File name: Pandora103s1_Downsview_20191122_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T062951.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191122_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191122 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191122T122747.0Z 7265.519294 372 1 32.01 2 89.75 118.74 44.64 153.85 0.00 1 0.00 1 0 15 4.287e-02 4.218e-02 4.059e-02 4.001e-02 4.893883e+03 2.444540e+03 2.521267e+02 -6.000000e+00 2.166630e+03 276.35 -2.00 20.00 -2.00 505.24 0.00e+00 1.947420e-03 1.053501e-03 8.531804e-05 -6.000000e+00 1.157263e-03 276.35 -2.00 20.00 -2.00 499.97 0.00e+00 2.744709e+00 7.854488e-01 5.884758e-02 -6.000000e+00 8.245549e-01 222.47 -2.00 3.57 -2.00 501.62 0.00e+00 20.307 0.163 489.00 513.00 1 9.0939e+00 5.9941e-02 3.6786e-02 -6.0000e+00 6.2832e-02 1.2014e-01 1.5687e-02 2.3001e-03 -6.0000e+00 1.6754e-02 1.0224e-05 4.5489e-03 2.9803e-03 4.3732e-05 -6.0000e+00 3.3432e-03 1.0408e-02 -4.3333e-05 12 8 8 10 0 0 -0.68 15.00 3.17 0.01041 0.04196 8 1 1 4 0 4000.000 21.69 15.00 18.53 2262 10459 -5543 -255 -5891 -1764 -6981 252 -4063 8250 -1973 -2761 -4877 4624 2750 4125 1239 6641 -5678 1983 1117 -539 -1320 -5062 -1642 -4377 10312 4126 -1776 -2192 603 3999 -1926 1695 -445 -249 2914 3032 9825 1052 2693 -828 571 -2216 -752 -1772 1009 8771 -336 1151 -6243 -517 -7095 -1769 264 -2208 3052 963 424 571 -912 313 9564 -1411 -1825 4898 -280 89 461 -2912 1988 -6556 5997 979 3587 -7899 4744 -615 -4275 -3198 -1001 824 -941 942 6579 -6702 1755 7743 5000 3763 -6617 880 8244 1848 -5042 2941 -6096 3003 -2856 6078 1224 -570 -7053 1460 -139 3684 198 -6685 -850 -6272 4197 -3267 4898 -1598 312 -3668 3186 4445 -986 -5776 5763 -3091 8831 133 4878 480 -3962 5230 5884 1339 4864 187 2211 909 -1571 5112 -8012 -1923 -2550 8537 -557 2366 5687 1351 -7608 -4179 -5306 -2465 -834 -1168 2101 9123 -5864 -267 -6677 -1957 -8329 284 -4756 8429 -2184 -3045 -5401 4593 2758 4089 1279 6688 -6659 2186 1236 -606 -1495 -5963 -1887 -5170 10505 4438 -1970 -2329 609 3918 -2039 1811 -504 -283 3155 3230 9658 1114 2808 -900 619 -2502 -847 -2020 1111 8823 -363 1195 -6715 -510 -7342 -1749 264 -2354 3164 1025 451 602 -973 332 9319 -1526 -1961 4837 -284 88 454 -2907 1864 -6701 5480 955 3455 -8412 4343 -579 -4131 -3040 -933 762 -887 876 5876 -6859 1651 6827 4501 3426 -6693 841 7481 1786 -5104 2684 -5914 2590 -2539 4833 1012 -487 -6674 1340 -133 3394 185 -6548 -777 -6106 3768 -3206 4492 -1572 302 -3702 3040 4220 -978 -5887 5144 -2947 7453 124 4369 448 -3870 4651 5182 1241 4323 170 1931 796 -1405 4374 -8023 -1845 -2492 7579 -543 2245 5259 1310 -8059 -4249 -5328 -2330 -758 -1065 SO 20191122T123154.0Z 7265.522153 376 1 32.01 2 89.10 119.46 44.34 155.22 0.00 1 0.00 1 0 15 1.872e-02 1.861e-02 1.982e-02 1.963e-02 3.867090e+03 1.171897e+03 3.090847e+02 -6.000000e+00 9.460282e+02 276.35 -2.00 20.00 -2.00 505.23 0.00e+00 1.999311e-03 5.179437e-04 1.085272e-04 -6.000000e+00 5.052755e-04 276.35 -2.00 20.00 -2.00 500.01 0.00e+00 1.599955e+00 3.866909e-01 2.651607e-02 -6.000000e+00 3.601085e-01 222.47 -2.00 3.57 -2.00 501.65 0.00e+00 19.045 0.135 489.00 513.00 1 8.6227e+00 2.9477e-02 3.2793e-02 -6.0000e+00 2.7439e-02 1.3359e-01 7.7979e-03 1.8908e-03 -6.0000e+00 7.3193e-03 2.1324e-05 6.7658e-04 1.4800e-03 4.4794e-05 -6.0000e+00 1.4595e-03 6.9138e-03 -4.9676e-05 12 8 8 10 0 0 2.91 14.99 1.79 0.00691 0.01161 8 1 1 4 0 4000.000 21.79 14.99 18.54 -2480 -276 -2302 140 -3399 904 233 2676 3433 923 1480 -1307 830 -2374 1109 -637 3816 -246 1038 30 4623 -2148 -803 1095 -1488 -2823 -2976 1922 -1600 1403 -2294 -291 -3585 1404 -889 1886 827 2258 525 -614 -1180 -1490 -1161 4356 941 2498 -1025 171 -1062 -311 -336 -2193 -2662 91 319 703 -256 -805 260 764 1430 -159 626 -855 420 -602 331 2101 564 -340 -973 -1282 -658 1611 3655 2856 417 2545 -4492 -449 -2707 1485 -2996 471 -562 4223 589 -1764 151 -890 342 1002 683 363 -1581 162 670 2801 2692 -2496 512 -3759 1743 -595 1042 -708 -1976 382 3046 -486 2844 919 -2928 325 -2464 3396 1796 1106 -393 -2147 -1246 -1844 -558 321 -2384 756 1409 -1667 -3016 -1170 4336 -325 1625 -491 780 -288 -921 -2919 -1657 570 -1973 1710 3098 110 1750 -342 2853 177 -1454 -837 -2412 -265 -2332 145 -3735 970 257 2925 3729 1014 1584 -1419 870 -2520 1125 -657 3802 -261 1124 34 4912 -2435 -897 1202 -1688 -3254 -3418 2096 -1772 1443 -2364 -294 -3788 1469 -994 2077 908 2406 561 -655 -1263 -1609 -1264 4551 1029 2704 -1143 186 -1151 -327 -341 -2196 -2625 87 314 717 -271 -865 276 800 1483 -169 661 -917 442 -628 336 2057 555 -333 -939 -1242 -639 1554 3514 2757 402 2341 -4370 -417 -2571 1368 -2898 442 -539 3908 565 -1721 144 -855 326 960 671 361 -1578 156 624 2484 2325 -2209 434 -3352 1521 -559 998 -691 -1920 355 2711 -450 2600 871 -2921 317 -2476 3231 1750 1093 -392 -2138 -1205 -1758 -520 299 -2305 709 1313 -1595 -2907 -1113 3901 -299 1435 -437 680 -257 -853 -2810 -1594 542 -1935 1620 2910 107 1679 -333 2641 163 -1320 -750 SO 20191122T123552.0Z 7265.524907 380 1 32.01 2 88.48 120.15 44.07 156.55 0.00 1 0.00 1 0 15 1.643e-02 1.642e-02 1.345e-02 1.333e-02 4.081748e+03 7.927553e+02 2.441298e+02 -6.000000e+00 8.304493e+02 276.35 -2.00 20.00 -2.00 505.25 0.00e+00 1.815883e-03 3.518115e-04 8.349086e-05 -6.000000e+00 4.435750e-04 276.35 -2.00 20.00 -2.00 500.06 0.00e+00 1.777386e+00 2.607954e-01 4.143727e-02 -6.000000e+00 3.160009e-01 222.47 -2.00 3.57 -2.00 501.71 0.00e+00 17.455 0.104 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