751 3056 -7187 5504 6855 -1789 1013 2711 4401 -11729 -2050 -2951 3055 -1745 6597 -6833 -3973 -3135 8954 -8996 5107 -7565 6457 -2719 1725 -7866 5769 -339 -438 1540 8347 -10214 -2471 620 SO 20190621T095137.0Z 7111.410845 145 1 32.01 2 88.45 58.32 65.32 199.48 0.00 1 0.00 1 0 15 3.463e-02 3.404e-02 3.346e-02 3.306e-02 5.869312e+03 2.123846e+03 4.310337e+02 -6.000000e+00 1.810805e+03 284.59 -2.00 20.00 -2.00 505.26 0.00e+00 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