File name: Pandora103s1_Downsview_20210903_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T151350.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20210901.txt Level 1 file used: Pandora103s1_Downsview_20210903_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210903 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210903T111719.6Z 7916.470366 168 1 49.84 2 84.89 84.69 43.89 100.40 0.00 1 0.00 1 0 17 5.709e-01 5.561e-02 4.926e-01 5.353e-02 9.064359e-01 3.116164e-02 1.041339e-02 -6.000000e+00 3.481700e-01 230.17 -2.00 3.57 -2.00 321.99 0.00e+00 -2.551669e-03 1.187716e-02 1.093653e-02 -6.000000e+00 1.543731e-02 285.89 -2.00 20.00 -2.00 321.38 0.00e+00 9.645 0.017 302.00 328.00 3 6.2375e-01 1.0443e-01 1.2463e-01 -6.0000e+00 8.7003e-01 1.8865e+00 1.2415e-01 9.8432e-02 -6.0000e+00 9.4221e-01 -2.0045e+00 7.4066e-02 3.1285e-02 -6.0000e+00 5.5923e-01 7.2373e-01 3.9085e-02 1.0242e-02 -6.0000e+00 2.3248e-01 7.9626e-06 8.5920e-04 1.5150e-03 9.9443e-05 -6.0000e+00 1.7979e-02 -2.6446e-02 0.0000e+00 12 8 8 10 0 0 -54.39 15.01 0.87 -0.02645 -0.01999 22 4 1 5 0 2264.910 21.88 15.01 18.78 31047 82972 6715 -6442 -8482 56402 -69614 900000 -18475 82974 -90171 21842 27836 50135 900000 76104 248866 69061 -3775 13298 230138 72504 290208 97723 36316 10835 -25808 49016 900000 -36416 -66189 -40771 8885 116020 177635 -6081 4850 1796 58928 26195 17835 171603 -2996 95445 72415 -46427 38476 68173 -56041 -40342 16369 48056 -490 76640 20292 28861 93220 47773 -7531 -13203 109356 42342 31357 32699 47872 -2173 29087 34555 41685 -10600 35222 -22427 24043 -10392 62956 -15324 -10880 1706 456 17418 -24140 -2102 17344 35215 8893 10908 22182 28579 4455 9237 -1715 -271 -18764 12932 -8830 3901 -1858 -7841 -6476 4310 -11622 -5337 -8052 -4559 -12817 -2038 -9705 2681 -3090 2227 4427 8886 -2376 2238 -1236 1489 -386 -1114 -56 37 2064 3005 7210 1223 1936 -1256 360 886 3539 -5396 -593 -3226 4775 -371 820 -332 664 -173 -1333 1922 -1616 -2550 2140 2565 4329 613 -560 -627 2943 -8474 900000 -1366 4329 -13329 1243 1716 2853 900000 3971 12984 3931 -430 1198 12007 3783 15141 5098 2239 822 -2571 2557 900000 -3627 -10046 -5415 759 6053 9268 -519 391 170 3633 2485 1946 8953 -398 4980 4534 -8368 3212 4268 -11429 -7462 2050 4764 -77 6398 3070 4065 6809 5234 -1336 -2342 5705 4639 4254 4777 6244 -465 4553 5408 6742 -2916 7167 -7446 5268 -2928 7555 -3598 -2327 338 105 3999 -9823 -779 5791 10472 3619 4553 8564 10437 2022 3807 -743 -110 -9202 4993 -4883 2239 -1319 -6709 -5375 3553 -10490 -4065 -5839 -3187 -10231 -1553 -8507 2266 -3128 2451 5359 11080 -3409 3035 -1690 1950 -524 -1592 -83 56 2983 4108 9066 1589 2434 -1586 449 1188 5318 -10248 -1201 -7287 10737 -948 2217 -950 1927 -508 -3902 5205 -4216 -6252 4901 SS 20210903T113030.8Z 7916.479524 171 1 50.49 2 82.52 86.96 41.63 103.14 0.00 1 0.00 1 0 25 4.650e-01 1.725e-02 3.089e-01 7.644e-03 7.913291e-01 4.452322e-03 1.032576e-02 -6.000000e+00 2.823784e-01 230.17 -2.00 3.57 -2.00 322.07 0.00e+00 1.490250e-02 2.820974e-03 9.334213e-03 -6.000000e+00 1.292453e-02 285.89 -2.00 20.00 -2.00 321.56 0.00e+00 7.108 0.007 302.00 328.00 3 8.5004e-01 1.8530e-02 9.1554e-02 -6.0000e+00 7.0545e-01 6.0200e-01 2.6231e-02 6.5519e-02 -6.0000e+00 7.6391e-01 -8.5580e-01 2.3968e-02 3.7208e-02 -6.0000e+00 4.5347e-01 3.5343e-01 1.0643e-02 1.3092e-02 -6.0000e+00 1.8920e-01 9.9685e-05 -1.3417e-03 2.3173e-04 3.4396e-04 -6.0000e+00 1.4480e-02 -2.7919e-02 0.0000e+00 12 9 8 11 8 0 22.56 14.99 0.31 -0.02792 -0.03800 114 21 1 5 0 442.770 21.88 14.99 18.77 -97683 -140963 -77500 900000 -95253 -234669 -35579 -95043 900000 -166345 -79766 -187964 -57815 -155566 -34295 -60653 87107 109065 69031 33167 -21020 -4184 108282 8980 -62191 -52235 -42064 23967 -30661 -21035 -34286 50024 22058 31927 -18621 30804 -19577 6708 -13180 53450 35760 31160 13812 60324 29929 36214 30942 19700 24718 24440 42824 36349 32479 24336 22268 22973 23862 628 12116 12982 18434 11825 18831 14966 18662 10581 15160 8706 16524 9578 10161 10022 1492 3494 1522 2573 -7041 -6048 -5323 4751 -2918 4347 -3309 2611 -1274 342 21 1435 -563 97 -793 -2635 -3396 -2619 -2235 -3293 -1038 -597 -1125 -3664 -1312 -2080 -1014 -1459 -3216 -4269 -1224 -657 1140 485 1097 -337 63 -198 -107 734 1468 400 -498 -472 610 2341 1651 301 407 720 222 1721 -593 -47 -52 188 126 479 -275 -315 264 441 -448 -285 -130 -239 -510 -993 -2483 -735 900000 -903 -8267 -265 -837 900000 -3043 -648 -5348 -587 -5585 -465 -1274 649 813 566 395 -384 -69 807 127 -1643 -1238 -972 286 -663 -470 -976 820 542 738 -631 689 -703 235 -598 1553 1359 1324 664 2068 1298 1673 1425 1068 1356 1457 2350 2364 2398 2077 2021 2116 2182 71 1190 1258 1773 1354 2296 2129 2731 1699 2331 1498 2922 2044 2340 2383 378 812 328 498 -1436 -1278 -1280 1236 -969 1534 -1390 1109 -597 167 11 748 -298 49 -385 -1237 -1580 -1281 -1241 -2179 -789 -517 -1074 -3653 -1207 -1744 -779 -1119 -2638 -3774 -1120 -648 1235 600 1509 -504 96 -298 -155 1034 2079 600 -793 -773 980 3559 2424 435 570 975 300 2422 -966 -87 -106 419 276 1116 -689 -827 709 1191 -1210 -742 -317 -595 -1242 SS 20210903T114207.4Z 7916.487586 174 1 50.58 2 80.42 88.96 39.65 105.70 0.00 1 0.00 1 0 17 4.421e-01 8.190e-03 1.246e-01 2.618e-03 6.765785e-01 1.507553e-03 8.376120e-03 -6.000000e+00 2.677412e-01 230.17 -2.00 3.57 -2.00 321.68 0.00e+00 8.247736e-03 8.383671e-04 5.636122e-03 -6.000000e+00 1.188895e-02 285.89 -2.00 20.00 -2.00 321.11 0.00e+00 5.727 0.004 302.00 328.00 3 7.4928e-01 5.7055e-03 7.1316e-02 -6.0000e+00 6.6756e-01 1.1771e-01 8.0149e-03 4.8360e-02 -6.0000e+00 7.2225e-01 -1.9559e-01 7.8557e-03 2.7517e-02 -6.0000e+00 4.3035e-01 7.9056e-02 3.6111e-03 9.3373e-03 -6.0000e+00 1.7958e-01 4.7766e-04 -9.1283e-04 8.3922e-05 2.0024e-04 -6.0000e+00 1.3605e-02 -2.8602e-02 0.0000e+00 11 8 0 10 0 0 8.97 15.00 0.19 -0.02860 -0.03546 289 54 1 5 0 174.980 21.88 15.00 18.76 -183063 -91112 -101230 -142552 -141337 -155655 -125336 -141754 -173783 -121102 -126846 -116983 -55261 -107275 -34581 -51507 -34048 -42534 10957 -51829 -32958 -45801 -14331 -21129 -25098 -40348 -23633 -58342 -33404 -35008 -27821 -5994 -8047 533 -5395 -7170 -378 6053 5125 11121 -2599 3156 2596 8561 3189 9916 8806 9072 1792 5124 6047 9122 9549 6384 6911 3385 -130 1310 2031 -1202 5734 5724 6887 3955 4824 3082 5539 3579 3818 1663 2925 63 1242 -1508 -1217 -2778 -1857 -2347 -2520 -1974 -1392 -1064 -2708 -1113 -1120 -389 43 -93 -278 -162 -797 -970 -1856 -833 -1128 -931 -51 232 -840 -918 -954 -310 681 -74 -1602 -1187 -158 684 1420 1314 860 215 592 282 533 701 573 359 -94 -641 42 499 864 -325 -637 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