File name: Pandora103s1_Downsview_20201222_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T113012.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20201222_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20201222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201222T132752.3Z 7661.561022 54 1 50.61 2 85.21 129.28 132.95 35.11 0.00 1 0.00 1 0 25 6.122e-01 6.436e-02 4.872e-01 5.379e-02 1.060009e+00 3.098962e-02 1.159148e-02 -6.000000e+00 3.646690e-01 222.48 -2.00 3.57 -2.00 322.02 0.00e+00 -3.898119e-02 1.154850e-02 1.432568e-02 -6.000000e+00 1.758342e-02 273.22 -2.00 20.00 -2.00 321.42 0.00e+00 10.156 0.020 302.00 328.00 3 4.3286e-02 9.9111e-02 1.6082e-01 -6.0000e+00 8.9786e-01 2.1909e+00 1.1961e-01 1.7864e-01 -6.0000e+00 9.8384e-01 -2.2695e+00 7.8793e-02 4.6646e-02 -6.0000e+00 5.7993e-01 7.8547e-01 4.1934e-02 2.6332e-02 -6.0000e+00 2.4221e-01 8.0340e-06 -3.6153e-04 1.4298e-03 3.3113e-04 -6.0000e+00 1.9313e-02 2.4149e-03 0.0000e+00 12 8 8 10 0 0 37.31 15.00 0.96 0.00241 -0.00030 28 5 1 5 0 1807.030 21.88 15.00 18.68 58476 900000 149746 900000 -37385 900000 -59833 178947 -48056 900000 2598 108041 10755 41514 87473 195437 135467 60591 -4622 25681 62483 32055 66920 -37040 900000 74323 100325 -23019 900000 24897 293817 -8527 900000 4211 61179 -31753 30268 -28631 93181 16871 124095 200998 -41977 36243 -12032 69669 48522 103710 21039 -6477 11197 900000 47449 120211 -25518 194362 85577 148941 52474 50551 26747 67459 31640 8535 31109 14893 17590 -22905 41803 5723 35814 6071 35518 1124 52663 -30149 33295 -42961 107264 -11540 2587 -27322 -16254 18462 9343 15543 8804 -3576 -8954 24966 -2039 -9523 4407 -7644 6487 -6952 -8000 -4887 -3795 826 -17968 9344 -1399 3875 -5050 -5479 -1595 -6603 16433 -1295 -1638 7576 7 -4288 10276 -4777 19066 1008 377 -425 317 723 6929 -2354 4713 -11147 6439 -7434 2278 1059 -851 2486 -2239 459 -2034 1224 -1031 3226 -4493 591 -1644 2098 2660 4339 900000 7843 900000 -3753 900000 -9401 9373 -9229 900000 329 5659 1220 3443 4998 10236 7095 4039 -504 2079 3273 2289 3824 -6628 900000 5308 5255 -3069 900000 1660 15389 -893 900000 381 3204 -3780 2162 -4499 5324 2410 6500 10527 -10393 3624 -1719 3981 3234 5432 1903 -833 1333 900000 4744 6926 -6197 10180 8068 7801 5772 5031 3222 5653 4143 1382 4562 2574 3040 -5889 7006 1390 7503 1561 7069 257 6896 -8053 4534 -12069 8427 -3506 800 -11838 -6965 6575 3470 6187 3479 -1583 -4008 8238 -833 -4090 1708 -3723 3194 -4171 -5600 -3723 -3054 629 -15228 5922 -916 2415 -3624 -4190 -1253 -5471 13685 -1363 -1966 9018 10 -5962 12086 -6437 22568 1349 525 -595 423 996 8601 -3131 5703 -15413 7588 -11136 3627 1992 -1669 5173 -5320 1153 -5618 3415 -2991 8923 -13071 1539 -4418 5032 6269 SS 20201222T134018.2Z 7661.569655 57 1 50.44 2 83.50 131.57 131.62 38.73 0.00 1 0.00 1 0 17 5.188e-01 1.603e-02 4.028e-01 1.099e-02 9.139776e-01 6.449729e-03 1.035483e-02 -6.000000e+00 3.066808e-01 222.48 -2.00 3.57 -2.00 322.38 0.00e+00 1.716706e-02 3.751384e-03 1.649106e-03 -6.000000e+00 1.361306e-02 273.22 -2.00 20.00 -2.00 321.95 0.00e+00 8.020 0.010 302.00 328.00 3 3.8268e-01 2.4356e-02 9.5324e-02 -6.0000e+00 7.5562e-01 8.9855e-01 3.5160e-02 6.4167e-02 -6.0000e+00 8.2586e-01 -1.1776e+00 3.6782e-02 2.8271e-02 -6.0000e+00 4.8812e-01 4.7748e-01 1.6827e-02 1.6194e-02 -6.0000e+00 2.0259e-01 5.9650e-05 -1.7955e-03 3.1863e-04 2.8591e-04 -6.0000e+00 1.5998e-02 1.8038e-03 0.0000e+00 12 8 8 10 0 0 14.28 15.00 0.36 0.00180 -0.01169 106 20 1 5 0 475.760 21.88 15.00 18.69 -38270 -127330 -128911 -179519 -114816 900000 -188237 -97574 900000 -140325 -91868 -139397 59291 -100182 -53689 -77008 73403 65498 -25827 -67434 49541 -74058 248312 52518 -18328 -103784 -23770 -58467 139115 -4381 81858 5475 81406 -41032 -39917 27494 23737 32497 29059 44052 29681 32108 -28314 48750 20680 -10879 10181 44020 -10143 15784 23007 26747 41893 22822 30181 40147 20356 -1923 12012 -10422 1712 57229 37532 18811 19499 11153 27782 8872 8289 15857 16947 5897 5614 9152 -1707 -13707 -12294 -4875 -2165 9199 1623 5500 829 -744 -1158 6833 -157 2100 -2171 -5640 1475 455 329 -2139 -2064 -4784 -1381 -254 -2045 -86 -1890 150 -1160 -1907 -2071 -3268 -1264 -593 1886 -387 -1128 -1219 -106 -1286 208 447 1045 545 1106 -709 1200 2504 2387 -159 -713 61 908 1961 -810 -533 -219 638 478 253 -678 0 799 -358 -445 -167 -465 49 -91 -410 -1985 -2010 -4198 -1231 900000 -3668 -1046 900000 -1641 -985 -2173 635 -1952 -837 -1801 787 702 -453 -1774 531 -1876 2661 563 -275 -3236 -357 -1253 1491 -70 877 123 960 -1519 -1400 530 509 731 779 1133 954 1067 -1628 1463 842 -572 502 1651 -642 846 1278 1590 2559 1623 2058 2503 1527 -174 913 -985 152 3619 3035 2071 2280 1445 3113 1288 1357 2688 3038 1195 1094 1578 -294 -2431 -2108 -845 -432 1990 449 1672 290 -282 -465 2663 -69 908 -964 -2489 575 172 126 -921 -1041 -2974 -982 -205 -1825 -76 -1574 110 -791 -1306 -1494 -2537 -1029 -528 1869 -452 -1496 -1742 -154 -1863 289 612 1452 797 1682 -1112 1794 3513 3213 -213 -940 78 1159 2709 -1335 -1015 -466 1458 1179 674 -1773 0 2187 -993 -1212 -471 -1218 119 -217 SS 20201222T135058.2Z 7661.577063 60 1 50.47 2 82.08 133.58 130.39 41.71 0.00 1 0.00 1 0 25 5.627e-01 1.184e-02 2.694e-01 4.924e-03 8.143600e-01 2.841289e-03 9.060768e-03 -6.000000e+00 3.297892e-01 222.48 -2.00 3.57 -2.00 322.14 0.00e+00 1.495403e-02 1.584586e-03 1.657329e-03 -6.000000e+00 1.436296e-02 273.22 -2.00 20.00 -2.00 321.70 0.00e+00 6.787 0.006 302.00 328.00 3 5.2443e-01 1.0397e-02 8.2152e-02 -6.0000e+00 8.1109e-01 4.2639e-01 1.5604e-02 5.6752e-02 -6.0000e+00 8.8560e-01 -5.8690e-01 1.7185e-02 2.5647e-02 -6.0000e+00 5.2689e-01 2.4436e-01 7.8705e-03 1.4870e-02 -6.0000e+00 2.1961e-01 1.9050e-04 -1.9816e-03 1.5022e-04 2.1137e-04 -6.0000e+00 1.7287e-02 2.3372e-03 0.0000e+00 12 8 8 10 0 0 98.94 14.99 0.23 0.00234 -0.01255 210 39 1 5 0 240.310 21.88 14.99 18.70 -159922 136254 -69069 -171158 -215476 -151185 11347 -217807 -175739 -167533 -88027 -190572 -129026 -165197 -29686 -131602 -65981 -86090 108420 -63391 -4553 -53122 -47242 -53640 -57038 -22450 -95557 -59416 -22326 40352 -48183 20259 -16393 51497 -40212 24409 -5372 39844 2679 12958 -4450 22460 -3003 28236 5533 25405 10220 33394 14204 17020 17463 14355 23543 7391 18991 3040 9706 -1939 6313 -4495 18452 7865 15464 6412 8460 5569 13510 6861 8147 8015 7328 2582 2072 1279 -634 2725 -1601 2650 212 -773 -2912 148 -1166 1759 -1483 -394 -887 470 -1141 1911 -463 551 -958 -1209 -2642 -1680 -224 -1303 -889 -1812 -264 -336 1633 -2175 -1849 -2666 -471 -671 624 178 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