File name: Pandora103s1_Downsview_20220402_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T181401.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20210901.txt Level 1 file used: Pandora103s1_Downsview_20220402_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220402 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220402T113054.5Z 8127.479798 44 1 50.46 2 84.83 88.00 93.66 75.66 0.00 1 0.00 1 0 25 7.086e-01 6.975e-02 5.347e-01 6.410e-02 1.176348e+00 3.890712e-02 1.410750e-02 -6.000000e+00 4.349150e-01 227.13 -2.00 3.57 -2.00 322.11 0.00e+00 -3.832380e-02 1.260296e-02 7.354609e-03 -6.000000e+00 1.897909e-02 275.89 -2.00 20.00 -2.00 321.52 0.00e+00 9.594 0.017 302.00 328.00 3 4.9194e-01 1.2571e-01 1.3747e-01 -6.0000e+00 1.0832e+00 2.4959e+00 1.4659e-01 1.3498e-01 -6.0000e+00 1.1820e+00 -2.4672e+00 8.5955e-02 3.2800e-02 -6.0000e+00 6.9249e-01 7.9733e-01 4.8459e-02 3.0444e-02 -6.0000e+00 2.8255e-01 6.4670e-06 -3.6169e-04 1.6120e-03 4.3195e-04 -6.0000e+00 2.2939e-02 -8.6197e-03 0.0000e+00 12 8 8 10 0 0 -104.10 14.97 0.98 -0.00862 -0.01134 22 4 1 5 0 2293.240 21.58 14.97 18.31 203705 18541 -15905 83234 900000 -34025 900000 13821 8185 56073 113724 69832 -33389 900000 117768 -6189 -677 -46342 157395 -59268 59912 117797 -50233 51649 -53257 319493 65725 900000 13386 -17094 162834 280672 35254 900000 202800 -34888 -29988 34431 14428 265067 64403 -28836 31766 822 85971 -8908 33421 -43658 155353 31225 48467 58758 111925 900000 69978 39406 900000 64584 225669 -64577 22150 63922 40494 -40367 900000 -12275 13175 -151 -12907 38277 -9002 84723 -8881 136234 26151 -21460 -25683 -8193 -27646 890 24847 -5268 4997 45543 4598 15590 742 -463 11537 -7239 36443 -9804 18373 -29317 -8875 -5916 14287 21473 15773 -12334 -745 -15968 3434 6497 5627 -6486 7859 -2265 2127 -2103 2782 3604 4800 -1322 -9765 7446 8173 979 -4492 6575 2720 -1191 -5529 3467 -4196 3533 -4332 3724 -6187 3284 2091 -1475 998 -5144 1416 -57 1313 -554 1222 -2003 3152 -1427 1254 12714 1639 -1655 5195 900000 -3009 900000 1078 766 3500 7098 4359 -5383 900000 7350 -773 -77 -7954 9824 -9864 3739 7352 -7838 3810 -11634 19941 4102 900000 987 -1649 10163 17518 2400 900000 12658 -4157 -3743 2735 1719 16544 5847 -6545 3605 112 5366 -1061 2465 -6936 9696 2658 3850 4667 6986 900000 6353 5143 900000 6230 14085 -17588 2388 4715 4136 -10078 900000 -2438 2093 -30 -3296 6515 -2605 10576 -2419 8503 4244 -4505 -5392 -1534 -7216 207 5357 -1763 1673 10853 1722 5396 303 -189 3993 -2834 9553 -3616 5848 -15304 -4431 -3390 7782 12305 10292 -10637 -528 -11688 1890 3428 3129 -4306 4816 -1696 1762 -2136 3094 4376 6046 -1786 -14129 8957 9878 1317 -6575 8581 3519 -1500 -6933 3875 -4952 3769 -5088 4480 -9724 5552 4081 -3307 2394 -14359 3986 -170 3942 -1686 3564 -5681 7761 -3384 2839 SS 20220402T114358.6Z 8127.488873 47 1 50.48 2 82.47 90.25 91.40 77.83 0.00 1 0.00 1 0 17 5.172e-01 1.800e-02 3.416e-01 9.292e-03 9.715520e-01 5.510168e-03 1.067071e-02 -6.000000e+00 3.097401e-01 227.13 -2.00 3.57 -2.00 322.41 0.00e+00 1.789052e-02 3.421271e-03 2.490912e-03 -6.000000e+00 1.374032e-02 275.90 -2.00 20.00 -2.00 322.00 0.00e+00 7.082 0.007 302.00 328.00 3 8.9994e-01 2.1908e-02 9.3223e-02 -6.0000e+00 7.7009e-01 9.4695e-01 3.1161e-02 7.3849e-02 -6.0000e+00 8.3819e-01 -1.3172e+00 3.1082e-02 3.0322e-02 -6.0000e+00 4.9767e-01 5.3828e-01 1.4044e-02 1.6471e-02 -6.0000e+00 2.0651e-01 7.5598e-05 -2.3751e-03 2.6385e-04 2.7051e-04 -6.0000e+00 1.6029e-02 -9.5230e-03 0.0000e+00 12 8 8 10 0 0 45.82 14.99 0.33 -0.00952 -0.02737 111 21 1 5 0 454.710 21.58 14.99 18.31 -172352 -45517 900000 -162628 -58761 -223293 -6116 -146759 -185538 -137401 -180644 -102945 900000 -61554 -15620 -84464 -42309 -84802 900000 41358 -12816 -56001 -60338 124887 -47673 -25225 -91812 47198 -80980 -14931 -33184 94568 -12584 34923 -47800 -8020 54168 17213 -4472 22808 57608 39434 49573 8259 39245 37163 50362 62917 42089 40681 51617 42157 63243 53520 50651 17489 52071 25321 15330 12720 7700 29126 16175 26504 25389 15088 26530 21313 16279 16642 16151 13742 12055 11498 -5357 6497 -5038 -1777 -87 2953 183 8598 -87 5950 -1025 4300 2832 2528 1361 -296 1105 -3199 -3042 -7846 -3583 -3308 -139 -2207 -1801 -2669 -2603 -2069 -863 -990 -4400 -2786 -2789 -383 -813 -569 -509 -313 -1372 -433 -608 285 480 -30 540 516 1163 2066 2393 1425 416 -293 1159 1606 -719 -19 414 687 953 373 -444 -539 598 333 -746 -290 -94 -532 -649 -3772 -412 900000 -3481 -532 -6236 -55 -1933 -3514 -1584 -3421 -1102 900000 -811 -167 -2156 -801 -2653 900000 412 -190 -1199 -1292 1131 -864 -388 -2419 427 -2067 -257 -792 857 -342 664 -1810 -198 834 437 -147 702 1357 1179 1392 326 1280 1279 1596 1880 1677 1805 2291 2083 3036 2732 2753 1339 2787 1710 1098 922 615 2110 1545 2597 2718 1839 2949 2667 2399 2741 2872 2546 2184 1922 -948 925 -784 -290 -17 661 50 2499 -30 2097 -409 1706 1189 1084 583 -124 432 -1254 -1200 -3547 -1820 -2018 -98 -1681 -1500 -2278 -2081 -1601 -602 -681 -3275 -2170 -2324 -342 -832 -618 -627 -418 -1918 -597 -820 376 643 -43 791 768 1672 3044 3351 1957 563 -388 1523 2281 -1213 -33 835 1507 2250 955 -1224 -1553 1736 969 -2159 -797 -238 -1250 -1482 SS 20220402T115539.4Z 8127.496984 50 1 50.46 2 80.36 92.28 89.36 79.76 0.00 1 0.00 1 0 17 6.258e-01 9.856e-03 1.850e-01 3.183e-03 8.341685e-01 1.832060e-03 9.518317e-03 -6.000000e+00 3.739308e-01 227.13 -2.00 3.57 -2.00 321.97 0.00e+00 1.463900e-02 1.028790e-03 1.984518e-03 -6.000000e+00 1.641414e-02 275.90 -2.00 20.00 -2.00 321.52 0.00e+00 5.698 0.004 302.00 328.00 3 8.9295e-01 6.7402e-03 7.3015e-02 -6.0000e+00 9.2852e-01 3.0011e-01 1.0441e-02 5.0381e-02 -6.0000e+00 1.0095e+00 -4.2379e-01 1.1660e-02 2.8733e-02 -6.0000e+00 5.9966e-01 1.7456e-01 5.2692e-03 1.6816e-02 -6.0000e+00 2.4952e-01 3.3867e-04 -1.7505e-03 9.2854e-05 2.6140e-04 -6.0000e+00 1.9334e-02 -1.0580e-02 0.0000e+00 12 8 8 10 0 0 -23.34 15.00 0.21 -0.01058 -0.02373 239 45 1 5 0 211.080 21.58 15.00 18.36 -140788 -223365 900000 -255602 -165090 -268260 -176831 -219581 -154467 -219011 -159945 -184983 -139777 -88793 -48520 -58625 -87833 -241 -68241 -37443 -56898 -29007 -58933 -35863 -91912 -13225 -52003 -50995 -66743 1605 -38047 -3301 -27330 24765 -3138 -15328 -29841 -21612 -17601 -3578 12674 9149 20488 -1207 23252 10241 16710 13962 19539 14058 22676 10819 18289 9180 15908 3241 7359 1278 1257 6070 6871 10467 6673 9241 6606 8918 4304 6788 4413 4735 2975 3006 -901 -162 -2624 -87 -4560 -1038 -2074 1169 -478 -177 -1577 -1133 -674 -918 -286 -864 169 -256 151 -2538 -1580 -2654 -1349 -1610 666 -543 -113 -1187 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