File name: Pandora103s1_Downsview_20191205_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T065509.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191205_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191205T124248.0Z 7278.529722 493 1 32.01 2 89.77 122.07 142.42 10.42 0.00 1 0.00 1 0 29 5.909e-02 5.826e-02 5.745e-02 5.639e-02 3.882278e+03 3.402655e+03 4.518433e+02 -6.000000e+00 2.969568e+03 274.88 -2.00 20.00 -2.00 505.21 0.00e+00 6.535567e-03 1.485904e-03 2.407132e-04 -6.000000e+00 1.589790e-03 274.88 -2.00 20.00 -2.00 499.84 0.00e+00 7.851026e-01 1.128755e+00 3.661457e-02 -6.000000e+00 1.138063e+00 222.31 -2.00 3.57 -2.00 501.50 0.00e+00 20.370 0.165 489.00 513.00 1 9.5258e+00 8.6031e-02 3.7173e-02 -6.0000e+00 8.6667e-02 1.8963e-01 2.2606e-02 2.1151e-03 -6.0000e+00 2.3138e-02 7.1426e-06 1.3457e-02 4.2404e-03 8.4387e-05 -6.0000e+00 4.6067e-03 -1.3638e-02 3.9911e-05 12 8 8 10 0 0 -3.16 15.00 4.76 -0.01364 0.07970 8 1 1 4 0 4000.000 21.69 15.00 18.45 -10351 -1568 -4537 3709 -1636 -925 -395 2685 -11361 8069 -7432 8960 -7495 6320 -12340 2888 453 4044 3088 -1452 9391 -5778 -729 3399 -2041 154 4370 -7435 4734 -3375 -952 -4013 14640 -299 10315 -1889 8753 961 4555 -4285 7655 648 -2483 -3850 904 7187 -4787 5588 -5480 -1653 -9243 -643 1928 9134 -2278 16827 243 3509 6651 -10127 -4499 6233 5277 -2039 3246 -982 -353 -3147 2451 -1976 4683 -3836 9386 -6166 5008 2867 1932 11151 3528 -316 -3180 -5646 4120 6739 4492 5945 7188 8035 -1081 13831 -5884 614 -2730 12916 -8851 -1438 3667 7377 5314 -1825 417 9125 -9727 2347 1366 7744 2508 4472 -7713 -11303 -6801 -4315 2453 -1138 5809 -7783 7208 -4266 57 4825 -6090 1404 180 -3995 9103 -6101 -3561 781 -1062 2554 -2100 4523 -3316 2258 -7515 -157 -6948 -3257 848 3531 -3599 1938 -2157 13624 555 -792 -5263 -3890 -6257 4831 -11313 -1615 -5018 3924 -1856 -1062 -458 3033 -14550 8353 -8771 8884 -8549 6207 -14435 2924 476 4230 3335 -1639 9480 -6761 -812 3665 -2339 173 4677 -8812 4791 -3535 -962 -4216 13223 -327 10421 -2130 8756 1022 4620 -4718 7570 695 -2789 -4451 1009 7542 -5590 5810 -6226 -1756 -10212 -638 1854 8360 -2420 15363 265 3711 6784 -12090 -5107 6427 5500 -2270 3383 -1044 -366 -3311 2409 -1987 4377 -3921 8533 -6626 4844 2773 1834 9514 3221 -298 -3099 -5669 3758 6028 4147 5413 6419 7052 -1031 11420 -5942 596 -2791 11290 -9363 -1384 3271 6163 4400 -1581 352 7216 -9628 2149 1272 6680 2230 3827 -7432 -11519 -6789 -4282 2312 -1119 5349 -8231 6644 -4386 55 4371 -6011 1267 165 -3873 7790 -6051 -3445 720 -998 2321 -1958 3851 -2998 1910 -7005 -140 -6748 -3082 779 3174 -3464 1768 -2056 11164 515 -731 -4912 -3460 -5610 3924 SO 20191205T124639.0Z 7278.532396 497 1 32.01 2 89.19 122.74 142.28 11.91 0.00 1 0.00 1 0 15 4.560e-02 4.452e-02 4.263e-02 4.196e-02 -6.762898e+02 2.253756e+03 3.220671e+02 -6.000000e+00 2.291521e+03 274.88 -2.00 20.00 -2.00 505.22 0.00e+00 4.988496e-03 1.102388e-03 2.517138e-04 -6.000000e+00 1.226674e-03 274.88 -2.00 20.00 -2.00 499.89 0.00e+00 3.752317e+00 8.319363e-01 6.158021e-02 -6.000000e+00 8.781465e-01 222.31 -2.00 3.57 -2.00 501.55 0.00e+00 19.263 0.139 489.00 513.00 1 9.1884e+00 6.3452e-02 3.4025e-02 -6.0000e+00 6.6874e-02 1.1384e-01 1.6798e-02 1.9388e-03 -6.0000e+00 1.7853e-02 9.6873e-06 -1.6022e-03 3.1643e-03 7.2830e-05 -6.0000e+00 3.5555e-03 1.3691e-02 -1.1643e-04 12 8 8 10 0 0 91.94 15.00 3.16 0.01369 0.00258 8 1 1 4 0 4000.000 21.69 15.00 18.46 -40 -5952 1141 -2688 4937 -3617 -3893 -380 -487 -3394 3084 2639 -8709 5328 -4389 4047 -3434 2940 3469 -1413 -3459 2570 -1706 -3717 -5311 -1741 7766 11106 463 4079 143 1428 -1874 4602 -866 1158 -564 198 285 1732 -981 -37 -2732 697 9849 2650 1702 1601 3342 5134 -7758 -3124 3617 1226 -5468 -6725 -1157 236 -3077 2661 86 7647 -2127 4018 -6002 4960 -3887 1102 4046 -1836 -3585 1543 1501 6500 4255 1787 -5133 5499 8249 2626 -943 2951 3385 -4835 -1304 -9235 9258 -599 5167 -6715 9629 -3647 431 -1999 4653 -6023 -7168 1685 4283 -3766 -963 5471 11948 -1054 852 3225 -5511 7657 467 -449 -7788 930 3308 5112 -7228 2906 935 117 9 -439 -470 -5054 -942 5491 2178 5518 3230 6096 -872 -4734 11617 -6493 2394 -1189 784 -9186 -144 -6956 -1542 -6042 2615 3930 4487 5 1474 5588 -1619 -3835 -8679 2526 -38 -6116 1129 -2883 5076 -4115 -4539 -434 -559 -3956 3301 2793 -10145 5313 -4752 4021 -3694 3031 3672 -1602 -3993 2791 -1930 -4291 -6284 -2004 8125 11201 510 4154 146 1426 -1955 4664 -969 1294 -633 217 308 1822 -1058 -40 -3057 765 10032 2917 1887 1755 3543 5240 -8686 -3233 3428 1184 -5765 -7469 -1254 256 -3440 2790 92 7632 -2350 4176 -6829 4989 -4168 1105 3896 -1843 -3585 1460 1431 5970 4058 1745 -5234 4917 7078 2364 -877 2662 3052 -4717 -1238 -9547 7985 -565 4583 -6675 8181 -3564 415 -2004 4359 -6174 -7325 1543 3710 -3421 -833 4446 9306 -969 792 2919 -5320 6358 409 -398 -7575 850 3021 4669 -7514 2749 906 114 9 -420 -443 -4905 -871 4817 1999 4906 2939 5392 -821 -4655 9761 -6386 2110 -1067 682 -8853 -130 -6911 -1472 -6084 2431 3600 4101 5 1405 5109 -1559 -3644 -8364 2159 SO 20191205T125027.0Z 7278.535035 501 1 32.01 2 88.61 123.40 142.13 13.37 0.00 1 0.00 1 0 15 3.809e-02 3.771e-02 3.545e-02 3.493e-02 4.112601e+03 2.089539e+03 2.380149e+02 -6.000000e+00 1.913868e+03 274.88 -2.00 20.00 -2.00 505.21 0.00e+00 3.927579e-03 9.166171e-04 1.927073e-04 -6.000000e+00 1.024490e-03 274.88 -2.00 20.00 -2.00 499.88 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