File name: Pandora103s1_Downsview_20200222_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T073837.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v7d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20200222_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200222T125158.1Z 7357.536089 483 1 50.19 2 83.04 111.46 82.85 124.35 0.00 1 0.00 1 0 25 4.610e-01 2.296e-02 4.128e-01 1.869e-02 1.018028e+00 1.134358e-02 1.080330e-02 -6.000000e+00 2.755842e-01 224.92 -2.00 3.57 -2.00 322.43 0.00e+00 5.976913e-03 6.105236e-03 2.479389e-03 -6.000000e+00 1.243728e-02 272.35 -2.00 20.00 -2.00 322.01 0.00e+00 7.578 0.008 302.00 328.00 3 1.3568e+00 4.1513e-02 9.3797e-02 -6.0000e+00 6.8209e-01 1.4227e+00 5.5166e-02 6.0831e-02 -6.0000e+00 7.4534e-01 -1.7674e+00 5.0723e-02 3.1577e-02 -6.0000e+00 4.3941e-01 6.9385e-01 2.4421e-02 1.0181e-02 -6.0000e+00 1.8314e-01 2.6624e-05 -2.3272e-03 5.2996e-04 1.5724e-04 -6.0000e+00 1.4622e-02 1.3303e-02 0.0000e+00 12 8 8 10 0 0 49.97 15.00 0.47 0.01330 -0.00418 45 8 1 5 0 1115.070 21.48 15.00 18.15 900000 178452 -54943 900000 900000 59234 -121892 900000 -82626 14555 -71262 -88275 -64666 42615 900000 -8107 67921 106381 189900 -23055 47431 -32912 -15848 -109540 22435 17958 -68994 -671 900000 -39093 -10967 58016 -3385 21542 84336 11895 179330 75194 32188 61816 -11017 125868 36121 100002 53070 48616 3404 5490 23378 90241 -12824 52133 69145 74608 45192 41783 198 57356 -4959 -3906 30210 23887 21094 7606 22867 12603 -982 455 39465 12898 21427 6037 14249 8773 12087 1082 -10235 -11907 -4606 15220 -3943 6421 64 6752 5836 5197 8438 5155 -3199 167 930 -5588 -8734 3149 -6300 -162 -4647 -5441 -1574 -3957 -754 -3338 1240 -1609 -5797 -1419 -2030 -1148 184 -139 -707 236 1788 -2397 472 555 1642 -634 728 -1293 939 1813 1163 -226 1510 807 1715 5138 -1149 -1282 -270 1205 807 74 -557 -173 891 419 -937 -271 -433 468 -1252 900000 3250 -1584 900000 900000 1079 -4439 900000 -2189 265 -1770 -3069 -2248 776 900000 -268 1237 1937 3458 -916 864 -1253 -498 -8886 483 386 -3312 -16 900000 -1553 -399 1249 -146 713 1536 394 3266 1780 1226 2139 -766 2521 1615 2549 2126 2036 208 345 1316 3122 -1253 2934 3903 4212 3217 3113 22 3760 -517 -388 2421 2056 2130 982 2688 1669 -153 75 4965 2349 3795 1249 2571 1510 1781 161 -1677 -2168 -923 3023 -1123 1881 22 2303 2106 1970 3199 2031 -1334 64 336 -2082 -3441 1225 -3181 -92 -3270 -4414 -1329 -3419 -583 -2354 768 -1020 -4021 -1001 -1542 -956 174 -153 -889 318 2447 -3401 636 740 2211 -912 1073 -1951 1332 2405 1484 -285 1822 957 2046 6549 -1826 -2379 -558 2676 1945 195 -1561 -503 2594 1218 -2695 -730 -1072 1063 -2834 SS 20200222T130209.3Z 7357.543163 486 1 50.58 2 81.34 113.31 81.37 126.20 0.00 1 0.00 1 0 25 5.963e-01 1.390e-02 3.040e-01 6.128e-03 8.821075e-01 3.646992e-03 9.491207e-03 -6.000000e+00 3.553034e-01 224.92 -2.00 3.57 -2.00 322.22 0.00e+00 1.555553e-02 2.040382e-03 3.705821e-03 -6.000000e+00 1.646730e-02 272.35 -2.00 20.00 -2.00 321.80 0.00e+00 6.273 0.005 302.00 328.00 3 1.3772e+00 1.3375e-02 8.5396e-02 -6.0000e+00 8.7894e-01 5.1300e-01 2.0688e-02 7.2613e-02 -6.0000e+00 9.6073e-01 -6.9522e-01 2.3219e-02 2.8643e-02 -6.0000e+00 5.6896e-01 2.8531e-01 1.0527e-02 1.4697e-02 -6.0000e+00 2.3629e-01 1.1633e-04 -1.8794e-03 1.8504e-04 1.8825e-04 -6.0000e+00 1.8467e-02 1.3005e-02 0.0000e+00 12 8 8 10 0 0 29.89 14.99 0.30 0.01301 -0.00112 109 20 1 5 0 463.950 21.48 14.99 18.16 900000 -267858 -137091 -221468 900000 -270411 14224 -196108 20279 -243564 900000 -187947 -120203 -145102 -35639 -77821 -63872 900000 21168 -23021 -24702 128632 -104196 900000 -18446 21988 -82353 9540 -108099 -31044 -26021 29720 -14011 12997 -13501 31367 27131 20136 41224 36403 16474 -501 43180 -10989 54576 29483 35444 2205 54375 23996 23010 15957 24328 26388 20151 11587 19197 -1253 5036 6098 14693 23437 11112 13878 9327 14817 8341 15512 5199 6001 2658 2718 1619 32 -3948 1928 -5471 1349 -1097 2671 2640 1826 -1132 -1972 18 891 -62 -1783 2948 -1851 1567 -1557 -519 -3805 1716 -3037 -37 -2724 -907 -1327 -26 390 810 -1220 -2680 -1697 -1778 15 86 1280 -1157 -606 -242 146 -308 1145 315 1008 -1322 -62 840 2103 371 347 147 -157 1857 1025 -550 -544 44 380 1067 124 -350 -130 623 -371 -606 -365 269 -516 125 900000 -5331 -819 -2645 900000 -4575 85 -1810 121 -3834 900000 -2448 -1109 -2363 -251 -1014 -832 900000 138 -237 -255 768 -2319 900000 -180 143 -1520 72 -2934 -472 -480 387 -319 233 -308 460 457 426 828 869 528 -20 1195 -543 1452 1056 1270 118 1889 1250 1361 1135 1743 1977 1674 1069 1636 -128 470 566 1340 2226 1266 1733 1299 1991 1224 2285 957 1227 602 623 361 7 -772 326 -983 247 -243 690 805 639 -447 -837 8 409 -30 -888 1376 -868 673 -662 -220 -1831 913 -2017 -28 -2415 -851 -1247 -22 298 572 -882 -2067 -1376 -1541 14 91 1533 -1583 -879 -355 209 -430 1552 440 1461 -2044 -96 1245 2925 503 457 188 -196 2296 1395 -877 -997 88 827 2473 311 -936 -361 1744 -1048 -1682 -962 653 -1179 280 SS 20200222T131649.3Z 7357.553348 491 1 50.53 2 78.93 116.04 79.31 128.93 0.00 1 0.00 1 0 25 5.017e-01 8.748e-03 1.112e-01 2.181e-03 7.381785e-01 1.225110e-03 8.250415e-03 -6.000000e+00 2.963426e-01 224.92 -2.00 3.57 -2.00 321.61 0.00e+00 1.034231e-02 6.043446e-04 9.541053e-04 -6.000000e+00 1.275739e-02 272.35 -2.00 20.00 -2.00 321.14 0.00e+00 5.027 0.002 302.00 328.00 3 1.1166e+00 4.0891e-03 6.4183e-02 -6.0000e+00 7.3298e-01 1.4936e-01 5.9252e-03 4.4403e-02 -6.0000e+00 7.9951e-01 -2.0906e-01 6.6590e-03 2.3026e-02 -6.0000e+00 4.7453e-01 8.3689e-02 3.1322e-03 1.3018e-02 -6.0000e+00 1.9633e-01 5.8182e-04 -1.2667e-03 6.6255e-05 1.5557e-04 -6.0000e+00 1.5428e-02 1.2583e-02 0.0000e+00 11 8 0 10 0 0 33.48 15.00 0.22 0.01258 0.00306 299 56 1 5 0 168.940 21.48 15.00 18.15 -183994 -178494 -190641 -143874 -173528 -117045 -206335 -122240 -197252 -129703 -160035 -84596 -93749 -37870 -68209 -32661 -34167 -33661 -49108 -15218 -22209 -7858 -16433 -24259 -33773 -42893 -25461 -43549 -16385 -18874 -13729 -11519 10801 -7208 4050 -5958 -3033 -6352 -4654 -1453 -3122 2783 3027 6321 1065 3057 4227 3569 4690 7782 4991 10110 6572 6757 5187 3242 87 3065 -16 4653 4689 5753 3829 4698 3849 4614 5341 4214 3904 1127 99 -1734 -547 -1553 -2008 -2777 -1135 -1441 -808 -1741 -227 -2609 -1218 -919 -418 -375 -472 -220 -207 73 191 -655 -900 -895 -677 -119 263 -269 -1076 -631 -190 1048 2131 -61 -2320 -943 -341 760 1122 570 -135 -205 -3 259 573 1533 674 397 -451 -1111 224 643 105 -615 -473 -198 1626 879 -702 -717 -610 308 634 463 -484 -384 444 -253 -859 -122 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