File name: Pandora103s1_Downsview_20190822_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T051515.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190822_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190822T103616.0Z 7173.441852 166 1 32.01 2 89.73 73.82 32.59 190.71 0.00 1 0.00 1 0 15 5.090e-02 5.113e-02 5.110e-02 5.021e-02 7.163932e+03 3.308681e+03 4.671651e+02 -6.000000e+00 2.684585e+03 286.90 -2.00 20.00 -2.00 505.19 0.00e+00 1.970603e-03 1.365603e-03 8.986147e-05 -6.000000e+00 1.410592e-03 286.90 -2.00 20.00 -2.00 499.82 0.00e+00 1.153632e+00 1.000549e+00 5.157137e-02 -6.000000e+00 9.849616e-01 231.29 -2.00 3.57 -2.00 501.47 0.00e+00 19.950 0.155 489.00 513.00 1 9.4376e+00 7.6613e-02 3.5692e-02 -6.0000e+00 7.5257e-02 1.6765e-01 2.0131e-02 2.2548e-03 -6.0000e+00 2.0058e-02 8.4817e-06 3.0018e-03 3.7135e-03 5.0245e-05 -6.0000e+00 3.9709e-03 -3.9369e-02 2.0519e-04 12 8 8 10 0 0 8.65 15.00 5.69 -0.03937 -0.01855 8 1 1 4 0 4000.000 22.09 15.00 19.07 -2849 -3153 -4264 -5025 1422 652 -5311 1344 -1235 2085 -3422 4005 -63 1847 -3185 338 -5688 1714 1233 5185 -554 2882 -3467 1666 3716 9465 979 4821 10691 -9429 1786 -6550 -1083 -3832 377 -7932 2785 5191 4556 3602 2719 -734 5659 4212 -3646 1365 -9220 2439 -3308 5457 -2670 829 -4516 -5908 -3438 827 1038 578 1908 10481 5906 2628 6093 -3435 294 5143 7795 10339 -3675 4120 2499 -3482 -2307 1195 1020 -14706 2343 -5593 272 -2876 -3721 -285 10090 6800 9393 2344 -4882 -8972 6246 -3236 -1041 -5332 3704 1169 -933 4334 -2236 6468 -2544 270 -10087 1575 -1235 3721 6847 4938 -4426 -799 4208 4727 2354 2905 -11011 9174 829 -4067 8572 2377 -5831 -8123 7014 6836 4466 -8845 2939 515 7068 3362 244 -4062 7669 -5320 1883 -11 -7383 200 5443 -2559 3361 -717 5472 -3597 -4188 -236 1852 1556 -14776 41 2060 4860 -2858 -3208 -4533 -5613 1533 720 -6355 1527 -1439 2320 -3932 4228 -68 1924 -3446 353 -6356 1826 1364 5611 -632 3176 -4055 1855 4086 9870 1103 5203 10669 -10927 1796 -7141 -1137 -4301 423 -9757 3042 5450 4745 3737 2840 -798 5843 4466 -4224 1512 -11266 2623 -3699 5475 -2797 813 -4574 -6071 -3548 852 1095 619 2010 10067 5908 2732 6158 -3803 312 5104 7377 9393 -3788 3871 2345 -3465 -2291 1165 1011 -16896 2220 -5578 253 -2740 -3573 -267 8588 5999 8190 2211 -4935 -9381 5588 -3166 -1000 -5413 3516 1141 -910 3899 -2083 5369 -2246 226 -9239 1305 -1089 3304 6125 4514 -4367 -745 3674 4130 2147 2678 -11736 8081 792 -4081 7691 2289 -6051 -8455 6163 5876 3879 -8828 2642 473 6096 2995 223 -3882 6507 -4991 1613 -9 -6808 174 4635 -2396 3001 -675 4874 -3506 -4124 -224 1726 1444 -15745 36 1757 4015 SO 20190822T104032.0Z 7173.444815 170 1 32.01 2 88.99 74.56 32.73 192.59 0.00 1 0.00 1 0 15 3.076e-02 3.082e-02 2.738e-02 2.709e-02 1.071535e+04 1.857852e+03 5.910774e+02 -6.000000e+00 1.621788e+03 286.90 -2.00 20.00 -2.00 505.28 0.00e+00 2.637488e-03 7.369219e-04 1.298771e-04 -6.000000e+00 8.526554e-04 286.90 -2.00 20.00 -2.00 500.14 0.00e+00 1.879441e+00 5.368915e-01 9.484384e-02 -6.000000e+00 5.971426e-01 231.29 -2.00 3.57 -2.00 501.77 0.00e+00 18.516 0.124 489.00 513.00 1 8.9321e+00 4.1073e-02 3.2289e-02 -6.0000e+00 4.5580e-02 9.7018e-02 1.0712e-02 2.5854e-03 -6.0000e+00 1.2231e-02 1.6045e-05 5.1174e-03 2.0022e-03 6.2881e-05 -6.0000e+00 2.4040e-03 -1.2800e-02 -3.2508e-05 12 8 8 10 0 0 1.04 14.99 2.46 -0.01280 0.02270 8 1 1 4 0 4000.000 22.09 14.99 19.08 900000 -2392 -3121 4270 -994 -139 2310 596 -5282 3921 -3444 312 2231 1875 -324 -3675 258 392 -1561 1637 -731 -1187 1467 -8146 3092 -1116 -1156 -7 2860 3067 4159 -4360 1600 1740 2484 750 1669 -2267 1368 -1515 -711 222 -522 3460 -1114 3394 -3622 3324 82 -751 -1456 -1041 2515 746 3043 1009 -3647 -1560 4110 6225 5179 -1662 2554 1495 -120 -50 727 -2441 -1413 -2557 2185 -806 3192 -9289 6717 -4474 -3552 -546 -1484 -950 -635 -491 -1066 234 2237 1902 731 3488 -5173 6300 -2072 -2399 1426 4500 -1161 -2618 -4838 138 -3426 1309 2198 5936 -1661 5916 487 1289 859 4155 2585 -3447 3462 -5281 1523 -647 289 -3872 -2181 2764 4200 -3240 619 -4426 -260 3162 944 -2797 418 5609 2016 3736 4276 2942 -510 4502 556 -687 -5422 -3667 -1702 -146 -7575 1269 -4226 -1338 1692 5020 842 611 -3261 2816 900000 -2303 -3133 4166 -1049 -148 2457 653 -6130 4101 -3791 328 2263 1875 -327 -3842 262 408 -1714 1770 -806 -1315 1581 -9666 3320 -1253 -1292 -8 2994 3061 3985 -4545 1601 1813 2679 830 1805 -2508 1442 -1623 -756 235 -565 3653 -1245 3649 -4149 3511 88 -793 -1495 -1033 2367 716 2945 1037 -4025 -1702 4233 6230 5221 -1805 2676 1580 -128 -52 739 -2519 -1430 -2574 2066 -786 3023 -10086 6338 -4673 -3580 -521 -1412 -892 -594 -463 -1015 221 2104 1812 703 3243 -5183 5623 -2013 -2373 1387 4250 -1128 -2494 -4552 120 -3012 1074 1769 4674 -1466 5145 466 1232 815 3738 2327 -3316 3182 -5366 1461 -637 282 -3938 -2213 2716 4062 -3309 595 -4356 -243 2882 889 -2734 397 5056 1871 3428 3885 2638 -464 3877 496 -632 -5382 -3636 -1675 -143 -8073 1245 -4401 -1360 1668 4764 816 576 -3118 2532 SO 20190822T104444.0Z 7173.447732 174 1 32.01 2 88.26 75.28 32.89 194.43 0.00 1 0.00 1 0 15 2.186e-02 2.184e-02 2.242e-02 2.217e-02 1.066330e+04 1.538287e+03 6.945818e+02 -6.000000e+00 1.152609e+03 286.90 -2.00 20.00 -2.00 505.24 0.00e+00 2.222069e-03 6.015730e-04 1.307747e-04 -6.000000e+00 6.059669e-04 286.90 -2.00 20.00 -2.00 500.01 0.00e+00 1.360947e+00 4.439450e-01 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