File name: Pandora103s1_Downsview_20200326_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T080237.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v8d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20200326_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200326 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200326T124436.2Z 7390.530975 455 1 50.48 2 73.71 102.52 88.13 82.77 0.00 1 0.00 1 0 25 2.105e-01 8.072e-03 1.590e-01 3.092e-03 5.694965e-01 1.685993e-03 6.673284e-03 -6.000000e+00 1.256841e-01 226.67 -2.00 3.57 -2.00 320.78 0.00e+00 8.196732e-03 6.775650e-04 1.205201e-03 -6.000000e+00 5.503406e-03 275.22 -2.00 20.00 -2.00 320.26 0.00e+00 3.507 0.001 302.00 328.00 3 3.3770e+00 5.1691e-03 4.5793e-02 -6.0000e+00 3.1157e-01 7.6161e-02 6.6195e-03 3.0593e-02 -6.0000e+00 3.3918e-01 -7.6822e-02 6.4891e-03 1.8847e-02 -6.0000e+00 2.0106e-01 2.4928e-02 3.2137e-03 1.0704e-02 -6.0000e+00 8.3161e-02 2.8685e-04 -1.0066e-03 9.7814e-05 1.2538e-04 -6.0000e+00 6.4912e-03 3.6192e-03 0.0000e+00 11 8 0 10 0 0 99.97 15.00 0.20 0.00362 -0.00394 97 18 1 5 0 520.270 21.69 15.00 18.48 50095 -51416 37203 -57087 900000 -112099 104626 -93130 13972 -69765 -9143 -54868 58354 -39116 23406 -19218 11289 -23017 -3771 1317 -8426 6727 2970 -2888 -11198 6013 -31370 4651 -12595 12918 -12149 13341 -12632 11939 -10780 14415 -1568 6313 -3578 5309 -6097 1600 -4108 -1966 3400 3533 7811 2559 7928 2698 7555 242 6370 -386 5286 -3132 452 -4004 -83 -209 3784 1972 3131 1078 416 1873 1801 2583 1837 1466 -675 -630 -1276 -443 -3013 -1240 -4297 564 -1778 -648 -2271 -805 -2566 -604 -799 43 68 -517 -248 674 1572 169 1090 255 90 199 498 -488 -555 -1165 143 -308 1335 -309 -1078 -853 34 10 1516 818 306 -50 29 500 505 1486 808 690 -804 -406 -531 455 -300 130 -625 -224 208 740 -825 -811 -827 -131 69 403 -145 -175 494 -171 -354 -270 153 -73 872 168 -493 162 -573 900000 -1763 315 -1445 87 -982 -80 -859 408 -839 344 -480 237 -722 -106 37 -262 183 86 -93 -409 192 -1415 151 -499 447 -621 626 -834 645 -712 769 -108 476 -349 542 -762 199 -563 -273 461 492 1075 383 1180 451 1321 50 1340 -92 1241 -819 116 -1060 -21 -53 986 578 1011 385 154 671 636 944 747 665 -336 -321 -642 -209 -1345 -500 -1703 220 -793 -330 -1342 -521 -1819 -446 -626 36 58 -454 -215 558 1217 124 775 190 75 186 523 -570 -684 -1433 163 -324 1324 -317 -1172 -977 40 13 2057 1217 487 -83 47 781 753 2136 1180 1050 -1295 -670 -873 722 -464 194 -910 -314 287 1061 -1311 -1409 -1532 -251 139 845 -321 -403 1150 -404 -831 -616 331 -153 1792 SS 20200326T125105.3Z 7390.535477 459 1 50.51 2 72.57 103.73 86.99 83.84 0.00 1 0.00 1 0 25 9.087e-02 6.547e-03 2.183e-02 7.311e-04 5.384659e-01 3.955561e-04 6.313538e-03 -6.000000e+00 5.409556e-02 226.67 -2.00 3.57 -2.00 320.44 0.00e+00 5.263491e-03 1.451546e-04 1.007039e-03 -6.000000e+00 2.338327e-03 275.22 -2.00 20.00 -2.00 319.91 0.00e+00 3.291 0.001 302.00 328.00 3 1.2373e+00 1.1814e-03 4.3100e-02 -6.0000e+00 1.3421e-01 3.1065e-02 1.4624e-03 2.8661e-02 -6.0000e+00 1.4608e-01 -4.6186e-02 1.3599e-03 1.6213e-02 -6.0000e+00 8.6732e-02 1.1090e-02 6.8576e-04 7.4951e-03 -6.0000e+00 3.5897e-02 3.1763e-03 -8.1821e-04 2.3184e-05 9.1547e-05 -6.0000e+00 2.7951e-03 3.4554e-03 0.0000e+00 11 8 0 10 0 0 99.97 15.00 0.17 0.00346 -0.00269 671 125 1 5 0 75.260 21.69 15.00 18.48 -16922 -36465 -7349 -36725 -23458 -41086 -17353 -39786 -33246 -32413 -23446 -22886 -15800 -2290 -6620 395 847 2995 -93 4397 -4371 2564 -6690 -2845 -7193 -5841 -12392 -4323 -6289 869 299 2260 87 -2930 -1450 -989 -6 1087 -24 -2025 -1190 -2010 -395 -885 605 75 1498 1237 2366 2938 3021 2373 3161 1533 1362 176 -1059 -1682 -441 811 1930 2837 2016 1343 -255 1735 983 2423 1958 452 -636 -822 -1222 -1416 -1993 -1228 -1505 -638 -376 -1112 -1013 -1862 -1768 -735 -227 -261 226 104 185 71 705 -145 359 592 311 243 689 -263 -848 -685 -529 332 1338 179 -1682 -721 -172 577 1112 872 160 78 94 372 687 1337 804 558 -510 -851 -252 267 -20 -356 -431 -615 799 488 -778 -758 -694 -291 288 254 -231 -285 511 -161 -397 -92 40 287 768 -144 -381 -64 -376 -219 -418 -167 -487 -414 -422 -302 -344 -278 -44 -162 10 25 93 -3 149 -165 92 -272 -119 -333 -274 -618 -198 -300 42 17 147 6 -227 -109 -76 0 110 -3 -288 -170 -308 -62 -144 108 14 276 234 462 608 627 546 781 409 380 51 -316 -501 -128 234 582 936 746 540 -107 693 388 981 882 231 -354 -471 -689 -754 -980 -547 -637 -299 -180 -620 -646 -1335 -1369 -600 -196 -239 215 101 178 65 604 -117 278 474 277 246 788 -311 -1066 -851 -610 375 1429 197 -2005 -833 -208 739 1544 1330 264 132 158 590 1028 1922 1173 852 -828 -1432 -420 428 -31 -535 -623 -855 1077 691 -1228 -1320 -1295 -568 544 508 -490 -631 1149 -368 -899 -200 83 565 1492 SS 20200326T125649.3Z 7390.539459 462 1 50.58 2 71.56 104.80 85.97 84.78 0.00 1 0.00 1 0 25 6.894e-02 6.437e-03 1.401e-02 5.482e-04 5.129305e-01 2.939767e-04 5.984906e-03 -6.000000e+00 4.103455e-02 226.67 -2.00 3.57 -2.00 320.27 0.00e+00 4.670037e-03 1.019215e-04 7.050724e-04 -6.000000e+00 1.773859e-03 275.22 -2.00 20.00 -2.00 319.73 0.00e+00 3.122 0.001 302.00 328.00 3 9.2666e-01 8.6631e-04 4.0852e-02 -6.0000e+00 1.0181e-01 2.6279e-02 1.0553e-03 2.7116e-02 -6.0000e+00 1.1081e-01 -4.1831e-02 9.4734e-04 1.4793e-02 -6.0000e+00 6.5793e-02 9.1753e-03 4.8161e-04 6.6472e-03 -6.0000e+00 2.7227e-02 5.2407e-03 -8.8859e-04 1.7443e-05 7.6820e-05 -6.0000e+00 2.1205e-03 4.2180e-03 0.0000e+00 11 8 0 10 0 0 73.02 15.00 0.15 0.00422 -0.00246 984 183 1 5 0 51.230 21.69 15.00 18.48 -20980 -10368 -17512 -21706 -18847 -25624 -25264 -23867 -28361 -24794 -26728 -13163 -11018 -2002 -6164 3344 2359 3834 305 3289 304 2113 -1712 -3256 -4448 -7288 -8855 -7189 -5269 -355 429 1079 -340 -5031 -2427 -2293 1577 491 472 -1399 -1622 -1599 -942 -346 789 942 1278 689 1649 2918 2377 2516 2280 1590 712 263 -1221 -1101 -620 1099 2312 2606 2089 679 -254 1263 1199 2080 2139 124 -313 -931 -1005 -1404 -1560 -1256 -1113 -691 -680 -1332 -1150 -1865 -1654 -637 -363 -42 221 60 67 177 767 62 482 647 283 348 550 -201 -905 -628 -596 350 1357 168 -1588 -613 -269 517 1018 852 161 -13 109 297 738 1268 874 478 -402 -946 -265 163 -89 -384 -330 -604 771 489 -711 -757 -755 -256 311 330 -259 -247 485 -157 -501 23 6 332 654 -219 -108 -199 -246 -196 -286 -307 -320 -431 -383 -453 -226 -230 -48 -184 104 82 142 12 136 13 91 -80 -164 -240 -415 -509 -402 -294 -20 28 82 -29 -455 -211 -204 151 57 65 -225 -264 -277 -169 -63 158 192 264 146 359 667 547 634 623 463 219 83 -398 -356 -197 345 757 936 836 297 -114 543 503 898 1021 67 -184 -565 -600 -794 -812 -594 -497 -314 -342 -779 -767 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