File name: Pandora103s1_Downsview_20210225_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T122226.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20200901.txt Level 1 file used: Pandora103s1_Downsview_20210225_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210225T123420.2Z 7726.523845 251 1 50.43 2 84.95 107.43 100.40 311.19 0.00 1 0.00 1 0 25 5.344e-01 4.179e-02 4.914e-01 4.276e-02 1.057951e+00 2.521487e-02 1.129018e-02 -6.000000e+00 3.164045e-01 225.04 -2.00 3.57 -2.00 322.37 0.00e+00 -1.346197e-02 1.004171e-02 1.124165e-02 -6.000000e+00 1.382824e-02 272.57 -2.00 20.00 -2.00 321.87 0.00e+00 9.775 0.018 302.00 328.00 3 1.3148e-01 8.5298e-02 1.3286e-01 -6.0000e+00 7.8271e-01 2.1155e+00 1.0121e-01 1.1434e-01 -6.0000e+00 8.5309e-01 -2.3178e+00 6.5556e-02 3.9983e-02 -6.0000e+00 5.0661e-01 8.1350e-01 3.5675e-02 1.1459e-02 -6.0000e+00 2.1079e-01 1.0659e-05 5.1018e-04 1.1547e-03 1.2723e-04 -6.0000e+00 1.6511e-02 -1.1029e-03 0.0000e+00 12 8 8 10 0 0 53.62 15.00 0.84 -0.00110 0.00273 39 7 1 5 0 1292.710 21.88 15.00 18.69 3469 -11429 900000 91266 -20473 83672 73063 273656 27462 -12766 -64532 -46870 20012 -9925 45029 10460 42423 60398 172454 19384 183780 17790 130495 -44854 61830 88489 54309 -57757 -18226 5781 87318 -62873 76736 21406 214725 24246 -683 -39679 24883 -6175 71939 30859 110527 -26976 -10642 115369 -1072 45813 14997 17744 83142 27178 14898 97410 94413 77340 -37841 113073 -6274 64633 9013 -10334 -34008 36302 -18843 8454 10952 11000 71187 3801 48499 -16928 36165 24979 1311 -14174 16082 -51651 16441 29260 27610 -7112 3462 13562 11566 14082 8259 -5933 -6549 -5842 2576 -11954 12424 -571 7552 -8479 -262 9109 -676 -5545 -5734 3073 -16323 -4554 -4112 1347 837 -1259 6008 -261 -1185 4041 1746 -1223 3241 2448 1389 2061 1180 -3596 1454 1711 1572 -2989 3396 -843 3557 345 -950 -2437 1406 -4426 -253 -727 583 32 1455 675 729 -2484 -175 585 1331 313 -1112 900000 3805 -1280 3488 3046 11409 1249 -871 -6950 -4974 1214 -903 2560 872 2573 2976 7190 1249 7662 1011 5440 -5270 2578 3689 2264 -5910 -1174 307 3640 -8340 3199 1217 8952 1195 -47 -4662 1792 -679 4199 2456 4608 -3374 -1049 4810 -98 2674 1250 1554 4159 2606 1739 5279 5511 5481 -7601 5185 -863 4042 977 -1465 -6805 3935 -3692 1269 1644 1789 7123 824 7077 -4729 5579 3853 224 -2541 2078 -14212 2673 5001 5640 -2343 1126 4240 3858 4755 3030 -2498 -2676 -2241 859 -4485 3781 -221 3180 -4984 -166 5962 -524 -4485 -4279 1870 -11160 -2772 -2623 865 579 -987 5060 -273 -1423 5003 2293 -1652 4107 3102 1818 2801 1678 -5367 1982 2196 1940 -3776 3936 -998 4123 461 -1513 -4612 2890 -10592 -634 -1985 1681 96 4416 2059 2169 -7206 -455 1404 3140 SS 20210225T124627.2Z 7726.532260 254 1 50.47 2 82.87 109.60 101.98 313.45 0.00 1 0.00 1 0 25 4.430e-01 1.957e-02 2.877e-01 7.849e-03 9.637352e-01 4.686329e-03 1.038044e-02 -6.000000e+00 2.629025e-01 225.04 -2.00 3.57 -2.00 322.47 0.00e+00 1.827428e-02 2.669878e-03 7.319844e-03 -6.000000e+00 1.183217e-02 272.57 -2.00 20.00 -2.00 322.06 0.00e+00 7.428 0.008 302.00 328.00 3 3.1379e-01 1.7629e-02 1.0664e-01 -6.0000e+00 6.5186e-01 1.0797e+00 2.3836e-02 9.7780e-02 -6.0000e+00 7.1147e-01 -1.4897e+00 2.2991e-02 3.2992e-02 -6.0000e+00 4.2138e-01 6.1341e-01 1.0762e-02 1.5418e-02 -6.0000e+00 1.7443e-01 1.0028e-04 -2.8466e-03 2.2678e-04 1.7609e-04 -6.0000e+00 1.3654e-02 -2.0063e-03 0.0000e+00 12 8 8 10 0 0 11.13 15.01 0.26 -0.00201 -0.02340 155 29 1 5 0 325.550 21.88 15.01 18.71 -120541 -9794 -127181 6084 -184342 -60512 -46901 -42910 -142238 900000 -160573 -54416 -123112 -53988 -23127 28566 39421 3371 900000 -19029 33365 -38634 158474 -82873 29205 -41697 124423 -63133 5424 -13775 85563 778 -10510 38403 46871 20058 27709 2294 26238 29503 34426 80931 14812 65545 13531 84148 13413 57288 56650 69331 21989 53339 11945 59919 19933 38971 25562 17939 19818 27952 30539 24492 29968 18428 25666 25505 35537 9282 20806 13167 20309 10522 11554 7523 11169 -72 5605 -1408 1814 988 4522 5270 1633 6012 1119 2844 -266 1889 72 1312 -1868 3273 -7033 -5356 -6175 -3153 -3791 -1132 -3098 -2098 -2307 -1328 -1591 -733 -5351 -2769 -1108 -2123 -113 -857 -431 -1805 53 -2458 172 -23 401 -64 572 -918 2223 3241 2430 831 1019 9 2686 1254 -249 256 270 763 576 978 -304 -5 314 396 -1192 -224 -309 63 -1405 -3228 -102 -3812 47 -7405 -673 -424 -358 -3067 900000 -4245 -606 -3683 -1089 -434 378 521 68 900000 -477 464 -1021 1213 -3113 380 -957 952 -1713 87 -287 917 22 -366 828 968 474 636 77 785 944 1126 1920 639 1906 612 2125 653 1913 2049 2411 1361 2671 980 3209 1636 2657 1956 1423 1475 1886 2103 2010 2689 2102 2928 2981 3832 1388 3097 2363 3631 2101 2186 1355 1733 -11 811 -237 350 234 1230 1495 529 1990 409 1074 -108 762 29 503 -702 1223 -2695 -2210 -3016 -1799 -2592 -870 -2659 -1807 -1863 -947 -1040 -469 -3750 -2011 -847 -1803 -107 -952 -540 -2491 74 -3511 234 -31 547 -92 853 -1409 3210 4394 3171 1071 1279 11 3256 1679 -393 470 557 1711 1394 2542 -853 -16 930 1171 -3515 -623 -795 148 -3277 SS 20210225T125702.3Z 7726.539610 257 1 50.62 2 81.08 111.53 103.31 315.46 0.00 1 0.00 1 0 17 6.407e-01 1.275e-02 2.178e-01 3.027e-03 8.405991e-01 1.754917e-03 9.258081e-03 -6.000000e+00 3.823592e-01 225.04 -2.00 3.57 -2.00 322.03 0.00e+00 1.445849e-02 9.652442e-04 1.431006e-03 -6.000000e+00 1.747869e-02 272.57 -2.00 20.00 -2.00 321.61 0.00e+00 6.114 0.004 302.00 328.00 3 3.8969e-01 6.2847e-03 7.7562e-02 -6.0000e+00 9.4472e-01 3.6318e-01 9.8869e-03 5.6499e-02 -6.0000e+00 1.0304e+00 -5.4309e-01 1.1213e-02 2.7015e-02 -6.0000e+00 6.0949e-01 2.2929e-01 5.0742e-03 1.6161e-02 -6.0000e+00 2.5447e-01 3.9380e-04 -1.6295e-03 9.0069e-05 2.2033e-04 -6.0000e+00 1.9940e-02 -2.8803e-03 0.0000e+00 12 8 8 10 0 0 8.39 15.00 0.23 -0.00288 -0.01512 333 62 1 5 0 151.510 21.88 15.00 18.71 -253673 900000 -240155 900000 -243331 900000 -276036 -68609 -254366 89858 -225108 900000 -180321 -55930 -111092 -57232 -57592 -46829 14246 -927 -32553 -55963 118098 -81178 -3183 -86117 149875 -87148 61469 -62296 92620 -23375 60532 -18369 75984 -5645 20951 2151 30739 17993 6688 14978 21309 23963 7819 27584 9239 25765 9590 37050 12273 36890 12814 28883 10235 21272 5187 13310 605 9774 7238 11684 7749 10426 10121 8611 10084 7348 9955 3495 8044 762 3891 -1936 3351 -3763 2523 -5934 2570 -561 2087 -1932 -704 -1932 -1058 -656 174 38 -296 127 -815 -331 -3147 -1176 -3077 -728 -1092 18 -1739 -274 -892 254 197 -387 -2513 -1454 -943 383 629 690 66 -282 -87 -361 280 195 920 -65 71 -738 962 1044 1441 -666 31 -642 1745 971 -509 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