File name: Pandora103s1_Downsview_20190820_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T051538.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190820_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190820T103358.0Z 7171.440255 161 1 32.01 2 89.74 72.87 47.23 217.40 0.00 1 0.00 1 0 15 2.073e-02 2.056e-02 2.354e-02 2.334e-02 1.288279e+04 1.645779e+03 7.934954e+02 -6.000000e+00 1.093795e+03 287.07 -2.00 20.00 -2.00 505.33 0.00e+00 3.906631e-03 6.367033e-04 2.089964e-04 -6.000000e+00 5.747419e-04 287.07 -2.00 20.00 -2.00 500.25 0.00e+00 2.612685e+00 4.618344e-01 9.036741e-02 -6.000000e+00 4.021757e-01 231.47 -2.00 3.57 -2.00 501.86 0.00e+00 19.962 0.155 489.00 513.00 1 8.4994e+00 3.5317e-02 3.6555e-02 -6.0000e+00 3.0704e-02 7.7607e-02 9.1841e-03 2.7949e-03 -6.0000e+00 8.2312e-03 1.8738e-05 -8.5100e-04 1.6973e-03 8.3443e-05 -6.0000e+00 1.6196e-03 -2.2610e-02 8.0772e-05 12 8 8 10 0 0 -2.77 14.99 3.14 -0.02261 -0.02851 8 1 1 4 0 4000.000 22.19 14.99 19.10 900000 433 -7614 3593 -3534 3025 -1190 4316 -4241 451 1196 1346 413 -2890 -1239 -1223 543 -2890 999 -372 391 -729 -47 199 652 177 -586 -2483 -769 728 2812 1507 -1833 140 940 199 218 -1029 2861 915 1835 -138 1854 -3421 -648 5021 2388 -1188 -1884 190 190 -302 -1252 59 -2 -42 -1119 1741 1557 2081 850 2481 3427 1394 1494 1384 787 -599 -193 -1781 -3130 3413 746 -2194 -1554 -32 -3066 1462 1108 -2287 37 -1005 -3444 -117 328 872 -1460 -1291 1608 3043 67 69 -1752 1921 395 3251 -899 1266 -4502 2157 -2294 103 -1602 5398 -166 571 988 3405 777 -1844 187 43 1007 -2132 2033 -324 -302 1175 662 -1524 -2045 -808 1593 846 1767 -1894 4973 -1533 -1006 -524 2077 -2541 1128 -2807 -1357 -2499 -2852 -755 -1122 2506 -191 4262 -1568 998 3372 516 -799 -3657 -1672 -1402 900000 396 -7750 3429 -3735 3058 -1281 4479 -4798 483 1246 1380 422 -2993 -1248 -1229 540 -3034 1044 -403 421 -791 -51 215 706 194 -645 -2776 -833 747 2717 1467 -1866 145 1011 220 238 -1120 2963 954 1892 -146 1950 -3842 -719 5316 2591 -1319 -2075 201 195 -301 -1232 57 -2 -44 -1205 1850 1657 2188 900 2600 3585 1488 1586 1448 811 -614 -195 -1802 -3150 3211 726 -2225 -1593 -32 -3118 1383 1036 -2190 34 -951 -3357 -110 313 838 -1435 -1257 1505 2787 63 66 -1740 1855 379 2925 -811 1082 -3971 1745 -1904 84 -1374 4584 -157 545 934 3088 710 -1734 176 41 968 -2125 1947 -317 -300 1173 669 -1551 -2046 -778 1470 790 1661 -1852 4563 -1501 -974 -506 1962 -2455 1028 -2640 -1254 -2365 -2792 -739 -1113 2438 -193 4148 -1623 1012 3342 524 -809 -3710 -1621 -1344 SO 20190820T103818.0Z 7171.443264 165 1 32.01 2 89.00 73.62 47.69 218.70 0.00 1 0.00 1 0 29 1.320e-02 1.319e-02 1.041e-02 1.036e-02 1.402948e+04 7.254820e+02 9.266605e+02 -6.000000e+00 6.962505e+02 287.07 -2.00 20.00 -2.00 505.37 0.00e+00 2.828487e-03 2.815291e-04 1.518832e-04 -6.000000e+00 3.659676e-04 287.07 -2.00 20.00 -2.00 500.47 0.00e+00 1.938178e+00 2.014604e-01 8.580546e-02 -6.000000e+00 2.562587e-01 231.47 -2.00 3.57 -2.00 502.06 0.00e+00 18.522 0.124 489.00 513.00 1 7.9171e+00 1.5378e-02 3.2283e-02 -6.0000e+00 1.9561e-02 4.9385e-02 3.9943e-03 2.7020e-03 -6.0000e+00 5.2501e-03 4.3730e-05 2.5722e-03 7.4494e-04 9.6935e-05 -6.0000e+00 1.0314e-03 9.9247e-03 -1.8210e-04 12 8 8 10 0 0 72.05 15.00 2.24 0.00992 0.02777 8 1 1 4 0 4000.000 22.19 15.00 19.10 900000 -1138 -1922 193 -491 -552 -477 -830 2816 628 1552 -3447 162 -1758 210 -2233 -421 -1541 -1042 928 482 249 769 657 1417 -760 -6 535 1155 186 -1851 -1028 -1084 748 423 1120 -874 1652 -453 843 57 831 644 660 -522 1774 696 2071 963 2064 788 -1596 -1727 -1053 38 -2801 1559 453 1106 -105 1373 571 2593 971 1237 -1005 -8 -989 -442 -1756 -2879 -232 850 1075 -351 -971 -1195 -2006 -3031 -701 -448 55 -601 -524 -21 1112 -34 1637 -220 1209 -430 1478 1002 3060 -654 220 -451 1489 -968 -956 -1362 -1798 -1029 -1856 2624 -1216 -135 -1193 -102 -1944 774 435 517 336 -26 1910 1731 324 2548 850 -1942 250 -424 -79 1348 1378 1480 206 1843 -104 -508 -700 -1844 325 -2074 -210 -1794 737 65 1363 -2059 413 891 901 921 1022 -9 -3358 -1179 -1550 900000 -1026 -1805 186 -489 -560 -495 -878 2885 650 1560 -3591 161 -1750 203 -2209 -413 -1566 -1089 971 505 262 805 690 1491 -821 -6 568 1197 186 -1830 -1008 -1079 761 451 1204 -945 1720 -476 864 59 857 674 701 -568 1902 752 2184 1011 2101 786 -1579 -1680 -1018 38 -2943 1617 480 1165 -112 1428 603 2703 1028 1300 -1061 -9 -1008 -444 -1761 -2872 -225 826 1057 -356 -988 -1189 -1960 -2953 -662 -421 51 -574 -502 -21 1079 -33 1569 -212 1144 -414 1417 986 2959 -638 205 -408 1278 -833 -806 -1138 -1526 -902 -1743 2483 -1213 -132 -1161 -96 -1885 747 428 512 335 -26 1875 1728 335 2590 865 -1985 244 -408 -77 1304 1337 1440 203 1778 -102 -503 -678 -1771 304 -1984 -200 -1793 732 66 1382 -2181 430 929 943 963 1064 -9 -3496 -1175 -1542 SO 20190820T104229.0Z 7171.446169 169 1 32.01 2 88.27 74.34 48.15 219.94 0.00 1 0.00 1 0 22 1.183e-02 1.157e-02 2.904e-03 2.890e-03 1.535612e+04 1.974093e+02 1.005895e+03 -6.000000e+00 6.239416e+02 287.07 -2.00 20.00 -2.00 505.43 0.00e+00 3.500095e-03 7.916104e-05 1.834842e-04 -6.000000e+00 3.279522e-04 287.07 -2.00 20.00 -2.00 500.97 0.00e+00 1.600145e+00 5.459662e-02 1.009496e-01 -6.000000e+00 2.296079e-01 231.47 -2.00 3.57 -2.00 502.48 0.00e+00 16.684 0.090 489.00 513.00 1 6.7686e+00 4.1560e-03 2.8306e-02 -6.0000e+00 1.7527e-02 -2.6062e-02 1.0805e-03 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