File name: Pandora103s1_Downsview_20190812_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T044823.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190812_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190812T102507.0Z 7163.434109 295 1 32.01 2 89.74 69.29 120.86 266.89 0.00 1 0.00 1 0 15 4.881e-02 4.893e-02 4.659e-02 4.578e-02 5.708480e+03 2.997660e+03 4.172327e+02 -6.000000e+00 2.578741e+03 287.38 -2.00 20.00 -2.00 505.25 0.00e+00 5.700742e-03 1.235399e-03 3.368712e-04 -6.000000e+00 1.354606e-03 287.38 -2.00 20.00 -2.00 499.92 0.00e+00 3.893506e+00 9.258813e-01 5.611558e-02 -6.000000e+00 9.479342e-01 232.02 -2.00 3.57 -2.00 501.57 0.00e+00 19.942 0.154 489.00 513.00 1 9.0850e+00 7.0908e-02 3.6495e-02 -6.0000e+00 7.2369e-02 1.0500e-01 1.8575e-02 2.1561e-03 -6.0000e+00 1.9411e-02 9.3664e-06 6.2712e-04 3.4344e-03 9.0784e-05 -6.0000e+00 3.8150e-03 -2.8414e-02 8.9786e-05 12 8 8 10 0 0 -2.80 14.99 5.03 -0.02841 -0.02406 8 1 1 4 0 4000.000 22.19 14.99 19.09 900000 -423 -2875 -4900 -1653 8323 4474 -4615 12492 -2458 6381 4974 -4209 2526 971 -2069 425 -4884 -7211 -4631 1052 -2936 -2767 -1746 -5511 -78 -4008 2161 1206 1139 -2381 4322 577 6171 -11104 4418 -3946 1164 4523 -1024 -501 7088 1688 900 12775 7306 -710 3032 9384 1329 7271 -112 -1133 4609 8099 2357 1722 924 4069 -9751 -5447 -842 4607 789 -6731 -7220 -8384 -2116 -1176 5464 -2864 3227 -3752 5550 1544 8116 -9675 -6712 -4185 -1647 -926 5027 -4364 1651 -3744 5099 5094 2867 3770 4850 -3845 9844 -2422 1877 -652 4188 12876 -5108 -4553 -1090 -1156 -5242 -2121 3443 6704 -583 -2434 -5770 3937 -2524 2795 -2227 1141 2472 5083 -237 -781 5811 2712 7291 660 -2180 -4300 -3862 2807 460 -3649 -3321 -4146 5471 -9558 47 7008 2556 5709 -4763 -4216 2216 -1065 9208 -5349 1044 7060 -6835 -1045 -4208 2766 2933 2976 -2356 900000 -409 -2945 -5349 -1806 8401 4790 -5481 12583 -2829 6588 5128 -4677 2581 995 -2177 439 -5424 -8461 -5408 1159 -3357 -3156 -1975 -6529 -88 -4704 2379 1318 1193 -2483 4201 589 6180 -13778 4794 -4588 1266 4701 -1110 -540 7146 1820 992 12734 7738 -812 3301 9453 1418 7083 -114 -1134 4351 7564 2423 1835 1005 4287 -11661 -6213 -924 4822 856 -7803 -8269 -9499 -2214 -1205 5162 -2876 3041 -3807 5205 1528 7519 -10397 -6813 -4083 -1555 -865 4455 -4252 1516 -3655 4609 4595 2622 3383 4283 -3701 8389 -2381 1791 -630 3762 10357 -4753 -4096 -922 -960 -4542 -1830 2949 5783 -542 -2272 -5453 3329 -2283 2457 -2101 1058 2290 4617 -227 -760 5364 2575 6510 616 -2050 -4074 -3678 2541 427 -3533 -3207 -4016 4850 -9818 43 5862 2207 4744 -4428 -4013 2024 -1015 8042 -5422 996 6378 -7107 -1030 -4262 2571 2638 2598 -2149 SO 20190812T102929.0Z 7163.437141 299 1 32.01 2 89.00 70.04 121.62 267.60 0.00 1 0.00 1 0 29 2.965e-02 2.883e-02 2.507e-02 2.471e-02 9.950978e+03 1.716533e+03 5.704943e+02 -6.000000e+00 1.566473e+03 287.38 -2.00 20.00 -2.00 505.25 0.00e+00 4.095641e-03 6.750052e-04 2.215908e-04 -6.000000e+00 8.232583e-04 287.38 -2.00 20.00 -2.00 499.94 0.00e+00 2.327778e+00 4.980302e-01 8.057039e-02 -6.000000e+00 5.769342e-01 232.02 -2.00 3.57 -2.00 501.58 0.00e+00 18.523 0.124 489.00 513.00 1 8.7821e+00 3.8089e-02 3.2334e-02 -6.0000e+00 4.4027e-02 1.1559e-01 9.9925e-03 2.3613e-03 -6.0000e+00 1.1838e-02 1.7668e-05 1.1620e-03 1.8201e-03 7.2791e-05 -6.0000e+00 2.3182e-03 -1.6931e-03 -2.0768e-04 12 8 8 10 0 0 11.11 15.00 0.53 -0.00169 0.00637 8 1 1 4 0 4000.000 22.19 15.00 19.10 900000 -1942 -859 -4255 442 -2668 2941 -2895 3527 1578 -987 -985 -3703 735 -1761 -3467 2791 3668 -1666 -2547 -314 2233 -954 1342 -66 2425 3164 1069 -4174 4269 -4003 -1756 339 -1168 3615 1000 397 -1260 3619 -162 -769 -2512 2352 -3026 2178 -13 3022 -4192 4556 -2967 -1695 -2600 4653 1027 1535 -1189 3054 3339 1721 -678 3298 -2901 -2249 1704 2991 3657 -1810 5845 -227 4585 -6007 -2234 -3908 4663 -119 1046 1147 2212 1733 443 -1254 4346 -1530 -356 -862 -3626 -2032 -4538 -3909 53 5219 -2781 -1705 2890 -822 -1037 7074 -3490 -2460 -873 -1557 7607 2293 -467 -931 6932 -413 5718 -395 2841 -2144 3157 -1336 543 -2320 5858 955 1308 -3013 -643 3056 -3439 5 -3094 -3145 -2021 -1740 6895 1543 835 518 -3564 -1763 -1709 -1647 -6017 -314 -5038 3422 4046 40 339 3598 -1441 -2007 1112 -254 4068 -4295 -866 900000 -1903 -857 -4580 470 -2977 3175 -3362 3863 1744 -1093 -1075 -4091 764 -1850 -3689 2810 3734 -1843 -2910 -351 2428 -1068 1471 -74 2672 3452 1185 -4802 4343 -4235 -1804 345 -1245 3857 1117 442 -1401 3787 -173 -826 -2761 2498 -3430 2382 -14 3302 -4855 4772 -3277 -1792 -2679 4369 993 1507 -1248 3173 3512 1839 -736 3424 -3214 -2494 1818 3136 3752 -1916 5636 -229 4364 -6212 -2214 -3963 4403 -120 1042 1117 2071 1603 412 -1177 3884 -1455 -335 -825 -3606 -1991 -4523 -3831 49 4647 -2703 -1676 2748 -797 -976 5952 -3150 -2141 -730 -1286 5762 1881 -415 -872 6114 -388 4968 -358 2490 -2012 2871 -1284 516 -2272 5304 915 1270 -3064 -630 2827 -3307 5 -2916 -3009 -1919 -1650 6020 1410 770 481 -3368 -1598 -1531 -1466 -5634 -286 -4910 3103 3697 39 326 3360 -1420 -1990 1066 -243 3630 -4037 -779 SO 20190812T103342.0Z 7163.440070 303 1 32.01 2 88.28 70.76 122.34 268.29 0.00 1 0.00 1 0 22 1.382e-02 1.371e-02 1.244e-02 1.234e-02 1.402570e+04 8.749055e+02 9.034643e+02 -6.000000e+00 7.299221e+02 287.38 -2.00 20.00 -2.00 505.31 0.00e+00 3.141924e-03 3.352041e-04 1.802911e-04 -6.000000e+00 3.834662e-04 287.38 -2.00 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