File name: Pandora103s1_Downsview_20200808_L2Fit_fout2c9d20181123p1-8.txt File generation date: 20241101T093057.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20200521.txt Level 1 file used: Pandora103s1_Downsview_20200808_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200808 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0757 305.2165 305.3573 305.4981 305.6389 305.7797 305.9205 306.0612 306.2020 306.3427 306.4834 306.6241 306.7649 306.9055 307.0462 307.1869 307.3276 307.4682 307.6089 307.7495 307.8901 308.0307 308.1713 308.3119 308.4525 308.5930 308.7336 308.8741 309.0147 309.1552 309.2957 309.4362 309.5767 309.7172 309.8576 309.9981 310.1385 310.2790 310.4194 310.5598 310.7002 310.8406 310.9810 311.1214 311.2617 311.4021 311.5424 311.6827 311.8231 311.9634 312.1037 312.2439 312.3842 312.5245 312.6647 312.8050 312.9452 313.0854 313.2256 313.3658 313.5060 313.6462 313.7863 313.9265 314.0666 314.2068 314.3469 314.4870 314.6271 314.7672 314.9073 315.0473 315.1874 315.3274 315.4675 315.6075 315.7475 315.8875 316.0275 316.1675 316.3074 316.4474 316.5873 316.7273 316.8672 317.0071 317.1470 317.2869 317.4268 317.5666 317.7065 317.8463 317.9862 318.1260 318.2658 318.4056 318.5454 318.6852 318.8250 318.9647 319.1045 319.2442 319.3839 319.5236 319.6633 319.8030 319.9427 320.0824 320.2220 320.3617 320.5013 320.6409 320.7806 320.9202 321.0598 321.1993 321.3389 321.4785 321.6180 321.7575 321.8971 322.0366 322.1761 322.3156 322.4551 322.5945 322.7340 322.8734 323.0129 323.1523 323.2917 323.4311 323.5705 323.7099 323.8492 323.9886 324.1279 324.2673 324.4066 324.5459 324.6852 324.8245 324.9638 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200808T104952.3Z 7525.451300 192 1 50.64 2 84.93 72.75 51.53 217.90 0.00 1 0.00 1 0 17 5.043e-01 7.655e-02 5.248e-01 8.294e-02 9.222442e-01 4.855233e-02 1.067176e-02 -6.000000e+00 3.113691e-01 232.13 -2.00 3.57 -2.00 321.62 0.00e+00 -3.250928e-03 1.526855e-02 3.594029e-03 -6.000000e+00 1.412961e-02 287.32 -2.00 20.00 -2.00 320.87 0.00e+00 9.699 0.018 302.00 328.00 3 7.9360e-01 1.5322e-01 1.1010e-01 -6.0000e+00 7.8102e-01 2.2066e+00 1.7884e-01 5.7929e-02 -6.0000e+00 8.4562e-01 -1.9635e+00 9.9282e-02 2.4053e-02 -6.0000e+00 4.9969e-01 6.3352e-01 5.2205e-02 8.0869e-03 -6.0000e+00 2.0667e-01 5.0235e-06 -5.3603e-04 2.4151e-03 9.8201e-05 -6.0000e+00 1.6293e-02 2.7947e-03 0.0000e+00 12 8 8 10 0 0 -38.01 15.00 1.42 0.00279 -0.00123 13 2 1 5 0 3895.110 21.88 15.00 18.68 -9203 74433 18556 -33996 122519 900000 -57153 900000 -32293 88181 -45466 -27761 900000 -45591 18894 142662 7232 127805 -21481 900000 60628 12647 3503 103784 44671 16880 271849 -38003 94303 27778 900000 121431 94330 -42386 49451 17708 -26326 900000 110489 136754 12862 23720 900000 76385 -29233 -2398 -28610 5445 37166 83227 26886 40437 -16591 63403 17840 81063 135600 -30439 -32879 6551 23852 65844 35153 -1529 -41325 87102 -18392 -18496 25061 86222 -1705 5609 47204 17413 -3862 -35846 -21442 -66704 -4572 -5858 -9554 19406 5773 8049 -3583 40223 19540 -7569 18741 -22 18096 -14961 14431 3104 -5847 8813 -9808 14651 -2550 1024 -5418 -3526 -8676 24656 3696 3846 -7764 -9614 3900 14858 3438 3786 3895 9209 -982 -2251 11461 -2903 -4971 2279 1303 7393 -2471 -10594 -365 -3357 -12735 6616 4570 3245 3246 -332 -1378 -4417 -1919 -4450 -1430 3166 5406 1404 -1604 1270 1081 -1315 6013 1845 -4859 9897 900000 -8080 900000 -3696 7123 -5815 -3177 900000 -8286 2035 11524 974 10324 -3760 900000 4898 1277 377 8384 3609 1591 21960 -5117 7618 2244 900000 9809 7620 -7704 3995 1691 -4060 900000 8925 11047 2078 3484 900000 6170 -6440 -387 -5883 800 4094 6723 3751 5345 -4142 7450 3406 8334 10954 -8942 -9175 1155 3503 6770 5421 -370 -15477 8955 -5403 -5705 5521 11397 -576 1771 9360 4220 -1021 -11583 -5669 -28901 -1209 -1850 -3648 6271 2332 3369 -1763 13292 8179 -4169 7707 -10 6645 -7252 5712 1345 -3177 4854 -7563 10006 -2228 865 -4536 -2589 -6180 13743 2657 2921 -6386 -8754 3494 13639 3964 4671 4919 10888 -1247 -2843 14073 -4291 -7119 3387 1905 9675 -3413 -15404 -465 -4284 -17900 8284 6719 5583 6240 -718 -3251 -11598 -5256 -13086 -4170 8849 14543 3754 -4107 2944 2462 SS 20200808T110302.2Z 7525.460442 195 1 50.39 2 82.65 74.95 52.98 221.56 0.00 1 0.00 1 0 17 5.093e-01 1.612e-02 4.089e-01 1.156e-02 8.137637e-01 6.895041e-03 9.864289e-03 -6.000000e+00 3.105957e-01 232.13 -2.00 3.57 -2.00 322.28 0.00e+00 6.888999e-03 4.594501e-03 1.089074e-02 -6.000000e+00 1.453213e-02 287.32 -2.00 20.00 -2.00 321.78 0.00e+00 7.216 0.007 302.00 328.00 3 1.4217e+00 3.0297e-02 1.0146e-01 -6.0000e+00 7.7894e-01 5.5049e-01 4.3191e-02 8.5618e-02 -6.0000e+00 8.4259e-01 -8.5293e-01 3.9433e-02 3.8729e-02 -6.0000e+00 5.0038e-01 3.5258e-01 1.7375e-02 8.3475e-03 -6.0000e+00 2.0917e-01 5.2719e-05 -3.9339e-04 3.5293e-04 2.7588e-04 -6.0000e+00 1.5810e-02 4.2347e-04 0.0000e+00 12 8 8 10 0 0 -13.72 15.00 0.40 0.00042 -0.00253 73 14 1 5 0 690.240 21.88 15.00 18.68 900000 -84644 -95916 -177424 -143783 -166674 -46745 -141175 -34729 900000 -164185 -120629 900000 -86502 -56989 -117185 33167 -93480 11132 -39876 -51880 79671 -53122 -31682 1269 112211 -134010 -23785 249311 11306 -58377 8126 -27073 42792 -21819 46674 -3471 25302 -3703 52419 87000 8779 10239 3239 31247 342 11816 81507 -372 24966 55985 2901 58313 11957 19641 5914 28069 1353 34490 1237 22430 8438 18509 32595 21657 16399 11983 10755 11171 8585 10738 13308 9592 5297 7922 10490 -11506 -3512 -9311 5039 -5787 -5017 -5092 1620 -2093 -1514 927 6102 3826 208 1583 -1994 -2803 -3948 -2858 -3008 -1500 -2951 -1080 -1913 -704 -2766 -2486 -3166 -2907 -1387 704 -154 1180 2351 1237 1088 -691 -285 -774 -528 496 845 -216 1000 778 1635 16 1011 200 -1598 -304 783 -512 -562 85 907 -192 -450 130 104 54 371 251 23 -323 -455 -505 900000 -953 -1080 -3089 -1620 -2219 -527 -1590 -391 900000 -2690 -1482 900000 -1240 -759 -3360 374 -2584 125 -694 -1009 897 -1034 -519 17 1264 -6312 -402 2808 153 -1734 165 -804 723 -626 736 -98 627 -133 1358 1764 378 451 156 1267 18 557 2203 -22 1253 2522 226 3153 1004 1609 575 2213 137 2437 120 1837 881 1990 3404 2683 2166 1669 1608 1864 1661 2210 2753 2013 1085 1436 1686 -2215 -658 -2126 1192 -1801 -1772 -1987 635 -907 -691 434 2774 1763 96 682 -849 -1197 -1827 -1502 -1867 -1074 -2445 -955 -1724 -589 -2138 -1789 -2305 -2229 -1117 593 -143 1210 2713 1609 1516 -1001 -404 -1068 -715 675 1202 -327 1533 1178 2360 23 1372 266 -2100 -394 1076 -812 -1019 169 1941 -445 -1125 345 288 153 1060 710 62 -828 -1096 -1195 SS 20200808T111341.3Z 7525.467839 198 1 50.62 2 80.79 76.73 54.24 224.41 0.00 1 0.00 1 0 17 5.125e-01 1.128e-02 1.757e-01 4.000e-03 7.087597e-01 2.291191e-03 9.446373e-03 -6.000000e+00 3.123274e-01 232.13 -2.00 3.57 -2.00 321.76 0.00e+00 9.349405e-03 1.362942e-03 1.000802e-02 -6.000000e+00 1.387400e-02 287.32 -2.00 20.00 -2.00 321.21 0.00e+00 5.927 0.004 302.00 328.00 3 1.1728e+00 9.0430e-03 8.4658e-02 -6.0000e+00 7.8208e-01 2.0674e-01 1.2823e-02 7.2345e-02 -6.0000e+00 8.4510e-01 -3.7683e-01 1.2153e-02 3.4664e-02 -6.0000e+00 5.0325e-01 1.5892e-01 5.4750e-03 8.3302e-03 -6.0000e+00 2.0874e-01 2.5227e-04 4.9087e-05 1.2211e-04 2.6558e-04 -6.0000e+00 1.5771e-02 -1.5521e-04 0.0000e+00 12 8 8 10 0 0 3.38 15.00 0.24 -0.00016 0.00021 189 35 1 5 0 267.760 21.88 15.00 18.69 -228600 -132861 -184077 -45496 -96520 -165936 -161949 -123322 -205717 -148395 -153880 -109800 -117870 -103581 -69090 -87582 -28581 -74641 -10713 -62555 -1552 -75451 10160 -73065 -12067 -46652 3908 -46244 -27361 -27315 -40291 5571 -10358 25551 -12381 -14124 -17060 862 6196 19060 -241 31369 119 18212 6666 23099 3681 17941 1667 28301 13246 17620 10666 13831 11409 11666 4954 3096 6982 2224 9948 5266 13420 6214 9995 1920 7538 920 8124 2491 6503 1641 5139 257 -252 -1996 -3655 -1506 -3275 -614 -1001 93 -2259 -1495 -1053 3 -35 796 -482 1172 -1131 -582 -2651 -1898 -3014 -794 -1178 34 -451 -1320 -1419 -1533 -768 -824 -1957 -1716 -573 -122 1107 1298 1435 201 584 -285 173 -39 567 79 -36 -236 834 1283 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