File name: Pandora103s1_Downsview_20200316_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T080346.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v8d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20200316_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200316 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200316T115957.0Z 7380.499965 317 1 49.96 2 84.96 96.87 67.81 187.65 0.00 1 0.00 1 0 25 5.367e-01 6.338e-02 4.518e-01 6.084e-02 1.162775e+00 3.616876e-02 1.283627e-02 -6.000000e+00 3.184291e-01 225.89 -2.00 3.57 -2.00 321.88 0.00e+00 -1.622182e-02 1.039311e-02 5.129990e-03 -6.000000e+00 1.394478e-02 274.08 -2.00 20.00 -2.00 321.24 0.00e+00 9.785 0.018 302.00 328.00 3 4.7883e-02 1.0849e-01 1.2024e-01 -6.0000e+00 7.8880e-01 2.7962e+00 1.2764e-01 8.5284e-02 -6.0000e+00 8.5967e-01 -2.5506e+00 7.8757e-02 3.1464e-02 -6.0000e+00 5.1033e-01 7.8444e-01 4.3565e-02 1.4295e-02 -6.0000e+00 2.1305e-01 7.2222e-06 -1.1969e-03 1.5133e-03 1.9164e-04 -6.0000e+00 1.6573e-02 1.0172e-02 0.0000e+00 12 8 8 10 0 0 -64.65 15.00 0.96 0.01017 0.00118 26 5 1 5 0 1921.250 21.69 15.00 18.43 900000 98996 151606 -8536 35913 -8127 17092 -17196 25913 -33871 -2983 -3100 19163 29141 193419 27966 287660 64203 97712 65627 -23474 900000 1679 123169 -29636 88367 154001 121628 -82877 3375 39313 7035 -42611 813 -27354 97030 -21500 49311 16037 88761 52763 72172 78040 -3937 46906 -34657 16561 -55995 18117 -45924 900000 -53419 95665 55817 79827 41005 59071 30845 -17350 -1177 80106 79183 53890 113793 61823 37375 692 40825 3660 68145 -5956 36343 5251 96180 -34416 39111 -45266 -8576 -2854 27129 6067 8429 10874 -7011 3899 7738 -1124 26468 -8715 -7967 26353 -27987 16332 -10227 12477 -172 8253 -1720 15232 3200 6485 -11692 144 -4673 -5672 -8289 2155 4015 -1710 1872 -445 8306 -3576 482 -1366 -1566 4724 3568 -3947 3850 -5601 7762 714 9261 -8143 -2584 2310 8250 -5881 -2908 -806 -478 -430 -727 1523 -2660 2015 113 1543 -3707 1028 1556 2505 900000 6849 8990 -1181 2662 -884 1520 -2294 2305 -5523 -368 -414 2273 3456 11470 3731 17058 5711 5794 4865 -3828 900000 207 7304 -5565 5240 9132 7212 -17610 346 3179 872 -8212 105 -4276 5754 -3245 4253 2248 6699 5973 6614 6311 -658 4299 -6726 1875 -13282 2149 -11141 900000 -16703 7220 6620 7746 5968 7006 4490 -3648 -190 5614 5976 5810 8097 6999 5440 149 6382 927 9919 -1894 7445 1359 9696 -10019 5334 -12689 -1803 -661 5557 1799 2772 3810 -3099 1597 3129 -503 8847 -3947 -3350 8126 -13126 5106 -4686 5381 -100 5161 -1345 10757 2519 4510 -8572 85 -2872 -3669 -5809 1452 2943 -1540 1908 -531 9896 -4992 648 -1833 -2086 6010 4770 -5852 5231 -7941 8996 847 9835 -10053 -2954 2578 9740 -9510 -5392 -1665 -1087 -1070 -1978 4344 -8246 6051 344 4508 -10732 2594 3607 5685 SS 20200316T121152.4Z 7380.508245 320 1 50.73 2 82.83 98.96 68.15 190.50 0.00 1 0.00 1 0 17 5.345e-01 1.858e-02 3.914e-01 9.861e-03 1.016611e+00 5.969368e-03 1.066570e-02 -6.000000e+00 3.182811e-01 225.89 -2.00 3.57 -2.00 322.56 0.00e+00 1.080745e-02 3.571302e-03 7.829762e-03 -6.000000e+00 1.377018e-02 274.08 -2.00 20.00 -2.00 322.15 0.00e+00 7.384 0.008 302.00 328.00 3 6.4744e-01 2.3413e-02 1.0687e-01 -6.0000e+00 7.8969e-01 1.0820e+00 3.3368e-02 9.6536e-02 -6.0000e+00 8.6167e-01 -1.4789e+00 3.3323e-02 3.9246e-02 -6.0000e+00 5.1139e-01 5.9567e-01 1.5253e-02 1.1664e-02 -6.0000e+00 2.1066e-01 7.1524e-05 -2.2845e-03 2.8050e-04 1.6539e-04 -6.0000e+00 1.6444e-02 8.7355e-03 0.0000e+00 12 8 8 10 0 0 -2.29 15.00 0.30 0.00874 -0.00843 120 22 1 5 0 422.670 21.69 15.00 18.43 -132057 -102856 -52594 105649 -179356 -142781 -183442 -44287 -176230 -159165 -36637 -70244 -13138 -30146 900000 -28954 9794 -35521 900000 54869 59704 -55744 32134 -105660 203078 -113587 34674 -380 20802 -75505 44153 -22487 23845 16112 -22539 -18789 12153 12123 14286 101002 -9146 53896 7796 214110 -6951 106799 19336 25659 19253 74455 13382 35052 24378 49826 29013 33153 34625 27942 35504 28773 37583 11121 36198 27036 44623 13643 45234 3704 32380 5024 23612 4520 20705 6420 14166 -12016 3320 -5125 5234 -456 5161 6191 1763 6002 2425 3698 -1159 6101 2919 7973 -3667 1136 -7437 194 -4041 -1230 -3371 -2520 -3436 -2691 -2237 -1499 350 -658 -3824 -4143 -2223 -2152 1714 -1864 367 -1260 -42 -2055 -193 84 672 -571 -76 87 1427 1656 1706 1251 1317 1058 1826 1457 -682 464 -218 978 -39 695 -204 327 206 432 -865 52 -306 -256 -1344 -2539 -1566 -506 1016 -4310 -2371 -4115 -426 -4004 -3060 -352 -737 -126 -369 900000 -506 128 -776 900000 527 574 -1315 309 -4063 1952 -4566 333 -5 218 -2441 540 -648 479 352 -689 -542 276 318 424 1553 -416 1366 320 2058 -334 1848 760 1009 875 2147 795 1869 1576 2656 1978 2202 2239 1856 2079 1760 2201 952 2784 2575 3822 1633 4072 547 4046 922 3838 897 3329 1083 1968 -1974 461 -851 933 -105 1224 1666 547 1904 839 1324 -452 2238 1083 2689 -1319 377 -2752 74 -1903 -679 -2258 -1924 -2879 -2248 -1725 -1022 215 -406 -2555 -2954 -1666 -1784 1574 -2065 451 -1710 -58 -2893 -261 113 912 -821 -113 131 2031 2221 2187 1568 1610 1265 2201 1946 -1090 857 -455 2212 -95 1841 -581 966 619 1291 -2556 145 -783 -605 -3147 SS 20200316T122159.2Z 7380.515269 323 1 50.47 2 81.03 100.75 68.52 192.90 0.00 1 0.00 1 0 30 7.007e-01 1.134e-02 2.239e-01 3.498e-03 8.844482e-01 2.054795e-03 9.756943e-03 -6.000000e+00 4.156373e-01 225.89 -2.00 3.57 -2.00 322.21 0.00e+00 1.669948e-02 1.174603e-03 2.196062e-03 -6.000000e+00 1.794185e-02 274.08 -2.00 20.00 -2.00 321.78 0.00e+00 6.078 0.004 302.00 328.00 3 5.7111e-01 7.6427e-03 8.1901e-02 -6.0000e+00 1.0298e+00 4.1121e-01 1.1945e-02 6.7717e-02 -6.0000e+00 1.1218e+00 -5.7849e-01 1.3502e-02 2.8278e-02 -6.0000e+00 6.6604e-01 2.4027e-01 6.0945e-03 1.7026e-02 -6.0000e+00 2.7564e-01 3.1334e-04 -1.5528e-03 1.0316e-04 2.4431e-04 -6.0000e+00 2.1548e-02 7.7444e-03 0.0000e+00 12 8 8 10 0 0 15.40 15.01 0.24 0.00774 -0.00392 279 52 1 5 0 180.870 21.69 15.01 18.45 -205148 -191496 -188294 -269550 -174191 -219195 -278037 -189832 -256085 -127828 -218881 -132859 -154988 -128050 -151262 46476 -121191 -2088 -74542 45427 -99669 -18642 -74354 -16092 -91573 -72057 -41917 -67397 -47047 -49856 -36001 -27680 -22174 -17006 30303 -22131 36443 -13024 9424 -14681 28528 -6434 23921 11325 16530 573 30111 6717 23165 8876 24882 16483 23221 20934 12073 13205 6864 5783 185 13306 -2486 18341 4006 15622 9080 12904 6720 11809 7897 9926 4265 2855 1035 2032 719 -3623 -2640 -2477 313 -1893 1489 -1750 -378 -1725 536 -609 1597 -602 1020 -989 2148 -1547 -442 -1706 -1808 -1130 -518 -1004 -1380 -723 -933 259 17 -684 -3661 -755 -1299 498 174 757 -659 -111 -470 -213 -204 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