File name: Pandora103s1_Downsview_20211203_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T164802.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20210901.txt Level 1 file used: Pandora103s1_Downsview_20211203_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20211203 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211203T133315.2Z 8007.564759 71 1 50.93 2 82.23 131.18 75.83 139.16 0.00 1 0.00 1 0 17 4.606e-01 1.797e-02 3.686e-01 1.207e-02 8.098988e-01 7.002326e-03 9.477628e-03 -6.000000e+00 2.725755e-01 222.33 -2.00 3.57 -2.00 322.06 0.00e+00 1.118527e-02 3.881536e-03 4.504633e-03 -6.000000e+00 1.271625e-02 275.10 -2.00 20.00 -2.00 321.60 0.00e+00 6.896 0.006 302.00 328.00 3 1.9132e+00 2.5715e-02 8.1414e-02 -6.0000e+00 6.7017e-01 6.1797e-01 3.6813e-02 4.8016e-02 -6.0000e+00 7.3230e-01 -8.1905e-01 3.7621e-02 3.0499e-02 -6.0000e+00 4.3424e-01 3.3707e-01 1.7355e-02 1.3394e-02 -6.0000e+00 1.8345e-01 4.1318e-05 -1.7815e-03 3.6542e-04 2.4966e-04 -6.0000e+00 1.4596e-02 -5.8764e-03 0.0000e+00 12 9 8 11 8 0 49.75 15.00 0.43 -0.00588 -0.01926 38 7 1 5 0 1340.000 21.88 15.00 18.76 900000 54917 900000 -149075 -128696 -184274 900000 -179807 -16608 -230714 900000 -125137 -79011 900000 9910 -52843 -83677 -54805 -14579 -16373 75893 51609 -57834 39252 -60704 172313 4785 -6203 -45023 18535 52167 -8654 -35135 64574 1372 24304 13777 -30866 36615 -68 2862 -33857 29020 -15150 58168 18614 27701 36630 25923 26617 62900 27588 18270 13781 44330 13296 6342 -6902 4270 16770 3834 18382 13347 24430 11232 31194 16508 20617 -3354 13667 7155 6800 1535 321 -1795 -2141 -5061 -4532 -4944 1361 1056 -408 -312 -3444 741 2039 2396 -1577 2211 -1756 508 -5999 -1374 730 -2872 -2651 1227 1534 -1931 -2091 -2885 -2782 -1012 -1789 -3656 1483 -2062 -1088 -1529 -603 -329 624 262 344 -1014 2143 1032 1433 -1278 -93 559 2757 1284 677 -501 954 2235 1228 -42 -1709 -179 736 229 -366 578 -316 818 -398 -764 -545 269 -514 251 900000 646 900000 -2410 -1549 -3583 900000 -3542 -195 -7785 900000 -1996 -1057 900000 117 -1054 -2509 -1349 -256 -296 893 607 -1482 462 -1677 2026 69 -100 -1109 283 704 -252 -1465 1072 41 575 390 -1543 1125 -3 149 -2651 1307 -1060 2080 996 1414 1807 1511 1673 3108 2105 1658 1387 3485 1434 731 -885 479 1659 450 2094 1810 3325 1838 4263 2624 3337 -760 2942 1762 1717 396 78 -405 -445 -1048 -990 -1249 386 351 -156 -131 -1586 346 993 1214 -848 1134 -900 242 -2904 -636 355 -1658 -1790 930 1317 -1850 -2024 -2636 -2300 -766 -1364 -2988 1224 -1875 -1064 -1685 -745 -450 901 386 498 -1441 2905 1434 2068 -1981 -145 855 3966 1802 930 -679 1238 2865 1703 -67 -3141 -358 1563 519 -894 1478 -848 2219 -1096 -2089 -1430 659 -1194 568 SS 20211203T134553.5Z 8007.573536 74 1 50.61 2 80.55 133.60 74.46 141.76 0.00 1 0.00 1 0 25 4.796e-01 9.455e-03 2.803e-01 4.102e-03 7.245594e-01 2.329976e-03 8.462679e-03 -6.000000e+00 2.830403e-01 222.33 -2.00 3.57 -2.00 321.78 0.00e+00 1.277922e-02 1.235533e-03 1.837587e-03 -6.000000e+00 1.244177e-02 275.10 -2.00 20.00 -2.00 321.32 0.00e+00 5.801 0.004 302.00 328.00 3 1.2808e+00 8.2010e-03 6.8732e-02 -6.0000e+00 6.9511e-01 1.7283e-01 1.2083e-02 4.1417e-02 -6.0000e+00 7.5877e-01 -2.1646e-01 1.3356e-02 2.5754e-02 -6.0000e+00 4.5061e-01 8.7148e-02 6.2026e-03 1.5270e-02 -6.0000e+00 1.8784e-01 2.4524e-04 -1.6785e-03 1.2775e-04 2.1821e-04 -6.0000e+00 1.4768e-02 -5.3930e-03 0.0000e+00 12 8 8 10 0 0 99.90 15.00 0.21 -0.00539 -0.01801 212 39 1 5 0 238.720 21.88 15.00 18.76 -51902 -97554 -141755 -119525 -204968 900000 -129746 10345 -101211 -185889 -117747 -143653 -24745 -156594 -37505 -17913 31326 -80128 264538 -60433 14026 -42998 -31880 -57940 -40543 -51275 -22046 -12066 -7039 18533 -31752 34703 -1742 10863 -19376 -12632 -22923 -4115 -26589 6610 -6436 -1215 -12494 -1236 7999 17931 3452 8150 14015 9332 6322 9225 11815 7376 10163 1974 4324 -3189 3067 -793 8409 6186 10512 1802 6560 1341 7820 2738 3604 2629 159 -915 2088 -1749 -1325 -1328 -1787 -1578 -2536 2418 -1271 -794 -1578 -93 -2084 344 -952 -390 -1097 -56 -329 355 -1483 -338 -1659 -811 317 -368 -1170 -940 -69 400 1730 -525 -2195 -1818 251 281 1485 708 678 -439 29 -166 808 945 1439 592 -67 -1181 -82 1341 311 -341 -881 -325 707 1169 -681 -787 -692 366 259 556 -595 -215 415 144 -699 -363 -50 374 549 -208 -390 -850 -558 -2118 900000 -649 41 -439 -1983 -706 -1388 -108 -2939 -300 -143 194 -1549 1058 -1088 122 -659 -446 -1101 -676 -974 -316 -161 -96 229 -804 555 -46 264 -633 -392 -871 -154 -1366 281 -347 -67 -823 -76 468 993 233 557 970 741 578 917 1258 880 1238 269 581 -457 407 -110 1136 961 1792 348 1378 278 1643 640 867 719 48 -288 625 -509 -377 -346 -451 -420 -782 784 -501 -354 -776 -48 -1167 199 -585 -243 -682 -33 -185 187 -786 -188 -1063 -603 271 -358 -1238 -995 -67 352 1402 -437 -1956 -1714 246 298 1732 935 987 -682 45 -252 1165 1325 2032 880 -105 -1918 -129 2012 453 -483 -1218 -432 924 1616 -1081 -1418 -1369 765 576 1316 -1512 -568 1116 389 -1890 -941 -120 851 1227 SS 20211203T143422.5Z 8007.607205 107 1 51.05 2 74.75 143.44 70.00 152.28 0.00 1 0.00 1 0 17 1.340e-01 9.184e-03 1.075e-01 4.419e-03 4.857197e-01 2.341589e-03 5.905700e-03 -6.000000e+00 7.860731e-02 222.33 -2.00 3.57 -2.00 320.42 0.00e+00 4.941166e-03 8.438978e-04 1.831225e-03 -6.000000e+00 3.448718e-03 275.10 -2.00 20.00 -2.00 319.88 0.00e+00 3.732 0.001 302.00 328.00 3 3.9297e+00 6.9463e-03 4.4366e-02 -6.0000e+00 1.9315e-01 6.6446e-02 8.5585e-03 2.5928e-02 -6.0000e+00 2.1075e-01 -4.4697e-02 7.7849e-03 1.5396e-02 -6.0000e+00 1.2554e-01 1.1544e-02 3.9460e-03 6.5698e-03 -6.0000e+00 5.2506e-02 1.5297e-04 -1.2103e-03 1.4385e-04 9.1369e-05 -6.0000e+00 4.1168e-03 -6.4497e-03 0.0000e+00 11 8 0 10 0 0 99.96 15.00 0.27 -0.00645 -0.01554 44 8 1 5 0 1160.020 21.88 15.00 18.78 -25438 -59802 14776 -47333 778 -95095 16065 -27349 -29856 -54333 2416 10503 -26011 28544 2875 -2667 9217 21661 -4906 6526 -16181 12375 -8175 -3936 -16464 -5030 -8306 7560 3275 8271 -3484 9685 -4724 5910 873 -5150 -7447 6337 1137 -1342 -336 -2278 -1552 -5607 4732 -412 4403 2773 4628 554 6893 2973 4919 1807 3342 721 -1429 -453 -2671 955 558 2151 3328 1894 -277 1679 834 3402 1545 425 -831 -482 -1606 -491 -2090 -2049 -1952 -165 -1017 -1447 -850 -2671 -1664 -905 -405 -670 263 -578 358 -503 29 -239 1297 645 150 -351 999 74 -766 -1356 -180 293 1372 928 -1973 -605 -608 580 1446 1174 210 84 -175 381 767 1892 1686 1087 -451 -758 -746 505 32 92 -647 -1053 697 653 -736 -1199 -1013 -443 -125 172 -80 -302 691 -314 -637 -135 104 346 1145 -309 -1102 140 -765 8 -2251 147 -414 -500 -1195 33 154 -647 526 80 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