File name: Pandora103s1_Downsview_20201023_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T103630.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20201023_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20201023 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201023T135246.9Z 7601.578321 99 1 23.89 2 70.19 130.05 143.73 68.26 0.00 1 0.00 1 0 25 3.975e-02 8.936e-03 3.607e-02 4.351e-03 3.710520e-01 2.257979e-03 4.468674e-03 -6.000000e+00 2.350336e-02 224.59 -2.00 3.57 -2.00 319.07 0.00e+00 2.176492e-03 5.435650e-04 6.310045e-04 -6.000000e+00 1.043142e-03 279.96 -2.00 20.00 -2.00 318.39 0.00e+00 2.919 0.000 302.00 328.00 3 4.6539e+00 6.2163e-03 3.4313e-02 -6.0000e+00 5.7943e-02 5.9374e-02 7.1803e-03 1.9242e-02 -6.0000e+00 6.3083e-02 -2.6915e-02 5.0982e-03 9.8296e-03 -6.0000e+00 3.7624e-02 5.5536e-03 2.6408e-03 3.2695e-03 -6.0000e+00 1.5725e-02 1.8356e-04 -5.6024e-04 1.4064e-04 4.0662e-05 -6.0000e+00 1.2219e-03 -3.2246e-03 0.0000e+00 12 9 1 12 1 1 99.70 15.00 0.11 -0.00322 -0.00743 7 3 1 5 0 2964.700 21.98 15.00 18.82 -20285 -19961 -12430 -2023 -17250 4135 -11299 4769 -7686 -5068 -12140 -5805 -5410 4359 -3603 -1630 6630 -5719 898 -436 2091 1923 6774 -100 -1083 -2016 552 -4867 -2564 -3396 3259 -498 -2377 -4679 -2240 -1893 1696 2234 3006 2065 -2031 -1167 -2656 671 1177 935 791 530 491 3296 1388 1862 1982 246 -135 896 -850 296 -477 877 1246 2352 1212 87 -738 1991 1357 2443 3185 -700 -325 -1542 -858 -2190 -715 -2083 -730 -1974 -1076 -1166 -2642 -2282 -909 -683 648 -34 288 719 153 35 524 165 240 1336 432 67 869 -398 -1229 -1089 -960 544 1634 162 -2250 -439 53 592 1470 846 510 -117 -26 588 921 1510 1084 871 -181 -1357 -216 -333 28 -47 -553 -639 1114 493 -966 -1064 -978 -218 143 405 -511 -45 294 233 -625 168 -149 351 618 -820 -868 -504 -70 -651 127 -436 177 -346 -231 -616 -306 -332 288 -296 -145 584 -600 93 -47 225 209 727 -12 -140 -269 71 -639 -324 -448 443 -78 -407 -830 -380 -325 312 482 757 593 -657 -394 -936 233 410 328 278 186 175 1185 541 778 879 116 -66 446 -434 149 -239 438 646 1300 730 56 -476 1205 794 1438 2013 -502 -248 -1220 -669 -1659 -500 -1360 -442 -1205 -698 -844 -2148 -2007 -839 -661 654 -36 320 809 172 38 538 160 221 1229 426 73 1023 -509 -1644 -1442 -1206 634 1838 189 -2811 -567 71 822 2134 1304 820 -190 -42 896 1331 2108 1525 1270 -278 -2172 -346 -526 44 -70 -807 -901 1519 690 -1445 -1692 -1620 -368 248 726 -959 -86 577 462 -1246 327 -282 645 1128 SS 20201023T140341.6Z 7601.585898 102 1 11.18 2 68.71 132.43 141.96 70.92 0.00 1 0.00 1 0 25 2.825e-02 9.304e-03 2.843e-02 4.505e-03 3.446684e-01 2.334889e-03 4.177778e-03 -6.000000e+00 1.670744e-02 224.59 -2.00 3.57 -2.00 318.50 0.00e+00 2.084313e-03 4.759920e-04 4.046147e-04 -6.000000e+00 7.415170e-04 279.95 -2.00 20.00 -2.00 317.81 0.00e+00 2.729 0.000 302.00 328.00 3 4.4437e+00 6.2921e-03 3.1992e-02 -6.0000e+00 4.1189e-02 3.5937e-02 7.1826e-03 1.7841e-02 -6.0000e+00 4.4842e-02 -7.4313e-03 4.7985e-03 9.0041e-03 -6.0000e+00 2.6745e-02 -4.0445e-03 2.4676e-03 3.0063e-03 -6.0000e+00 1.1178e-02 2.8326e-04 -5.0380e-04 1.4463e-04 3.5654e-05 -6.0000e+00 8.6861e-04 -3.2676e-03 0.0000e+00 12 9 1 12 9 1 98.78 15.00 0.07 -0.00327 -0.00705 5 5 1 5 0 1832.650 21.98 15.00 18.82 7778 11168 -9827 -8827 2892 1009 -9277 -2905 -4196 2181 -15599 -2220 3984 -2290 -545 276 1463 2436 3375 -1003 4046 -997 7442 1299 167 -4388 -3509 -5758 -399 65 -183 3754 -4273 -4743 -1751 -389 -203 80 -1663 128 -1220 1099 -934 -247 -935 1769 777 -621 154 787 -422 961 1367 1587 827 -280 -211 -1103 38 1060 2038 2634 2800 -965 -199 -294 1147 1304 2917 -566 -224 -65 62 -552 -1854 -1390 -767 -908 275 -1269 -1635 -2542 -1249 184 26 593 -871 217 -4 19 714 601 558 1602 438 236 569 -525 -1191 -746 -1637 683 1367 -97 -2004 -934 -409 679 1367 568 106 -9 -86 808 1232 1670 1415 710 43 -1462 -1057 -30 -86 -221 -362 197 855 1470 -630 -1174 -1072 159 229 371 -568 -272 708 -287 -711 71 -412 597 635 343 513 -549 -462 128 45 -496 -163 -257 130 -1142 -157 308 -220 -59 32 181 315 453 -145 568 -148 1054 206 28 -788 -616 -1000 -65 11 -33 725 -948 -1067 -375 -84 -48 22 -542 46 -479 443 -393 -105 -402 746 330 -266 66 346 -198 476 713 860 464 -163 -124 -648 22 611 1210 1663 1889 -700 -143 -204 756 868 2054 -445 -186 -55 52 -452 -1445 -1003 -520 -612 194 -1001 -1418 -2385 -1224 187 28 658 -1012 254 -4 21 767 609 541 1549 451 263 683 -677 -1597 -988 -2084 811 1579 -116 -2537 -1222 -552 943 1976 865 168 -15 -135 1205 1751 2302 1961 1020 65 -2286 -1663 -46 -130 -327 -522 275 1162 2022 -922 -1817 -1718 259 381 636 -1014 -498 1314 -540 -1343 131 -746 1050 1112 SS 20201023T141102.8Z 7601.591005 106 1 5.70 2 67.75 134.07 140.76 72.62 0.00 1 0.00 1 0 25 1.557e-02 8.488e-03 4.499e-03 1.055e-03 3.324772e-01 5.464561e-04 4.030357e-03 -6.000000e+00 9.207696e-03 224.59 -2.00 3.57 -2.00 317.85 0.00e+00 1.198323e-03 9.269348e-05 2.740836e-04 -6.000000e+00 4.086810e-04 279.95 -2.00 20.00 -2.00 317.16 0.00e+00 2.619 0.000 302.00 328.00 3 1.4583e+00 1.4480e-03 3.0708e-02 -6.0000e+00 2.2700e-02 -2.9109e-04 1.6388e-03 1.7119e-02 -6.0000e+00 2.4714e-02 -1.7429e-02 1.0245e-03 8.5006e-03 -6.0000e+00 1.4740e-02 4.0267e-03 5.1331e-04 2.5096e-03 -6.0000e+00 6.1599e-03 6.4970e-03 -6.9322e-04 3.3400e-05 3.1114e-05 -6.0000e+00 4.7875e-04 -2.5793e-03 0.0000e+00 12 9 1 12 1 1 99.31 15.00 0.20 -0.00258 -0.00779 62 107 1 5 0 87.650 21.98 15.00 18.83 -686 -810 -4893 -4101 -5756 -2586 -2319 -2982 -2726 -5217 -4756 -2342 480 1265 1032 795 1550 912 2055 1921 1138 1274 650 183 -522 -2724 -2871 -2476 -1309 21 -21 53 -2170 -4869 -2573 -1013 -4 1445 173 -726 -1144 -279 -166 321 580 -83 -202 -166 319 1588 1505 1149 1764 873 926 1270 51 -243 548 1317 2218 2170 1226 -475 -1206 406 933 2283 2169 -246 -642 -993 -1005 -1177 -1239 -980 -938 -37 -353 -1514 -1650 -2097 -1490 -345 -126 -76 35 -10 -242 -99 264 326 1002 1243 673 326 509 -556 -1412 -1201 -617 610 1469 253 -1622 -636 -277 572 1194 787 109 -40 291 442 1235 1797 1118 710 -189 -1126 -557 50 -139 -234 -179 -356 1150 837 -753 -1014 -1084 -379 364 470 -368 -321 393 -91 -507 -172 -116 229 733 -50 -64 -398 -310 -412 -178 -174 -252 -249 -505 -473 -248 57 175 164 127 261 162 378 366 222 250 132 40 -121 -656 -679 -560 -285 5 -5 14 -624 -1449 -729 -287 -1 486 70 -336 -537 -137 -83 163 294 -42 -102 -83 160 812 820 677 1028 538 590 828 34 -162 358 857 1494 1581 917 -380 -968 304 704 1718 1668 -203 -572 -916 -918 -1029 -1065 -764 -722 -28 -269 -1312 -1515 -2008 -1520 -369 -135 -87 40 -12 -281 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