File name: Pandora103s1_Downsview_20191118_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T063025.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191118_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191118T122238.0Z 7261.515718 236 1 32.01 2 89.75 117.40 35.84 239.38 0.00 1 0.00 1 0 29 3.066e-02 3.019e-02 2.745e-02 2.697e-02 7.726821e+03 1.620395e+03 5.430107e+02 -6.000000e+00 1.552111e+03 276.81 -2.00 20.00 -2.00 505.56 0.00e+00 8.044910e-03 7.265728e-04 3.857939e-04 -6.000000e+00 8.285058e-04 276.81 -2.00 20.00 -2.00 501.51 0.00e+00 2.483491e+00 4.989315e-01 8.702610e-02 -6.000000e+00 5.896301e-01 222.52 -2.00 3.57 -2.00 502.93 0.00e+00 20.299 0.163 489.00 513.00 1 8.6182e+00 3.7988e-02 3.8356e-02 -6.0000e+00 4.4935e-02 -6.0880e-02 9.6470e-03 2.5834e-03 -6.0000e+00 1.1984e-02 1.5417e-05 1.9176e-03 2.0586e-03 1.2605e-04 -6.0000e+00 2.3911e-03 4.6916e-02 -2.7921e-04 12 8 8 10 0 0 37.26 15.00 3.33 0.04692 0.06022 8 1 1 4 0 4000.000 21.69 15.00 18.42 -4313 -8848 -2053 -5062 1509 -2367 -303 -586 890 -352 404 -262 2898 -3487 721 -4648 -3883 793 1348 1722 1535 -1114 1170 4904 751 2412 -2741 -1585 -706 3481 -776 218 -6223 8907 2545 -1123 4214 -2986 2307 3475 5438 -4101 490 1923 3452 3547 214 1658 -526 -1659 2569 -3673 4 -3634 1298 -1677 2911 5168 778 -2176 1116 -601 1939 2137 -635 227 -767 2093 6822 937 3095 -471 1600 1895 -1768 -887 -4531 -1301 -7211 -1928 -6344 -859 495 -1561 3177 -3961 -838 -4638 6138 245 -2606 1804 5132 -776 3071 -315 4679 -1726 488 -3626 -719 -5110 -1733 -2386 98 967 -259 822 329 -2795 1819 2966 1975 2946 -389 3989 2881 2615 1960 3629 -4493 1951 -3278 -1945 927 4186 -1443 4112 57 762 3010 -1520 3742 -6526 -4908 -902 1723 3803 1335 -4653 408 -265 636 1059 2868 -1874 2527 -3818 -3111 -4477 -3368 -7353 -1663 -4424 1275 -2121 -273 -536 802 -317 353 -227 2409 -3039 599 -4074 -3417 684 1196 1546 1377 -1027 1058 4308 697 2225 -2660 -1518 -657 2974 -672 188 -5821 7525 2391 -1105 3892 -2921 2125 3148 4868 -4091 477 1883 3393 3518 219 1659 -531 -1661 2393 -3542 4 -3483 1227 -1703 2914 5123 805 -2310 1149 -637 2021 2227 -676 236 -790 2069 6388 915 2917 -461 1551 1861 -1829 -906 -4675 -1273 -7406 -1873 -6435 -833 476 -1536 3024 -4076 -835 -4758 5621 237 -2609 1765 5003 -810 3041 -314 4336 -1656 448 -3375 -641 -4802 -1631 -2382 99 972 -260 804 321 -2853 1828 3020 2068 3097 -425 4212 3123 2883 2171 3894 -5123 2051 -3601 -2143 1009 4438 -1627 4400 63 849 3278 -1692 3888 -7439 -5492 -989 1899 4183 1523 -5709 481 -315 755 1261 3364 -2292 2906 -4531 -3584 -5229 SO 20191118T122648.0Z 7261.518611 240 1 32.01 2 89.09 118.12 36.48 240.57 0.00 1 0.00 1 0 15 6.753e-02 6.674e-02 6.414e-02 6.321e-02 1.050575e+04 4.152141e+03 4.052479e+02 -6.000000e+00 3.418903e+03 276.81 -2.00 20.00 -2.00 505.44 0.00e+00 2.069181e-03 1.679899e-03 1.473679e-04 -6.000000e+00 1.824911e-03 276.81 -2.00 20.00 -2.00 500.71 0.00e+00 2.562714e+00 1.211610e+00 1.399391e-01 -6.000000e+00 1.298712e+00 222.52 -2.00 3.57 -2.00 502.29 0.00e+00 19.003 0.134 489.00 513.00 1 9.7391e+00 9.2355e-02 3.4469e-02 -6.0000e+00 9.8974e-02 1.0071e-02 2.3731e-02 3.1358e-03 -6.0000e+00 2.6394e-02 6.4087e-06 -3.5577e-03 4.6983e-03 6.5626e-05 -6.0000e+00 5.2664e-03 1.9674e-02 -1.1172e-04 12 8 8 10 0 0 3.13 15.00 2.75 0.01967 -0.00500 8 1 1 4 0 4000.000 21.69 15.00 18.43 -3559 2182 2045 -5521 8746 -8155 2859 -363 705 -5282 -7223 12391 2807 2878 8624 -3843 -5105 9703 6811 -5623 -4642 -4646 -9929 -9212 -4449 7092 3923 1359 3323 10991 -4548 -4323 -1355 5223 3033 -10967 1105 5672 -6420 2222 15397 16385 4844 2547 6838 -3037 8318 -213 2619 653 -576 -6452 654 -539 10424 -6133 -3156 2101 -7029 5872 -2909 -5924 7721 7960 4205 -9843 5372 -4696 3888 5223 -4734 10048 -3642 -3515 4575 5348 1056 6271 1203 4609 -7008 -8989 -8798 -8052 15000 -3136 2664 502 17108 -1789 12075 -666 -6934 -14467 -3690 -987 12740 -584 64 8328 -622 2342 -5727 11977 3694 2422 1979 6302 -5267 10387 -6894 977 6054 4027 8867 -3902 -7147 1098 4561 -4493 7498 -7279 1520 -15719 3060 675 6308 3902 12895 -8312 361 -7436 4146 4828 -1437 3141 -7168 8270 1305 10373 3031 -9262 401 1298 3055 -10652 -9184 5031 4033 6359 -3122 1824 1765 -5359 7651 -8577 2767 -369 714 -5626 -7692 10775 2649 2668 7482 -3758 -5096 8576 6411 -6129 -5020 -5026 -11313 -10440 -4858 6977 3971 1407 3334 9843 -4558 -4300 -1326 4969 3094 -13098 1164 5629 -7080 2226 13530 14354 4805 2620 6848 -3376 8279 -228 2686 670 -580 -6656 616 -511 9094 -6548 -3383 2174 -7957 5825 -3127 -6600 7597 7828 4272 -11306 5216 -4943 3729 4884 -4791 8785 -3668 -3588 4398 5120 1032 5671 1126 4142 -7030 -9261 -9121 -8324 12562 -3178 2559 490 14108 -1763 10418 -658 -7439 -16875 -3807 -960 10493 -530 57 6619 -530 1955 -5345 9971 3518 2382 1945 5838 -5362 9091 -7281 975 5814 3968 8353 -4166 -7970 1153 4660 -4953 7207 -7888 1484 -18240 3007 682 6050 3841 11575 -9203 369 -8040 3917 4499 -1418 3002 -7816 7944 1358 10044 3193 -11063 439 1418 3291 -13084 -10980 5107 4026 6153 SO 20191118T123105.1Z 7261.521587 244 1 32.16 2 88.41 118.87 37.15 241.77 0.00 1 0.00 1 0 43 1.147e-01 1.076e-01 9.565e-02 9.246e-02 -1.978213e+03 5.046947e+03 3.918416e+01 -6.000000e+00 5.806021e+03 276.81 -2.00 20.00 -2.00 505.29 0.00e+00 -1.074181e-03 2.479026e-03 1.732057e-04 -6.000000e+00 3.096705e-03 276.81 -2.00 20.00 -2.00 500.01 0.00e+00 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