File name: Pandora103s1_Downsview_20220224_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T174401.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20210901.txt Level 1 file used: Pandora103s1_Downsview_20220224_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220224T123624.1Z 8090.525279 190 1 50.62 2 84.96 108.09 69.53 191.86 0.00 1 0.00 1 0 25 6.078e-01 6.075e-02 4.326e-01 5.117e-02 8.175942e-01 2.918904e-02 9.649580e-03 -6.000000e+00 3.632760e-01 225.00 -2.00 3.57 -2.00 321.75 0.00e+00 5.059989e-03 9.974259e-03 5.602946e-03 -6.000000e+00 1.653793e-02 272.50 -2.00 20.00 -2.00 321.22 0.00e+00 9.788 0.018 302.00 328.00 3 5.8915e-01 9.2310e-02 1.0748e-01 -6.0000e+00 8.9851e-01 1.8446e+00 1.0549e-01 4.8315e-02 -6.0000e+00 9.8097e-01 -1.8865e+00 6.1946e-02 2.1795e-02 -6.0000e+00 5.8174e-01 6.5937e-01 3.3795e-02 6.2803e-03 -6.0000e+00 2.4134e-01 8.2600e-06 9.0226e-04 1.5364e-03 1.7792e-04 -6.0000e+00 1.9407e-02 -6.2169e-03 0.0000e+00 12 8 8 10 0 0 34.48 15.00 1.03 -0.00622 0.00056 23 4 1 5 0 2200.300 21.88 15.00 18.73 50544 131195 -21567 900000 -48138 81416 297412 185856 -22001 78783 3897 26640 -29021 66842 38226 239355 -26750 900000 43132 57681 900000 10223 900000 9106 44674 900000 -17649 -57100 900000 -83272 131647 484 27128 -32749 204728 46539 11448 -35770 900000 11484 96060 82719 47464 2145 19625 79320 -7176 204921 116320 143994 50187 95748 -1782 49525 -14304 99431 -19179 50838 -3979 81394 -23912 26165 6097 29318 18777 79344 9455 37511 29260 17282 -19496 28087 38187 1647 107203 -31038 32775 -22322 19752 -35350 30063 -3361 -9905 7942 16341 -1939 30457 -11700 5284 13450 -2826 12131 -24355 198 -14221 -7421 1069 15083 -13282 1325 -9326 4081 3545 -3301 -8363 2219 -1871 1807 6881 7949 5700 -1333 1115 -5912 9356 -1530 1425 -2746 1229 -1763 4332 36 4560 -6877 530 -2141 4855 -966 3203 -5035 -830 -1157 2970 1492 -730 -584 -23 607 -363 1236 -2165 2508 -1458 4828 6538 -3672 900000 -7397 4057 14822 9262 -2102 3926 275 1810 -3736 4240 3637 11929 -4888 900000 4104 4443 900000 1065 900000 908 3036 900000 -1919 -8537 900000 -16977 6561 55 2458 -5193 10203 2952 1089 -6158 900000 1509 5658 5621 4516 311 2312 5031 -1073 10212 5797 7176 5002 7158 -339 5834 -3240 7928 -4431 6081 -703 6490 -5092 4042 1160 5260 3837 8699 2073 6543 6124 4479 -6978 6859 7993 451 9082 -9436 5063 -6341 4233 -14094 7941 -1390 -4308 3364 6678 -996 11688 -6255 2555 5697 -1324 4655 -13473 93 -8859 -5067 778 10749 -12216 1149 -8320 2868 2350 -2369 -6669 1692 -1585 1612 6584 8556 6959 -1854 1533 -8544 11237 -2021 1868 -3941 1777 -2671 6045 51 5863 -9664 673 -2720 5806 -1334 4869 -9510 -1663 -2508 6631 3636 -1939 -1618 -63 1707 -1015 3251 -5502 5725 -3436 SS 20220224T124851.8Z 8090.533933 193 1 50.62 2 82.83 110.32 70.05 194.74 0.00 1 0.00 1 0 17 4.527e-01 1.930e-02 3.158e-01 1.026e-02 8.052704e-01 5.916515e-03 9.222761e-03 -6.000000e+00 2.697835e-01 225.00 -2.00 3.57 -2.00 322.12 0.00e+00 1.628401e-02 3.179627e-03 1.294436e-03 -6.000000e+00 1.169134e-02 272.50 -2.00 20.00 -2.00 321.68 0.00e+00 7.392 0.008 302.00 328.00 3 1.0001e+00 2.1231e-02 8.5600e-02 -6.0000e+00 6.6832e-01 7.7824e-01 2.8405e-02 5.1953e-02 -6.0000e+00 7.2908e-01 -1.0054e+00 2.7866e-02 2.4364e-02 -6.0000e+00 4.3303e-01 4.0563e-01 1.3140e-02 1.5817e-02 -6.0000e+00 1.7977e-01 6.3819e-05 -2.1626e-03 3.1341e-04 2.5778e-04 -6.0000e+00 1.3925e-02 -6.3669e-03 0.0000e+00 12 8 8 10 0 0 99.32 14.99 0.37 -0.00637 -0.02262 86 16 1 5 0 588.510 21.88 14.99 18.73 -125224 900000 -92918 -60968 -182810 -29289 -194579 87487 -161738 -89006 -118149 -114489 -70243 1909 -34282 -36883 900000 -63701 40242 -19463 28472 -64423 96099 -21816 71102 -53866 152118 -46039 27725 -18859 13226 -37149 15294 30906 97974 23022 -7181 10609 6675 27079 25075 46776 6891 81183 700 51686 12467 75939 12334 27430 9798 47879 20110 48415 21393 26008 2487 18219 9754 17308 16243 16804 14547 15338 21340 11421 19180 11274 19809 7259 15447 -2072 12271 710 7219 1374 5958 -853 1119 -4356 22 -1868 -1056 -2747 -250 916 -2732 -382 -5709 1186 -3355 -2124 -8499 -137 -4604 1478 -2026 997 -1064 -1316 -1199 819 -2709 -391 -3868 -1616 -116 -670 158 -50 -646 -803 563 -2235 -1180 -503 1889 -379 1351 -808 1973 2281 3145 -332 1159 -85 1624 1789 399 -609 -985 288 379 848 -495 37 561 63 -415 368 -915 225 -1271 -2781 900000 -1664 -739 -6311 -293 -6687 875 -4056 -1105 -2056 -2306 -1221 22 -696 -901 900000 -2407 588 -505 453 -2366 961 -515 711 -1675 1521 -1304 411 -502 317 -1722 481 857 1382 652 -288 410 306 1143 1164 1874 418 2511 47 2233 809 2856 895 1866 862 3242 1908 3710 2177 2569 304 1879 1059 1747 1742 1993 2002 2329 3235 1922 3015 2012 3609 1657 3500 -565 2840 171 1487 274 1099 -178 264 -1284 7 -712 -437 -1229 -115 441 -1424 -199 -3102 583 -1632 -975 -4122 -65 -2632 936 -1552 843 -994 -1245 -1066 647 -2061 -291 -3133 -1359 -102 -646 168 -61 -877 -1163 820 -3284 -1666 -694 2589 -556 2044 -1275 2992 3315 4371 -464 1560 -113 2119 2494 638 -1120 -2010 625 871 2077 -1301 100 1557 176 -1157 983 -2330 532 -2994 SS 20220224T130024.2Z 8090.541946 196 1 50.52 2 80.89 112.43 70.63 197.38 0.00 1 0.00 1 0 17 4.656e-01 9.360e-03 2.092e-01 3.117e-03 7.005316e-01 1.738088e-03 8.210069e-03 -6.000000e+00 2.758765e-01 225.00 -2.00 3.57 -2.00 321.66 0.00e+00 1.278394e-02 8.759870e-04 2.322863e-03 -6.000000e+00 1.185741e-02 272.50 -2.00 20.00 -2.00 321.21 0.00e+00 5.999 0.004 302.00 328.00 3 7.5355e-01 5.8712e-03 6.9489e-02 -6.0000e+00 6.8248e-01 2.0095e-01 8.5890e-03 3.9382e-02 -6.0000e+00 7.4362e-01 -2.6486e-01 9.5528e-03 2.6582e-02 -6.0000e+00 4.4140e-01 1.0721e-01 4.4609e-03 1.6538e-02 -6.0000e+00 1.8320e-01 3.5938e-04 -1.1917e-03 9.6467e-05 2.3142e-04 -6.0000e+00 1.4311e-02 -7.6716e-03 0.0000e+00 12 8 8 10 0 0 27.40 15.00 0.18 -0.00767 -0.01663 250 47 1 5 0 201.990 21.88 15.00 18.76 -215339 82112 -177462 -26957 -200862 -105486 -212908 -113977 -165631 -14396 -156293 -20572 -92741 -30449 -62666 -46113 -10859 -65447 66672 -37268 67432 -59475 25054 -44703 -11714 -54637 -35489 -41505 -1715 -27695 26558 -4114 26869 -4343 15997 -7510 5923 5087 -127 12990 -3695 3572 10248 9758 -235 17127 1951 17350 893 9749 7302 13793 6891 10378 4721 8317 205 1 704 3010 6066 6568 9653 4491 6893 4943 7411 3121 4923 594 1293 -991 -404 -1938 -1175 -4253 -2649 -2184 197 -425 -611 -1649 -2291 -1205 -1459 -347 -287 550 -731 213 -620 -574 -1920 -677 -2006 -267 -631 310 -998 -98 -780 -31 995 33 -1728 -1195 -259 1140 1583 1074 758 -48 -6 -393 392 -139 1073 -47 305 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