File name: Pandora103s1_Downsview_20190821_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T051528.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190821_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190821T103504.0Z 7172.441019 167 1 32.01 2 89.75 73.34 39.19 206.30 0.00 1 0.00 1 0 28 1.422e-01 1.239e-01 1.303e-01 1.234e-01 -3.587508e+03 7.051328e+03 1.072818e+02 -6.000000e+00 7.500301e+03 286.99 -2.00 20.00 -2.00 505.16 0.00e+00 4.608297e-03 3.385805e-03 2.114475e-04 -6.000000e+00 3.948731e-03 286.99 -2.00 20.00 -2.00 499.67 0.00e+00 5.794735e+00 2.535589e+00 7.565602e-02 -6.000000e+00 2.773924e+00 231.38 -2.00 3.57 -2.00 501.34 0.00e+00 19.968 0.155 489.00 513.00 1 9.9911e+00 1.9477e-01 3.6211e-02 -6.0000e+00 2.1147e-01 1.0120e-01 5.1572e-02 2.2659e-03 -6.0000e+00 5.7158e-02 3.3262e-06 -7.4216e-03 9.2448e-03 5.3073e-05 -6.0000e+00 1.1123e-02 5.2193e-02 -8.3295e-04 12 8 8 10 0 0 5.67 15.00 8.22 0.05219 0.00071 8 1 1 4 0 4000.000 22.19 15.00 19.11 900000 -600 8393 -2188 15705 22212 -2662 -3597 1772 -10185 9369 -8180 -8191 1578 7340 -6696 16143 929 1801 -5255 -5722 -6331 27 1674 -14839 4120 12581 4952 -11225 -5241 6172 29192 4265 3950 -1346 24307 -1130 16539 -1271 -21209 -1768 239 8633 26250 4132 -7881 27343 -7991 2091 -608 9854 -15332 26795 807 -2303 -4606 -151 -10615 6135 1048 116 6931 8487 22209 8277 96 -11085 -10798 3501 -1574 -5881 7093 -26746 28162 14009 5173 -16088 -14161 -1748 9448 31624 -9235 4173 -6013 5289 -15147 3977 26511 10438 -11627 13216 -6459 19641 -16024 26781 3153 7020 -2317 7364 -6089 27570 -8945 1814 -27912 6620 3043 -8703 9040 43645 -1353 16627 -11643 -5392 39098 -2787 204 2105 6234 -5296 -3216 -10608 9453 4340 27983 -12670 11297 18915 34854 5570 10513 -21558 42494 13038 28953 -11976 4597 -15212 1487 -12832 -12425 -7523 -4744 8363 9266 15261 -14232 14259 -4013 -1085 21805 900000 -597 7745 -2312 14573 19932 -3093 -4308 2043 -13189 9911 -10037 -9912 1712 7396 -7643 14748 992 1949 -6288 -6998 -7775 31 1896 -19742 4611 13042 5507 -14532 -6283 6335 23187 4292 4038 -1502 22160 -1334 16217 -1457 -29061 -1983 262 8815 22873 4516 -9796 24362 -9962 2332 -684 9806 -18803 21188 802 -2347 -4926 -160 -12837 6384 1140 126 7020 8504 19578 8332 104 -13095 -12432 3447 -1608 -6151 6420 -33361 20823 12002 4896 -18625 -15677 -1670 7995 21491 -9276 3713 -5917 4656 -16339 3592 19244 8792 -12051 10787 -6385 15264 -17958 20230 2986 6347 -2271 6432 -5858 18593 -8383 1534 -32032 5647 2750 -8720 7457 25263 -1184 12301 -11549 -5158 24993 -2716 195 1988 5677 -5383 -3164 -10994 7957 3794 19392 -13132 9413 14650 23208 4907 8805 -24748 26418 10563 19693 -11854 3830 -15429 1322 -13431 -13136 -7657 -4718 7314 8067 12664 -15796 12015 -3958 -1005 15679 SO 20190821T103920.0Z 7172.443982 171 1 32.01 2 89.01 74.07 39.52 207.85 0.00 1 0.00 1 0 15 8.690e-02 8.477e-02 7.670e-02 7.387e-02 1.669902e+04 5.641758e+03 8.754256e+02 -6.000000e+00 4.584307e+03 286.99 -2.00 20.00 -2.00 505.18 0.00e+00 3.528516e-03 1.979077e-03 2.836464e-04 -6.000000e+00 2.408179e-03 286.99 -2.00 20.00 -2.00 499.55 0.00e+00 1.191972e+00 1.518445e+00 1.292548e-01 -6.000000e+00 1.681302e+00 231.38 -2.00 3.57 -2.00 501.22 0.00e+00 18.553 0.124 489.00 513.00 1 9.9889e+00 1.1554e-01 3.3600e-02 -6.0000e+00 1.2847e-01 1.7608e-01 3.0274e-02 3.1000e-03 -6.0000e+00 3.4234e-02 5.6679e-06 -7.6156e-05 5.1170e-03 8.5140e-05 -6.0000e+00 6.7805e-03 -9.0966e-03 3.7280e-05 12 8 8 10 0 0 -3.75 15.00 4.01 -0.00910 -0.00962 8 1 1 4 0 4000.000 22.19 15.00 19.11 -8672 -663 -5976 -3341 -2588 8261 -1456 21476 -2746 15855 9993 660 151 -12576 9448 -16949 3998 -7472 3488 -8145 16194 -636 -3959 -5506 -9910 5689 12768 -2455 2953 -21954 3039 8059 7916 1610 3890 1455 1885 3888 8870 7473 2140 8299 11510 11110 -9260 12667 -6784 14880 -5296 10975 -8724 -121 891 14560 -3112 -5669 -11990 1850 1138 11736 791 3517 -6233 2169 -8343 -2123 9473 4155 -3086 -15281 5827 -10668 -3265 -7740 16302 11299 1503 9536 207 1657 28783 -5979 -1985 6528 -8936 1797 630 1930 849 9813 -6406 819 3508 501 -11072 7720 2235 1558 -2392 5071 -1781 4036 590 4384 -9889 27 -3094 -5405 -9248 -1788 18071 2825 6930 -11242 4578 -3151 7394 -2410 6872 2790 15863 3529 12944 3434 21787 -9265 10278 -6811 -4330 -7931 4756 5120 -10939 -658 3006 4074 -5955 16674 -10382 -965 -8650 -8574 -5587 284 -2902 -9630 7075 3709 4954 21217 -9574 -683 -6681 -3799 -3009 8787 -1738 20809 -3368 16023 10452 745 169 -15583 9335 -21573 4180 -8915 3863 -10294 16101 -743 -4767 -6731 -12743 6316 13173 -2921 3272 -29633 3100 7798 7767 1741 4303 1671 2127 4231 9068 7642 2298 8448 11496 11281 -11614 12911 -8325 14600 -6215 10761 -10002 -123 881 12581 -3271 -6357 -14708 2007 1241 11442 853 3715 -7281 2332 -9865 -2323 9057 4106 -3235 -17755 5414 -11597 -3327 -8344 14142 10250 1461 8333 195 1522 20224 -5911 -1896 5759 -9281 1701 602 1804 790 8289 -6333 764 3251 479 -11476 6382 1865 1262 -1968 3798 -1402 3034 476 3632 -9921 25 -2941 -5155 -8989 -1622 13802 2539 6011 -11623 4047 -2998 6441 -2360 6187 2572 12547 3050 9989 2915 15686 -9029 8304 -6489 -3995 -7592 4017 4193 -10229 -554 2435 3313 -5490 12530 -10219 -881 -8596 -8554 -5436 261 -2741 -9642 5923 3122 4017 14597 SO 20190821T104333.0Z 7172.446910 175 1 32.01 2 88.28 74.80 39.87 209.37 0.00 1 0.00 1 0 15 4.800e-02 4.693e-02 5.102e-02 4.991e-02 1.148155e+04 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