File name: Pandora103s1_Downsview_20191130_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T063020.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191130_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191130T123723.0Z 7273.525961 521 1 32.01 2 89.77 120.98 127.02 87.37 0.00 1 0.00 1 0 29 5.479e-02 5.406e-02 4.953e-02 4.876e-02 5.048417e+03 2.969598e+03 4.115783e+02 -6.000000e+00 2.760139e+03 275.45 -2.00 20.00 -2.00 505.24 0.00e+00 9.423569e-04 1.296510e-03 3.892579e-05 -6.000000e+00 1.476080e-03 275.45 -2.00 20.00 -2.00 499.96 0.00e+00 1.215204e+00 9.639155e-01 1.998761e-02 -6.000000e+00 1.054397e+00 222.37 -2.00 3.57 -2.00 501.62 0.00e+00 20.346 0.164 489.00 513.00 1 9.4230e+00 7.3431e-02 3.6603e-02 -6.0000e+00 8.0324e-02 1.5512e-01 1.9525e-02 2.1019e-03 -6.0000e+00 2.1416e-02 8.3140e-06 -1.2435e-02 3.6293e-03 4.8817e-05 -6.0000e+00 4.2702e-03 -9.2812e-02 5.8290e-04 12 8 8 10 0 0 -4.75 15.00 2.53 -0.09281 -0.17907 8 1 1 4 0 4000.000 21.58 15.00 18.34 -1213 1102 -4290 9727 -6430 -64 -8302 -4074 7800 3710 -5236 2930 -4391 1644 -10258 3288 -1592 2626 -4505 -1389 2432 3946 5477 -8138 293 -6162 1836 -3306 4346 -4691 2351 -2006 12878 -10299 1728 6586 10514 8470 7089 7725 1981 -9363 6418 -739 -1146 -1373 -4685 -3787 -1423 7606 -2769 4391 -6413 547 1455 5677 -3687 6791 2044 -190 -2589 -3347 6045 -215 3318 -1615 7695 1869 2730 -490 2987 6557 2799 -3870 12087 -2766 2669 -6987 1407 -3663 5051 10229 -3936 -5060 4295 480 3446 779 -5761 -2190 -3499 4160 9057 6059 -1231 10264 -3662 3568 -2201 4280 1041 -7042 1629 2591 5631 5407 3941 2215 -420 -3468 7488 -5019 -4738 946 9373 -3079 726 -13335 2521 -1685 -10978 -2384 10067 -9971 4426 -4431 -2472 3549 15557 -1819 -3050 -2543 2060 6820 -4390 -6466 4338 -4107 -3247 -900 -211 1074 -3201 13656 -2672 660 -3828 -2687 2272 -2273 -1193 1043 -4346 8907 -7177 -69 -9858 -4744 8188 4049 -6144 3114 -4952 1719 -11842 3296 -1673 2680 -5063 -1567 2677 4272 5831 -9872 328 -7405 2042 -3845 4665 -5363 2395 -2075 11552 -11778 1835 6944 10727 8672 7249 7738 2073 -10919 6471 -807 -1272 -1543 -5458 -4342 -1571 7559 -2967 4235 -6664 521 1380 5342 -3948 6731 2139 -202 -2793 -3630 6026 -228 3405 -1723 7362 1853 2646 -485 2809 5873 2606 -3885 10566 -2835 2571 -7190 1305 -3529 4447 8583 -3830 -4999 3894 458 3225 748 -5863 -2142 -3463 3839 8089 5684 -1241 9061 -3606 3186 -2019 3590 879 -6384 1379 2261 5035 4999 3687 2072 -395 -3304 6471 -4995 -4774 911 8363 -3102 707 -15040 2455 -1694 -11845 -2316 8483 -10125 3955 -4346 -2374 3216 12481 -1719 -2933 -2414 1823 5653 -4015 -6007 3702 -3918 -3121 -855 -202 1017 -3166 11531 -2657 635 -3819 -2590 2018 -2060 SO 20191130T124114.1Z 7273.528635 525 1 32.17 2 89.17 121.65 126.35 88.03 0.00 1 0.00 1 0 22 3.269e-02 3.231e-02 3.186e-02 3.148e-02 -1.008841e+03 1.685002e+03 5.768671e+01 -6.000000e+00 1.646512e+03 275.45 -2.00 20.00 -2.00 505.24 0.00e+00 2.429314e-03 8.274776e-04 1.035530e-04 -6.000000e+00 8.805875e-04 275.45 -2.00 20.00 -2.00 499.97 0.00e+00 3.219731e+00 6.189072e-01 4.061863e-02 -6.000000e+00 6.292385e-01 222.37 -2.00 3.57 -2.00 501.63 0.00e+00 19.220 0.138 489.00 513.00 1 8.9731e+00 4.7213e-02 3.3331e-02 -6.0000e+00 4.7931e-02 1.1396e-01 1.2484e-02 1.9086e-03 -6.0000e+00 1.2788e-02 1.3053e-05 1.1676e-03 2.3900e-03 2.6175e-05 -6.0000e+00 2.5491e-03 6.8684e-03 -4.8829e-05 12 8 8 10 0 0 5.72 15.00 3.50 0.00687 0.01497 8 1 1 4 0 4000.000 21.69 15.00 18.35 -2091 -5677 2717 -4761 -1302 -543 -1827 1583 -3508 2174 -8691 3980 -5158 3630 -2710 3564 700 750 2485 -208 -2309 3030 -223 -613 1062 -2557 5837 1410 618 -4174 1846 755 1141 -619 2090 -2562 -991 3477 468 3592 -884 -761 3965 1853 -107 5547 -271 1810 172 392 1855 1267 -2567 482 -2701 -438 -268 2353 978 625 -4295 1300 306 -2988 -1445 701 1037 -6334 5533 1022 2268 -1512 1004 -69 4849 1136 -2270 1509 4267 -2545 2036 1278 -3036 260 4121 7992 3082 -3245 -3426 1045 3552 -16 -2327 5682 -2911 5050 7256 707 -2436 6028 -6812 308 -5173 -684 4639 -2234 726 362 -6640 5877 -35 -2430 5974 1512 1048 -4047 -1333 -6062 -1301 527 3990 -1602 1382 -1795 -1343 -356 5838 274 -2072 4069 2046 -638 -3325 -1264 -1762 149 -1277 809 -4610 1857 880 855 1878 3986 -4047 5052 -5429 2812 322 -10033 -2030 -5775 2633 -5182 -1409 -594 -2069 1759 -4099 2370 -10318 4126 -5755 3651 -2870 3547 723 794 2672 -233 -2640 3287 -249 -689 1184 -2965 6207 1558 675 -4559 1840 759 1161 -666 2288 -2967 -1115 3685 504 3703 -950 -822 4138 1999 -119 5872 -302 1950 185 412 1853 1232 -2539 462 -2749 -453 -284 2460 1033 656 -4711 1359 325 -3266 -1543 720 1040 -6706 5164 980 2110 -1458 953 -68 4568 1104 -2222 1387 3776 -2392 1832 1170 -2911 242 3730 7025 2840 -3167 -3338 975 3248 -15 -2335 5337 -2949 4670 6472 655 -2258 5000 -6304 268 -4878 -645 4262 -2177 673 329 -6356 5012 -32 -2344 5411 1451 1017 -4141 -1335 -6362 -1290 503 3622 -1513 1259 -1709 -1284 -337 5205 257 -1981 3688 1888 -592 -3095 -1135 -1573 132 -1185 752 -4572 1747 838 814 1780 3732 -4116 4683 -5454 2517 286 -9811 SO 20191130T124502.0Z 7273.531273 529 1 32.01 2 88.59 122.32 125.70 88.67 0.00 1 0.00 1 0 22 2.344e-02 2.296e-02 2.121e-02 2.100e-02 2.481365e+03 1.200296e+03 2.197349e+02 -6.000000e+00 1.180023e+03 275.45 -2.00 20.00 -2.00 505.24 0.00e+00 1.704821e-03 5.519657e-04 6.130957e-05 -6.000000e+00 6.311542e-04 275.45 -2.00 20.00 -2.00 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