File name: Pandora103s1_Downsview_20191124_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T063029.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191124_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191124T123016.0Z 7267.521019 446 1 32.01 2 89.76 119.36 65.44 132.86 0.00 1 0.00 1 0 15 1.814e-02 1.798e-02 1.556e-02 1.547e-02 4.880502e+02 8.095815e+02 4.995713e+01 -6.000000e+00 9.161605e+02 276.13 -2.00 20.00 -2.00 505.27 0.00e+00 2.355882e-03 4.080323e-04 9.907431e-05 -6.000000e+00 4.895061e-04 276.13 -2.00 20.00 -2.00 500.21 0.00e+00 2.320645e+00 2.990017e-01 1.558927e-02 -6.000000e+00 3.491586e-01 222.45 -2.00 3.57 -2.00 501.85 0.00e+00 20.317 0.163 489.00 513.00 1 8.1458e+00 2.2799e-02 3.6575e-02 -6.0000e+00 2.6601e-02 1.0900e-01 6.0518e-03 2.0049e-03 -6.0000e+00 7.0987e-03 2.7327e-05 8.9796e-04 1.1838e-03 2.6334e-05 -6.0000e+00 1.4146e-03 2.3097e-02 -1.6809e-04 12 8 8 10 0 0 -6.08 15.00 2.84 0.02310 0.02933 8 1 1 4 0 4000.000 21.58 15.00 18.30 -2714 -3274 -2893 2554 -2367 268 -1010 449 -1254 3537 -2080 -104 1799 -733 59 -2830 -776 1618 49 -726 -2200 464 1271 -570 -574 -675 -2102 -780 1611 -2031 -1552 2494 1305 736 2799 605 3279 294 2569 256 -9 -1232 1074 -1519 -797 754 -717 2328 1293 2826 -2003 335 -906 1254 -1122 -301 -650 787 -1519 1830 1242 700 1937 3061 -1605 1827 -752 384 -287 1407 -17 -971 2259 -619 -215 -638 2389 -2625 445 -3467 -791 2123 1456 -2710 375 -4065 940 2250 -204 916 2388 1406 2089 2037 293 954 -1035 2506 -797 1559 -4741 -1084 195 859 1084 -62 -775 270 -4045 891 118 2915 716 749 408 2021 53 -513 4126 -3729 -312 -1583 1213 -1271 -651 -881 1960 1164 -1838 1314 -665 -2855 -2245 1059 72 -1131 -414 -1118 -1431 534 972 -3908 -1892 1371 -1491 5683 413 51 -1279 -1735 -2564 -3146 -2861 2502 -2502 281 -1096 487 -1387 3689 -2243 -108 1820 -746 59 -2908 -789 1646 52 -796 -2439 502 1362 -623 -632 -747 -2348 -857 1698 -2121 -1560 2410 1295 763 2971 664 3463 314 2655 267 -10 -1311 1131 -1661 -877 822 -789 2457 1356 2858 -2052 325 -872 1182 -1112 -308 -686 828 -1631 1887 1283 731 2012 3143 -1712 1854 -767 381 -284 1347 -16 -934 2126 -608 -214 -635 2254 -2534 412 -3319 -738 1948 1351 -2623 357 -4073 898 2114 -196 869 2242 1351 2039 2013 291 929 -1010 2304 -735 1368 -4355 -969 177 811 1053 -61 -749 253 -3884 820 112 2741 700 741 407 1996 54 -525 3997 -3824 -304 -1539 1138 -1235 -636 -861 1865 1113 -1801 1257 -647 -2780 -2126 957 65 -1047 -393 -1090 -1417 525 954 -4019 -1919 1358 -1524 5402 404 48 -1196 -1618 SO 20191124T123427.0Z 7267.523924 450 1 32.01 2 89.10 120.08 64.92 133.81 0.00 1 0.00 1 0 15 1.220e-02 1.207e-02 8.555e-03 8.522e-03 2.011351e+03 4.707603e+02 1.357818e+02 -6.000000e+00 6.160055e+02 276.13 -2.00 20.00 -2.00 505.30 0.00e+00 2.012123e-03 2.250112e-04 9.265210e-05 -6.000000e+00 3.291309e-04 276.13 -2.00 20.00 -2.00 500.38 0.00e+00 2.014496e+00 1.636745e-01 2.380131e-02 -6.000000e+00 2.346773e-01 222.45 -2.00 3.57 -2.00 501.99 0.00e+00 19.043 0.135 489.00 513.00 1 7.7204e+00 1.2474e-02 3.2756e-02 -6.0000e+00 1.7881e-02 8.2355e-02 3.2882e-03 1.8373e-03 -6.0000e+00 4.7686e-03 5.1188e-05 1.5269e-03 6.4918e-04 3.0095e-05 -6.0000e+00 9.5132e-04 6.2868e-03 -2.5149e-05 12 8 8 10 0 0 7.84 14.99 1.19 0.00629 0.01688 8 1 1 4 0 4000.000 21.58 14.99 18.31 -2325 -2284 -1694 -3381 526 -322 613 770 78 -2 373 -611 -73 28 -1685 -864 -587 1113 523 1237 454 -315 -17 -452 -1386 1489 -1105 218 -917 114 -289 -896 -776 1341 1079 1868 393 236 2090 -253 -195 318 2219 -164 919 1148 2010 -655 1182 -2298 -525 -2310 -803 -1710 719 863 650 1038 -96 707 969 1368 946 1441 40 504 254 1478 -591 -209 -2734 889 -532 -844 -1383 1487 398 781 -584 -1307 -1546 -767 -321 -265 1259 -1212 1118 77 1805 -17 2729 -1712 1339 -790 1523 -1036 1912 -426 -603 806 -725 -1511 -1828 78 803 -301 -693 13 -1679 2137 -905 662 -735 1334 983 1752 849 1473 -1047 1494 -1617 401 -1251 -352 758 90 1243 1679 614 -262 -826 -599 280 -1912 -2143 -2122 1819 -2262 115 -384 1029 -233 -248 56 1385 240 887 -1538 -1813 -1793 -2142 -2129 -1624 -3435 529 -332 642 815 83 -2 385 -628 -74 28 -1681 -856 -586 1120 547 1308 483 -337 -18 -485 -1513 1588 -1202 234 -972 114 -283 -884 -777 1370 1151 1998 421 250 2143 -262 -202 329 2288 -175 984 1232 2131 -703 1228 -2413 -524 -2277 -766 -1649 698 869 673 1082 -100 732 998 1414 987 1496 42 515 255 1447 -585 -203 -2676 842 -516 -833 -1395 1453 383 732 -549 -1231 -1462 -727 -305 -252 1197 -1191 1075 74 1712 -16 2578 -1710 1328 -806 1504 -1028 1810 -402 -555 714 -643 -1365 -1710 75 791 -299 -679 13 -1603 1983 -882 648 -740 1331 989 1756 865 1499 -1083 1482 -1623 388 -1221 -345 742 88 1212 1625 598 -259 -818 -579 263 -1813 -2022 -2031 1729 -2278 115 -389 1033 -237 -253 57 1410 245 885 -1521 -1750 -1723 SO 20191124T123831.0Z 7267.526748 454 1 32.01 2 88.47 120.80 64.42 134.74 0.00 1 0.00 1 0 29 1.121e-02 1.096e-02 2.710e-03 2.701e-03 3.786964e+03 1.488456e+02 2.595972e+02 -6.000000e+00 5.658272e+02 276.13 -2.00 20.00 -2.00 505.34 0.00e+00 3.331973e-03 7.147226e-05 1.630838e-04 -6.000000e+00 3.023173e-04 276.13 -2.00 20.00 -2.00 500.94 0.00e+00 1.483245e+00 5.008395e-02 4.207376e-02 -6.000000e+00 2.155798e-01 222.45 -2.00 3.57 -2.00 502.44 0.00e+00 17.420 0.103 489.00 513.00 1 6.6688e+00 3.8009e-03 2.8813e-02 -6.0000e+00 1.6425e-02 8.8602e-04 9.9954e-04 1.7403e-03 -6.0000e+00 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