File name: Pandora103s1_Downsview_20200112_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T072050.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v7d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20200112_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20200112T125709.0Z 7316.539688 243 1 32.01 2 89.76 121.04 76.32 283.00 0.00 1 0.00 1 0 20 1.219e-01 1.149e-01 1.143e-01 1.099e-01 1.069091e+04 7.250792e+03 7.213570e+02 -6.000000e+00 6.053929e+03 271.98 -2.00 20.00 -2.00 505.26 0.00e+00 -1.683606e-03 2.859672e-03 1.229045e-04 -6.000000e+00 3.256147e-03 271.98 -2.00 20.00 -2.00 499.95 0.00e+00 4.966183e-01 2.193987e+00 8.150514e-02 -6.000000e+00 2.360754e+00 223.28 -2.00 3.57 -2.00 501.61 0.00e+00 20.402 0.165 489.00 513.00 1 1.0340e+01 1.6533e-01 3.7351e-02 -6.0000e+00 1.7941e-01 1.5691e-01 4.4877e-02 2.7443e-03 -6.0000e+00 4.8262e-02 3.5509e-06 -4.2898e-03 8.0396e-03 6.8658e-05 -6.0000e+00 9.5144e-03 3.5740e-02 -3.2925e-04 12 8 8 10 0 0 -7.26 15.00 1.99 0.03574 0.00598 8 1 1 4 0 4000.000 21.58 15.00 18.29 900000 -11643 1766 -9931 15225 -10320 -540 5766 8901 -3032 -4603 364 3223 21195 10165 -10189 8631 -3351 5730 4872 7229 6867 8411 964 13343 -6078 -1599 6207 -14828 13447 -8210 6972 -19986 9867 6197 -10885 -8989 12280 -17823 13887 -974 1416 14509 -299 -11382 13888 -2961 -5666 726 4692 13444 -18571 6185 -9573 3979 8544 1307 -4889 19398 4157 -13562 13049 -6417 10588 3129 22884 -3544 12187 -17886 14266 -12488 2952 13047 -7402 1860 -6943 12378 14283 -5029 6625 27580 10301 5210 5846 17506 -4680 22308 -15496 13800 4287 -741 -7013 -4423 -4479 17956 1008 15213 -21716 8757 1231 8811 6147 28859 1717 8556 -9919 -17293 6664 -226 3443 887 -4277 3093 1615 6463 11724 -7312 -791 -21612 19601 2551 40358 -7218 3259 -2975 8925 -5206 -3024 -3638 -4107 21275 -23765 13991 -8121 -1080 -27872 17682 -10239 -8841 11031 10023 -3194 -6567 -9957 7816 21882 18689 12437 34466 3373 900000 -12589 1719 -11260 14022 -12388 -602 6169 9307 -3540 -5359 398 3392 18429 9692 -11769 8362 -3714 6017 5310 7734 7363 8875 1091 13447 -7423 -1861 6665 -19300 12849 -9261 6718 -25204 9595 6541 -13914 -11209 12260 -23464 13252 -1063 1509 13734 -330 -14114 13584 -3401 -6605 782 4776 12195 -22120 5653 -10076 3730 7972 1351 -5457 17167 4226 -16229 12108 -7233 10147 3211 19179 -3752 10883 -21111 12218 -13587 2750 11116 -7783 1824 -7467 10858 11951 -4977 5809 19695 8740 4688 5257 14255 -4800 17761 -17705 11818 4002 -726 -7349 -4600 -4708 14950 953 12107 -23797 6967 1031 6742 4849 18893 1542 7643 -10895 -20357 6124 -217 3162 846 -4350 2950 1564 5959 10242 -7721 -798 -26917 16240 2435 26123 -7194 2925 -2870 7705 -5140 -2922 -3509 -3971 16184 -27397 10925 -7754 -958 -32218 13572 -10535 -9076 9482 8812 -3207 -6848 -10785 7142 17425 15173 10461 22816 2961 SO 20200112T130125.0Z 7316.542651 247 1 32.01 2 89.10 121.78 77.05 283.66 0.00 1 0.00 1 0 15 6.951e-02 6.762e-02 5.733e-02 5.622e-02 1.123791e+04 3.722931e+03 5.792298e+02 -6.000000e+00 3.453537e+03 271.98 -2.00 20.00 -2.00 505.20 0.00e+00 2.691921e-03 1.477335e-03 1.449483e-04 -6.000000e+00 1.856558e-03 271.98 -2.00 20.00 -2.00 499.95 0.00e+00 -4.148786e-01 1.122141e+00 1.185397e-01 -6.000000e+00 1.342736e+00 223.28 -2.00 3.57 -2.00 501.59 0.00e+00 19.110 0.136 489.00 513.00 1 9.8374e+00 8.5415e-02 3.4209e-02 -6.0000e+00 1.0214e-01 1.7317e-01 2.2450e-02 2.9511e-03 -6.0000e+00 2.7305e-02 7.1368e-06 -3.8471e-03 4.0511e-03 7.7442e-05 -6.0000e+00 5.4192e-03 1.6292e-02 -1.6170e-04 12 8 8 10 0 0 -8.51 15.00 5.11 0.01629 -0.01039 8 1 1 4 0 4000.000 21.58 15.00 18.30 -4228 343 -7728 -4949 3146 8710 -469 1427 -8285 4727 -14793 1802 -2066 2188 400 10011 -5686 5479 -7301 17063 1952 3654 -1259 5375 -2138 -3271 9245 -6785 2959 -3148 -5218 -5695 13333 -4064 8980 -5965 3311 1249 11850 -4386 4332 -3862 6165 -1061 445 5543 -2988 -7650 5480 3780 -8360 9516 -3132 9328 -7830 568 1496 4360 -1654 19262 -966 6662 718 6594 -8876 -5388 3232 11836 4275 -5847 5651 407 12196 -14594 -3444 513 9707 -2551 -2006 -5088 7969 -2681 14142 369 -5616 5648 3923 -1609 576 -2249 -2764 3157 1627 -6023 -6383 7490 -9612 16665 -5399 2311 -5276 1872 -1100 3987 -6979 3555 1995 6462 -1072 828 7157 -7780 12328 1338 1815 3989 11277 -11308 950 -11862 7173 642 16031 -1500 14218 427 -2075 -11691 -505 -2676 4532 10689 -404 8956 -4028 -939 -7475 -803 -4743 4058 -6311 12644 -5034 7629 -2584 7782 -10338 3572 -10133 -169 -4268 331 -8296 -5391 3276 8753 -526 1597 -10241 5101 -18889 1926 -2262 2253 413 9369 -6228 5480 -8533 16140 2139 3927 -1417 5666 -2440 -3799 9474 -8088 3169 -3439 -5571 -6046 11875 -4418 9016 -7094 3567 1350 11399 -4872 4395 -4264 6244 -1167 489 5852 -3426 -9079 5636 3879 -9357 8647 -3142 8230 -8314 579 1562 4502 -1814 17113 -1038 6676 769 6677 -10408 -6025 3255 10760 4140 -6169 5235 395 10617 -16700 -3600 518 8796 -2531 -1947 -5045 6928 -2600 11736 351 -5726 5237 3710 -1597 554 -2206 -2726 2967 1584 -6395 -6692 6629 -9692 12568 -4910 1906 -4590 1522 -948 3453 -7109 3344 1896 5780 -1010 763 6317 -8086 10638 1290 1740 3737 9927 -12619 948 -13234 6499 603 12665 -1404 11577 398 -1985 -12282 -472 -2552 4040 8793 -361 7209 -3653 -831 -7248 -745 -4615 3670 -6382 10669 -5060 6803 -2542 6892 -10761 3161 -9936 -148 SO 20200112T130535.0Z 7316.545544 251 1 32.01 2 88.46 122.51 77.76 284.30 0.00 1 0.00 1 0 15 2.772e-02 2.746e-02 2.997e-02 2.962e-02 5.009288e+03 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