File name: Pandora103s1_Downsview_20191225_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T065449.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v7d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191225_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191225T125719.0Z 7298.539803 516 1 32.01 2 89.77 123.62 84.50 129.28 0.00 1 0.00 1 0 22 1.855e-01 1.545e-01 1.727e-01 1.592e-01 2.699277e+04 1.248335e+04 2.145560e+03 -6.000000e+00 9.257309e+03 273.10 -2.00 20.00 -2.00 505.24 0.00e+00 2.577063e-03 4.141489e-03 1.325982e-04 -6.000000e+00 4.968129e-03 273.10 -2.00 20.00 -2.00 499.69 0.00e+00 -2.676080e+00 3.195733e+00 7.813202e-02 -6.000000e+00 3.576867e+00 222.56 -2.00 3.57 -2.00 501.32 0.00e+00 20.409 0.166 489.00 513.00 1 1.0856e+01 2.4030e-01 3.7641e-02 -6.0000e+00 2.7222e-01 2.3893e-01 6.4306e-02 3.6106e-03 -6.0000e+00 7.2700e-02 2.3988e-06 4.9417e-03 1.0555e-02 1.9687e-04 -6.0000e+00 1.4463e-02 1.1548e-02 -9.5638e-05 12 8 8 10 0 0 2.23 15.00 11.06 0.01155 0.04583 8 1 1 4 0 4000.000 21.48 15.00 18.20 526 21170 11694 36212 -7166 -16755 -13579 13128 6349 17843 -21495 13973 -12531 -9636 11410 -16016 22416 14671 5251 -1634 16673 -737 13830 7905 -5611 12980 31847 -18720 23351 35632 -2079 9601 2451 70 -10556 -11308 3925 9428 8576 -1190 -22112 -2633 -3488 4149 3623 24226 -21039 6473 -6399 -7099 -2020 -10905 -8296 21400 -26 -15764 6293 9881 17726 -4701 -3451 -11644 44443 7148 16777 2681 30851 -18342 26925 -7041 5550 -22228 64187 -15123 14587 1001 5575 21889 18369 13706 -9701 10580 20870 27650 6036 7033 -24901 13681 -12668 24667 -4996 31623 -15285 -10470 18399 22339 1723 -4261 10514 75376 -12871 -9281 5712 -3440 24309 -5867 -12019 -7284 30454 -24952 -1265 -9311 -1893 13339 5351 -6127 12454 50942 45413 18531 -9331 -4053 5238 3733 -5112 -7566 8216 63 -9023 -15432 2887 -16932 -25920 24029 -4378 17722 -15582 40213 -7505 1016 21056 30686 -7706 -6187 1804 18088 14224 -12685 5960 23437 534 17913 11217 28589 -8771 -22872 -18342 13843 7122 17612 -30316 13827 -15710 -11536 11044 -20168 19709 14243 5757 -1934 16463 -860 13974 8472 -6899 13356 27190 -25807 20923 27084 -2208 9141 2545 78 -13461 -14580 4303 9657 8734 -1316 -29960 -2979 -4030 4515 4010 22081 -29469 6859 -7548 -8226 -2152 -12287 -8972 17537 -27 -19824 6557 10022 16623 -5425 -3934 -14479 32474 7453 15815 2840 24448 -22967 21639 -7710 5315 -27891 35631 -18216 13386 1036 5369 17588 15074 11636 -10268 9280 16687 20918 5722 6670 -31952 11954 -13989 18860 -5094 23089 -17746 -11420 14464 15932 1414 -3576 7548 28715 -11230 -8008 4527 -3221 18533 -6108 -13224 -7507 21559 -30315 -1247 -9980 -1874 11307 4844 -6195 10813 31580 29863 15441 -9798 -3886 4484 3261 -4915 -7459 6987 58 -8932 -16281 2523 -17293 -28402 16352 -3920 13149 -16271 24758 -7350 935 16180 21641 -7853 -6173 1653 14028 11243 -12658 4883 16232 SO 20191225T130120.0Z 7298.542593 520 1 32.01 2 89.17 124.32 83.96 130.01 0.00 1 0.00 1 0 22 1.263e-01 1.155e-01 1.198e-01 1.150e-01 7.220732e+03 7.447664e+03 2.006030e+02 -6.000000e+00 6.300725e+03 273.10 -2.00 20.00 -2.00 505.21 0.00e+00 -2.269465e-03 3.055156e-03 1.268457e-04 -6.000000e+00 3.381567e-03 273.10 -2.00 20.00 -2.00 499.89 0.00e+00 -6.322508e-01 2.301625e+00 1.015856e-01 -6.000000e+00 2.433465e+00 222.56 -2.00 3.57 -2.00 501.57 0.00e+00 19.265 0.139 489.00 513.00 1 1.0639e+01 1.7531e-01 3.4232e-02 -6.0000e+00 1.8522e-01 1.8207e-01 4.6121e-02 2.5178e-03 -6.0000e+00 4.9430e-02 3.3877e-06 -1.5677e-03 8.4477e-03 5.8833e-05 -6.0000e+00 9.8477e-03 2.7223e-02 -1.3702e-04 12 8 8 10 0 0 15.90 14.99 1.64 0.02722 0.01635 8 1 1 4 0 4000.000 21.48 14.99 18.21 8887 -15355 32015 8974 6448 3833 15217 -11576 1843 -9807 5813 -7642 -4743 -4498 -14438 -13543 11602 3795 -1292 10888 1088 -5225 -4143 7067 -9658 -1388 8976 243 10123 2328 2125 11717 -7968 9457 5335 10354 -6500 4591 4054 -4401 9837 6252 -11007 -697 5247 4414 2022 -2584 5595 -16319 380 -5401 935 -13475 9845 -6040 16561 25858 5271 -6152 -1046 -7781 3090 -5064 23324 13818 4523 3374 -14498 17137 7175 -6144 6287 -2181 11979 20383 -1310 2585 2827 6147 -374 8218 27 -32493 -2102 -20821 17763 -1708 11490 -4838 8418 6055 201 -7208 6071 -15562 32366 1414 21448 -5396 26417 -2466 -1840 -14960 6556 16045 -12296 2078 28619 28604 9805 11292 -20399 -3077 -15174 34049 1225 15522 9716 9254 8131 -11940 8135 17385 11280 -18299 747 -7976 -7767 -13850 2088 7134 9349 -2090 -2736 -6969 5394 24927 -1176 7682 11266 21830 -7061 -21714 -5265 4987 -5648 2821 46583 -9553 7949 -17480 23801 8668 6563 4068 14798 -14805 2077 -12247 6127 -9063 -5392 -5008 -17489 -16238 11015 3978 -1473 11277 1237 -6315 -4941 7554 -12190 -1619 9407 276 10257 2435 2151 10782 -8977 9344 5734 10753 -7844 4897 4282 -4965 9616 6338 -13277 -768 5518 4695 2191 -2886 5678 -20003 383 -5563 886 -14620 8752 -6510 14775 21332 5289 -6830 -1099 -8773 3156 -5594 19500 12463 4371 3244 -16408 14116 6397 -6225 5711 -2187 10675 16753 -1295 2398 2582 5407 -350 7163 26 -42570 -2088 -25138 14846 -1717 10129 -4984 7654 5692 203 -7871 5711 -17479 22270 1269 15494 -4931 17594 -2196 -1689 -16520 6173 13952 -13889 2001 20921 20875 8698 10003 -24668 -3153 -17436 24363 1211 13543 8952 8415 7304 -12687 7002 13757 9554 -20554 697 -8062 -7767 -14708 1899 6035 7570 -1868 -2444 -6566 4652 18186 -1114 6767 9662 16969 -7279 -25892 -5362 4578 -5646 2523 26667 -9263 SO 20191225T130508.0Z 7298.545232 524 1 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