File name: Pandora103s1_Downsview_20210108_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T113121.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20210108_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210108T140046.4Z 7678.583871 227 1 6.85 2 80.80 133.19 60.24 195.17 0.00 1 0.00 1 0 25 5.297e-01 2.738e-02 3.772e-01 2.001e-02 7.012171e-01 1.158655e-02 8.086015e-03 -6.000000e+00 3.200014e-01 223.12 -2.00 3.57 -2.00 321.40 0.00e+00 1.384186e-02 5.456889e-03 7.414243e-04 -6.000000e+00 1.675088e-02 272.23 -2.00 20.00 -2.00 320.94 0.00e+00 5.944 0.004 302.00 328.00 3 2.8613e+00 3.7437e-02 6.9398e-02 -6.0000e+00 7.9297e-01 4.1893e-01 5.0108e-02 4.1540e-02 -6.0000e+00 8.7091e-01 -5.7583e-01 5.1031e-02 2.1882e-02 -6.0000e+00 5.1334e-01 2.5578e-01 2.4564e-02 1.4135e-02 -6.0000e+00 2.1447e-01 4.3395e-05 -2.6713e-03 6.2869e-04 1.6921e-04 -6.0000e+00 1.6899e-02 5.8771e-04 0.0000e+00 12 9 9 12 1 1 999.00 15.00 0.36 0.00059 -0.01949 2 4 1 5 0 2225.350 21.88 15.00 18.68 -87613 900000 900000 900000 -134110 900000 -211256 900000 -82036 900000 -28600 900000 -19604 900000 39200 900000 -53944 900000 900000 -14455 900000 -62286 900000 -84103 900000 -89749 8003 -58562 39470 -5659 900000 112702 122710 -68737 228592 -43992 1104 108204 17129 76351 122499 45429 34465 29844 -28803 86005 11279 284614 10885 61199 -13688 80303 7200 36586 -651 59529 19673 24353 4559 14095 -3117 36101 9840 6168 20339 8097 9633 6648 7973 1284 2689 1897 143 -6436 10201 -6149 10727 -99 4729 -2557 9840 -5203 1476 -4577 881 -2025 3599 -1464 -1448 -2291 -4812 -4633 -8010 -1844 -5660 1053 -2626 1726 -2841 237 -2091 3191 -1837 2451 -642 -1427 -1060 1854 1060 424 -1385 -1585 -269 -348 2406 928 2692 -1035 -543 -1062 1578 -1913 4465 -1127 1201 -725 5054 -85 533 -147 -197 942 40 870 -1020 -1033 159 1725 -1723 396 -152 0 -1073 -1704 900000 900000 900000 -2688 900000 -8326 900000 -1596 900000 -556 900000 -381 900000 763 900000 -1843 900000 900000 -398 900000 -2599 900000 -4331 900000 -4946 175 -2410 768 -169 900000 2192 2387 -6079 4447 -3008 53 2211 954 2743 3110 2529 2227 2080 -3583 3770 1033 5537 1107 4174 -2066 5521 1063 4335 -113 6008 2891 3370 746 2118 -581 5173 2037 1458 4418 1973 2307 1714 2240 427 948 690 52 -2328 2902 -1871 2684 -29 1485 -1007 3996 -2718 786 -2737 529 -1316 2323 -1009 -990 -1527 -3120 -2851 -5001 -1146 -4078 821 -2414 1703 -3114 254 -2161 2891 -1642 2122 -598 -1413 -1104 2014 1268 562 -2019 -2420 -409 -516 3378 1293 3734 -1536 -837 -1679 2423 -2933 6296 -1623 1653 -986 6512 -120 825 -253 -364 1819 80 1848 -2298 -2406 374 4023 -4091 900 -332 -1 -2213 SS 20210108T141259.1Z 7678.592351 233 1 22.26 2 79.22 135.58 60.90 198.39 0.00 1 0.00 1 0 17 3.100e-01 7.717e-03 1.217e-01 3.036e-03 6.492160e-01 1.644049e-03 7.514290e-03 -6.000000e+00 1.821559e-01 223.12 -2.00 3.57 -2.00 321.13 0.00e+00 8.097651e-03 7.330683e-04 1.690212e-03 -6.000000e+00 7.881842e-03 272.23 -2.00 20.00 -2.00 320.66 0.00e+00 5.152 0.003 302.00 328.00 3 1.4738e+00 5.2047e-03 6.0501e-02 -6.0000e+00 4.4877e-01 1.3231e-01 7.0349e-03 3.4824e-02 -6.0000e+00 4.8984e-01 -1.5252e-01 7.4511e-03 2.1889e-02 -6.0000e+00 2.9113e-01 5.7169e-02 3.6134e-03 1.1555e-02 -6.0000e+00 1.2110e-01 4.0522e-04 -1.1282e-03 9.2677e-05 1.4605e-04 -6.0000e+00 9.5250e-03 1.0064e-03 0.0000e+00 12 9 1 12 1 1 99.64 15.00 0.14 0.00101 -0.00747 69 30 1 5 0 315.450 21.88 15.00 18.68 -145259 -72930 -86237 -77730 -136097 -74545 -88551 -105351 -130164 -68856 -103145 -71125 -54573 -25268 -2846 -24858 -23421 -652 -4887 -16169 -4896 -26040 -15398 -30650 -18960 -10775 -10401 -24109 -18118 -30089 3631 -231 7775 -16505 -7544 -2352 -5708 -4660 3838 4779 -6072 1780 -1739 5716 -416 4145 3401 5117 6690 6561 5359 5460 7145 4953 2765 3104 -2426 746 -1458 817 1855 4413 4526 1548 3277 2125 2671 2971 4430 -9 282 -459 -500 -2157 -2332 -2693 -2354 -2238 -1075 -438 -360 -1858 -2150 -612 -667 30 -529 51 -179 258 236 -562 -533 -416 -907 -248 146 -10 -580 -647 -479 193 1341 44 -1190 -713 100 357 1214 628 91 166 -192 86 660 1039 1371 555 -213 -899 180 340 395 -437 -593 -933 853 904 -658 -844 -737 -195 299 276 -552 -183 388 -1 -514 0 -89 263 611 -1564 -475 -664 -529 -1429 -463 -682 -1061 -1647 -550 -1283 -779 -662 -299 -34 -395 -416 -11 -86 -331 -91 -603 -332 -817 -475 -255 -246 -662 -493 -1045 108 -9 299 -840 -347 -105 -295 -285 257 365 -574 167 -178 562 -45 441 378 585 800 851 780 810 1139 863 516 597 -499 147 -289 160 381 985 1141 443 960 626 779 910 1493 -4 120 -202 -215 -886 -877 -930 -777 -772 -416 -198 -189 -1114 -1408 -421 -488 23 -429 42 -146 201 173 -391 -363 -299 -737 -232 144 -11 -690 -765 -527 191 1343 42 -1210 -765 112 432 1610 933 138 261 -303 130 1021 1557 2071 883 -332 -1452 284 557 622 -672 -882 -1343 1196 1342 -1109 -1484 -1407 -394 633 622 -1241 -427 922 -3 -1227 0 -206 574 1316 SS 20210108T141933.2Z 7678.596912 236 1 50.46 2 78.40 136.88 61.30 200.09 0.00 1 0.00 1 0 17 3.031e-01 9.106e-03 2.683e-01 5.714e-03 6.120570e-01 3.142015e-03 7.182920e-03 -6.000000e+00 1.782195e-01 223.12 -2.00 3.57 -2.00 321.19 0.00e+00 1.073491e-02 1.386755e-03 1.258987e-03 -6.000000e+00 8.169110e-03 272.23 -2.00 20.00 -2.00 320.71 0.00e+00 4.816 0.002 302.00 328.00 3 2.9064e+00 9.9271e-03 5.6894e-02 -6.0000e+00 4.3930e-01 1.5320e-01 1.3304e-02 3.3782e-02 -6.0000e+00 4.7970e-01 -1.1716e-01 1.4129e-02 2.1801e-02 -6.0000e+00 2.8464e-01 3.9663e-02 6.8929e-03 1.4319e-02 -6.0000e+00 1.1880e-01 1.3145e-04 -1.0228e-03 1.8197e-04 1.7192e-04 -6.0000e+00 9.4334e-03 2.6278e-04 0.0000e+00 11 8 0 10 0 0 99.98 15.00 0.12 0.00026 -0.00742 87 16 1 5 0 579.830 21.88 15.00 18.68 -152697 25180 -57775 900000 -97218 212594 -14906 -55284 51685 900000 -121375 41894 17262 -211 61983 20875 46617 -41976 -4762 1702 -14745 22984 16512 51986 54085 -31827 -9142 -25903 14092 -2818 9791 15957 -4651 15399 -7991 3003 -7393 1075 -2132 -2143 -2452 7147 -8771 13993 -1561 6470 -141 5229 -184 3943 1398 8853 3953 4152 2001 -614 3346 -4836 -899 -2609 2432 3893 6138 2783 390 -1291 3388 1525 5781 -1193 1144 -2116 463 -3545 -1702 -1463 -1969 -2454 -524 -2604 -549 -865 -3048 -1142 -463 406 119 -531 -233 729 589 836 -2149 182 -1271 469 -243 787 -918 -482 -778 697 2850 738 -1499 -1652 -369 1325 1986 351 122 -505 762 -621 879 714 1531 616 -72 -791 53 220 232 -557 -242 -802 213 333 -990 -518 -671 -303 87 407 -599 -3 582 198 -733 -115 -275 719 566 -2245 140 -426 900000 -938 1184 -83 -415 288 900000 -1980 233 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