File name: Pandora103s1_Downsview_20191228_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T065436.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v7d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20191228_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20191228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191228T125813.0Z 7301.540428 520 1 32.01 2 89.77 123.45 109.14 102.60 0.00 1 0.00 1 0 15 7.879e-02 7.482e-02 7.364e-02 7.202e-02 4.336222e+03 4.237957e+03 5.318457e+02 -6.000000e+00 3.929062e+03 272.91 -2.00 20.00 -2.00 505.15 0.00e+00 3.028999e-03 1.862735e-03 2.036456e-04 -6.000000e+00 2.109148e-03 272.91 -2.00 20.00 -2.00 499.92 0.00e+00 1.660820e-01 1.423185e+00 3.694072e-02 -6.000000e+00 1.519470e+00 222.68 -2.00 3.57 -2.00 501.55 0.00e+00 20.412 0.166 489.00 513.00 1 9.8724e+00 1.0849e-01 3.7064e-02 -6.0000e+00 1.1564e-01 1.8831e-01 2.8816e-02 2.0357e-03 -6.0000e+00 3.0879e-02 5.5266e-06 5.0635e-03 5.4655e-03 7.5499e-05 -6.0000e+00 6.1420e-03 -1.7728e-02 8.7252e-05 12 8 8 10 0 0 89.27 15.00 7.22 -0.01773 0.01740 8 1 1 4 0 4000.000 21.58 15.00 18.32 -8091 2817 774 18706 2580 2813 -8175 6730 -7609 -1304 2529 23310 6769 1856 -162 -4622 10186 -2047 -8148 -1700 11195 5092 -2490 -5585 -6989 -3663 3001 2024 5164 -6653 4671 7578 3007 -5103 -4238 -1344 16490 -381 -482 -4710 -12060 9173 -7373 2436 -1677 449 4577 9629 4629 11201 -3719 10378 -4235 11212 -11207 6257 15312 -4520 -2245 -14532 9183 -769 998 6657 -7181 -9675 -2105 -9947 1921 -6164 6156 -15332 4624 -3187 5724 413 9392 5703 40 4194 3045 -9842 -6992 1689 139 2431 -1177 3285 -1708 -8564 7932 16547 -6372 4736 6654 2663 6660 -594 -7511 -1165 -5867 -4162 -1238 2980 -2108 -9731 2429 -3077 3486 -5705 17025 2906 -4012 -12781 1676 -6169 25443 -4173 -1724 7659 1983 470 4105 -4140 8520 3603 4697 -194 5008 3188 -8798 10268 -297 9340 -12519 21287 4483 12643 3228 22295 4132 -656 2126 -4759 -5468 -2850 -14799 2332 7293 -5963 -8522 2710 787 16657 2752 3045 -10054 7235 -9379 -1485 2718 20212 6771 1912 -168 -5021 9682 -2247 -9794 -1943 11225 5415 -2844 -6589 -8429 -4283 3271 2212 5335 -7353 4499 7114 3005 -5762 -4932 -1528 15512 -416 -519 -5228 -14390 8976 -8583 2613 -1895 499 4854 9582 4755 10528 -3900 9214 -4260 9771 -12537 6143 14107 -5085 -2462 -17812 8927 -830 1063 6703 -8194 -11103 -2199 -11047 1882 -6421 5606 -17246 4330 -3273 5464 412 8344 5130 37 3771 2774 -10262 -7113 1587 134 2314 -1158 3077 -1669 -8938 7086 13826 -6796 4551 6161 2503 5870 -546 -7180 -1020 -5323 -3764 -1128 2740 -2095 -10364 2258 -2952 3096 -5598 13685 2724 -4073 -14231 1624 -6470 19820 -4355 -1739 6909 1851 436 3647 -4033 7392 3272 4221 -182 4439 2890 -8883 8392 -264 7454 -12275 15308 3900 10319 2914 16894 3743 -622 1972 -4737 -5478 -2759 -15690 2022 5873 -5450 SO 20191228T130205.0Z 7301.543113 524 1 32.01 2 89.19 124.12 108.48 103.20 0.00 1 0.00 1 0 15 4.496e-02 4.396e-02 5.237e-02 5.147e-02 -1.191285e+03 2.721321e+03 1.212865e+02 -6.000000e+00 2.242130e+03 272.91 -2.00 20.00 -2.00 505.20 0.00e+00 2.821443e-03 1.346390e-03 8.275033e-05 -6.000000e+00 1.203829e-03 272.91 -2.00 20.00 -2.00 499.84 0.00e+00 3.509401e+00 1.020132e+00 1.722910e-02 -6.000000e+00 8.674388e-01 222.68 -2.00 3.57 -2.00 501.50 0.00e+00 19.316 0.140 489.00 513.00 1 9.4501e+00 7.7853e-02 3.3398e-02 -6.0000e+00 6.6009e-02 1.2355e-01 2.0690e-02 1.8647e-03 -6.0000e+00 1.7638e-02 7.8131e-06 2.9310e-03 3.8975e-03 2.8154e-05 -6.0000e+00 3.5052e-03 -1.8843e-03 -4.6784e-05 12 8 8 10 0 0 1.09 15.00 2.83 -0.00188 0.01845 8 1 1 4 0 4000.000 21.58 15.00 18.32 -2800 -740 -3005 -2615 -1251 -558 1413 3220 -2613 2298 5242 -2854 9314 1623 208 -1743 -3067 3807 1063 -993 591 1149 260 -3005 2467 -6490 1500 7727 -3617 4430 1239 1702 1653 219 2019 -627 -623 -1117 -2281 -139 -4426 -2957 -2910 3091 -5371 -3432 5110 -7350 5090 -1872 1163 490 6197 -1830 1186 -5803 5159 3818 1145 -1326 2343 873 -3757 9536 6423 -1700 2995 -4340 -6798 392 5885 5110 3435 951 -3468 2310 -13321 -5293 1839 512 8200 -462 -703 -3159 -2816 1654 4075 10004 3470 973 8853 10259 -6425 3111 -1173 -3285 -2587 -6547 5022 864 3193 8538 -4742 -1409 1893 6590 -6078 -6995 1010 1943 2485 -10667 7886 -217 -4707 -2384 1982 1526 -8941 5253 6258 -368 5384 1308 -2417 3263 -7045 2613 -4457 5147 7855 -659 -1125 2374 -5357 -1667 -940 -38 7641 -1995 3595 -5352 -455 -4240 7316 4758 -99 -5086 6955 -3591 -2786 -730 -3137 -2839 -1377 -621 1577 3578 -3073 2540 5514 -3206 9150 1688 217 -1852 -3332 3961 1174 -1138 664 1283 292 -3495 2745 -7904 1683 8116 -4152 4491 1254 1714 1692 237 2236 -720 -704 -1248 -2543 -150 -4965 -3292 -3277 3325 -6350 -4000 5450 -8722 5261 -2022 1177 483 5669 -1810 1171 -6379 5234 3958 1214 -1427 2423 922 -4165 9270 6380 -1794 2954 -4519 -7169 379 5294 4628 3188 917 -3543 2218 -14496 -5192 1664 466 6937 -429 -657 -3025 -2715 1539 3697 8530 3139 903 7634 8839 -6663 2975 -1161 -3271 -2521 -6462 4295 747 2660 6800 -4416 -1324 1765 5814 -5935 -6733 885 1701 2210 -11009 6930 -209 -4774 -2373 1900 1469 -9414 4724 5484 -339 4661 1193 -2307 2944 -7028 2366 -4307 4560 6758 -603 -1012 2030 -4888 -1486 -857 -35 6631 -1920 3285 -5329 -434 -4233 6556 4349 -92 -4828 5700 -3243 SO 20191228T130551.1Z 7301.545730 528 1 32.19 2 88.63 124.78 107.84 103.77 0.00 1 0.00 1 0 36 4.340e-02 4.294e-02 4.325e-02 4.266e-02 2.348535e+03 2.404853e+03 6.798263e+01 -6.000000e+00 2.164082e+03 272.91 -2.00 20.00 -2.00 505.19 0.00e+00 5.904476e-04 1.114155e-03 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