File name: Pandora103s1_Downsview_20200919_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T100405.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20200919_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200919T113532.8Z 7567.483019 49 1 51.64 2 84.84 93.30 110.85 78.72 0.00 1 0.00 1 0 25 4.227e-01 6.090e-02 4.921e-01 5.660e-02 1.000359e+00 3.290593e-02 1.099707e-02 -6.000000e+00 2.539881e-01 228.46 -2.00 3.57 -2.00 321.99 0.00e+00 -9.112874e-03 1.279018e-02 6.683452e-03 -6.000000e+00 1.177344e-02 284.25 -2.00 20.00 -2.00 321.36 0.00e+00 9.586 0.017 302.00 328.00 3 5.5815e-01 1.1252e-01 1.1790e-01 -6.0000e+00 6.3198e-01 2.1954e+00 1.3134e-01 8.2953e-02 -6.0000e+00 6.8588e-01 -2.1980e+00 7.7065e-02 2.7358e-02 -6.0000e+00 4.0780e-01 7.4539e-01 4.2071e-02 1.2932e-02 -6.0000e+00 1.7042e-01 7.4339e-06 8.1809e-04 1.5198e-03 1.0716e-04 -6.0000e+00 1.3051e-02 -1.2072e-02 0.0000e+00 12 8 8 10 0 0 -40.50 15.00 1.42 -0.01207 -0.00592 22 4 1 5 0 2346.790 21.79 15.00 18.52 32167 82642 86974 41237 100770 32360 34787 70835 -24852 900000 23811 57899 6066 72836 38423 77895 43979 68875 -26104 8399 14915 118566 -54390 63253 143843 51167 58446 -63115 22271 4418 57088 -23450 8264 -88278 96013 -22479 -16013 -25882 91747 55291 -11963 -2518 69530 -6351 210385 -10359 24338 37193 -28114 16014 50444 900000 54575 36234 -6191 33403 4885 11427 -48432 -11095 -11730 19928 34251 42781 50631 23823 35515 35158 11462 52500 48188 33818 6677 -10247 -10605 67516 -40423 -41593 -4890 32331 -7996 -12910 18302 -9438 35538 4960 10138 -11046 5255 11897 30309 -7840 12656 7482 20028 -18244 255 6514 -3431 17829 -14279 -3849 -11045 13026 7597 945 -10504 7760 -4641 10399 2913 3590 2863 5505 -5028 4005 -9004 5492 3765 -894 -2460 -2520 1094 -8160 10377 2071 -2027 -2220 -408 -2640 1601 -2389 2878 -2484 -2463 1931 609 -674 3886 -1572 2480 -2583 556 3106 4560 4799 2465 5560 1785 1919 3908 -2400 900000 1423 3195 530 4019 3276 4689 3750 4491 -4190 885 1347 6542 -9276 3490 7936 3080 3225 -9497 1340 332 3150 -2941 788 -21254 5297 -2481 -1767 -3635 5062 4437 -1980 -379 4883 -892 11608 -1351 2197 2985 -4513 1767 4731 900000 5721 4798 -1180 4792 833 1891 -12146 -1959 -2071 2749 4535 5665 6425 3943 5291 5625 2593 8690 8774 7090 1731 -2827 -2574 6705 -11375 -12622 -1187 6422 -2779 -5342 6059 -4374 10980 2162 4307 -5790 2262 4529 9030 -3288 4399 3013 8288 -13086 177 4816 -3010 12591 -12842 -2782 -7922 7331 4736 667 -8867 5995 -4635 10328 3520 4654 3854 7169 -7102 5104 -13313 7332 5317 -1332 -3597 -3490 1400 -11165 11508 2433 -2516 -3037 -639 -4924 3215 -5457 6766 -6674 -7081 5552 1807 -2027 10934 -4432 6198 -6314 1297 SS 20200919T114824.4Z 7567.491949 52 1 50.73 2 82.53 95.55 108.70 81.04 0.00 1 0.00 1 0 17 6.044e-01 1.633e-02 3.716e-01 8.331e-03 8.850707e-01 5.010086e-03 1.064284e-02 -6.000000e+00 3.687326e-01 228.46 -2.00 3.57 -2.00 322.33 0.00e+00 1.247050e-02 3.330934e-03 8.103045e-03 -6.000000e+00 1.704419e-02 284.25 -2.00 20.00 -2.00 321.87 0.00e+00 7.121 0.007 302.00 328.00 3 8.7987e-01 2.1665e-02 9.2339e-02 -6.0000e+00 9.1667e-01 6.4703e-01 3.1804e-02 6.4782e-02 -6.0000e+00 9.9647e-01 -9.0628e-01 3.0814e-02 3.6385e-02 -6.0000e+00 5.9139e-01 3.7117e-01 1.3568e-02 1.2765e-02 -6.0000e+00 2.4452e-01 8.6648e-05 -1.3123e-03 2.4744e-04 3.2217e-04 -6.0000e+00 1.9054e-02 -8.9511e-03 0.0000e+00 12 8 8 10 0 0 25.94 14.99 0.28 -0.00895 -0.01881 114 21 1 5 0 444.940 21.69 14.99 18.52 -140443 -185691 900000 -152083 -181772 -198982 900000 -129796 -218849 -134307 -156693 -95728 -130653 -77986 -112801 -29473 27333 900000 -48459 123153 -127454 -37723 -114847 98031 -88777 900000 -74596 -11723 -74618 -18461 39526 103999 175002 -22165 87651 -1091 34843 -6812 127265 -22434 98437 -14479 47653 3610 14830 -7855 24573 4408 54875 27610 43676 40010 62652 34895 17337 24468 14741 23226 13620 22254 3988 22820 10663 18887 11275 30657 4904 24599 3749 22116 9793 14100 1075 -1405 4494 2232 -2704 -3883 3337 97 3907 1011 1487 -4220 861 -3200 4349 -311 2922 -3718 1265 -5102 -698 -3604 -1745 -1089 -361 -3546 -1655 -1643 -1065 -975 -1892 -870 -4955 -3512 -1149 1756 -502 894 -771 1632 -1189 673 -197 1021 -405 1307 -230 -495 1956 2264 1011 -54 -247 -1082 2115 1147 -372 -892 156 -49 1099 -133 -71 -336 700 -353 -378 -597 174 -237 122 -1244 -2638 900000 -1571 -2281 -2790 900000 -1054 -4038 -1090 -1735 -777 -1832 -863 -2248 -305 222 900000 -787 1000 -4515 -529 -3475 796 -2162 900000 -1541 -130 -1652 -272 449 844 1421 -605 854 -23 566 -196 1240 -1010 1598 -705 1301 157 591 -406 961 224 1822 1324 1998 2126 2913 2292 1420 1914 1273 1800 1126 1675 380 2021 1228 2258 1556 3552 687 3304 639 3531 1908 2690 226 -280 832 386 -477 -745 639 23 1065 325 524 -1687 347 -1416 1865 -142 1279 -1673 513 -2112 -278 -1602 -884 -653 -253 -2941 -1466 -1468 -885 -727 -1317 -598 -3731 -2775 -947 1539 -510 1027 -1011 2244 -1724 945 -271 1366 -559 1858 -347 -763 2879 3168 1372 -72 -321 -1376 2613 1546 -586 -1628 314 -108 2554 -337 -192 -949 2000 -1023 -1080 -1631 439 -561 281 SS 20200919T115901.3Z 7567.499320 55 1 50.52 2 80.63 97.42 106.91 82.92 0.00 1 0.00 1 0 17 5.574e-01 9.037e-03 1.724e-01 3.037e-03 7.625324e-01 1.757875e-03 9.637209e-03 -6.000000e+00 3.347092e-01 228.46 -2.00 3.57 -2.00 321.92 0.00e+00 1.208221e-02 1.053297e-03 6.959601e-03 -6.000000e+00 1.489586e-02 284.25 -2.00 20.00 -2.00 321.40 0.00e+00 5.839 0.004 302.00 328.00 3 7.5245e-01 6.9214e-03 7.5825e-02 -6.0000e+00 8.3141e-01 2.0354e-01 1.0202e-02 5.3847e-02 -6.0000e+00 9.0172e-01 -3.0976e-01 1.0478e-02 3.3965e-02 -6.0000e+00 5.3754e-01 1.2779e-01 4.7220e-03 1.3766e-02 -6.0000e+00 2.2403e-01 3.8325e-04 -6.5302e-04 9.2546e-05 2.8706e-04 -6.0000e+00 1.7155e-02 -9.2567e-03 0.0000e+00 11 8 0 10 0 0 3.35 15.00 0.24 -0.00926 -0.01416 272 51 1 5 0 185.680 21.79 15.00 18.53 -219938 -145110 -218007 -132288 -178862 -119346 -190711 -162842 -201229 -163101 -187502 -141298 -120843 -90678 -48379 -68442 -46117 -58918 8001 -44671 2691 -57448 12434 -50083 -24688 -62206 -32704 -47495 14634 -31128 -42302 8130 10781 5676 -12994 2757 -17616 -2885 -15052 11134 -3142 7683 1597 6871 3972 11907 2934 11411 4323 10989 10366 9001 11366 13382 5921 5260 867 -1275 762 282 5108 4537 8839 6455 5497 4671 6636 714 4339 2935 2599 1844 -21 -1056 -733 -2126 -1778 -622 -470 -283 -428 -861 -2011 -434 -1296 -280 -760 340 -1283 -30 -581 -716 -1542 -1311 -1728 -537 131 33 -1548 -996 -931 179 1318 54 -2500 -1856 -353 731 1403 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