File name: Pandora103s1_Downsview_20220419_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T181323.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20210901.txt Level 1 file used: Pandora103s1_Downsview_20220419_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220419T155927.1Z 8144.666286 375 1 15.54 2 36.52 146.85 129.21 273.79 0.00 1 0.00 1 0 17 1.655e-02 8.861e-03 1.237e-02 5.067e-03 2.313660e-01 2.670847e-03 2.806873e-03 -6.000000e+00 9.952024e-03 228.52 -2.00 3.57 -2.00 316.76 0.00e+00 1.117775e-03 3.303039e-04 2.216488e-04 -6.000000e+00 4.306858e-04 277.85 -2.00 20.00 -2.00 316.12 0.00e+00 1.243 0.000 302.00 328.00 3 6.2832e+00 6.9918e-03 1.7237e-02 -6.0000e+00 2.4781e-02 5.8981e-02 7.8257e-03 1.1934e-02 -6.0000e+00 2.6893e-02 -1.2257e-02 4.5581e-03 5.8776e-03 -6.0000e+00 1.5968e-02 -3.5483e-03 2.1186e-03 1.7320e-03 -6.0000e+00 6.6245e-03 2.1470e-04 -3.6738e-04 1.6215e-04 2.1276e-05 -6.0000e+00 5.0909e-04 -2.0111e-02 0.0000e+00 12 9 1 12 9 1 99.98 15.00 0.07 -0.02011 -0.02287 3 2 1 5 0 3841.300 21.79 15.00 18.54 -2907 224 -3177 -6420 -7230 -2363 3184 2413 -2773 -2234 -497 -933 627 2056 -1433 3210 3542 1590 2559 3021 -1007 2981 4287 -679 -2442 -286 -3089 -1578 -1267 -328 47 -1055 1786 -3845 -2774 -3378 443 64 731 -669 358 -484 -239 -1777 -472 -68 134 -798 -1103 306 129 1114 1821 1552 2173 881 1101 113 819 1373 1706 2018 1026 581 -1208 34 -195 968 1399 67 -84 270 -243 94 -521 -1496 -2577 -1882 -2294 -1759 -1244 -1826 -1684 -320 -31 -44 454 483 935 406 -425 -1321 580 846 -525 -731 50 -454 356 -605 -151 -786 539 -221 -1743 -848 113 314 1518 1082 1222 1389 617 -21 63 394 42 686 -515 -343 -495 961 793 -98 154 -549 -142 71 -1227 -681 -1144 -463 420 -38 -155 -414 282 245 189 -273 -280 262 430 -459 36 -525 -1024 -1074 -327 445 377 -488 -400 -88 -174 128 467 -373 855 979 462 760 917 -321 917 1324 -229 -872 -102 -1102 -532 -408 -104 16 -376 651 -1474 -1022 -1251 172 29 375 -386 219 -310 -156 -1179 -310 -44 86 -504 -688 191 83 752 1278 1126 1603 668 840 86 618 1035 1320 1644 891 522 -1090 29 -156 762 1158 60 -81 267 -240 90 -474 -1272 -2056 -1448 -1835 -1520 -1164 -1836 -1776 -348 -36 -52 562 609 1169 496 -496 -1451 592 846 -551 -821 60 -581 468 -797 -190 -939 624 -263 -2197 -1108 152 433 2155 1601 1856 2112 919 -29 84 510 54 911 -720 -499 -733 1402 1134 -138 209 -720 -180 90 -1636 -946 -1646 -673 617 -58 -244 -673 467 410 317 -455 -455 415 676 SS 20220419T160428.0Z 8144.669768 378 1 50.94 2 36.04 148.76 130.07 274.66 0.00 1 0.00 1 0 17 1.406e-02 7.397e-03 9.890e-03 3.392e-03 2.287771e-01 1.780436e-03 2.773643e-03 -6.000000e+00 8.453963e-03 228.52 -2.00 3.57 -2.00 317.36 0.00e+00 8.890110e-04 2.520694e-04 2.768885e-04 -6.000000e+00 3.659381e-04 277.85 -2.00 20.00 -2.00 316.69 0.00e+00 1.236 0.000 302.00 328.00 3 6.1012e+00 4.6995e-03 1.7107e-02 -6.0000e+00 2.1050e-02 5.0277e-02 5.2774e-03 1.1820e-02 -6.0000e+00 2.2846e-02 -8.1432e-03 3.1293e-03 5.8371e-03 -6.0000e+00 1.3565e-02 -2.4204e-03 1.4892e-03 1.6794e-03 -6.0000e+00 5.6264e-03 2.6132e-04 -5.5435e-04 1.1042e-04 2.0904e-05 -6.0000e+00 4.3255e-04 -1.8715e-02 0.0000e+00 11 8 0 10 0 0 99.99 15.00 0.33 -0.01871 -0.02288 52 10 1 5 0 979.450 21.79 15.00 18.55 1696 -1208 -1929 -3089 -5550 -2623 1717 -3500 -1490 -4870 36 1844 1573 -1082 2456 -129 290 2882 1449 1542 305 742 964 -1781 -524 -788 -4678 -2189 -1547 3215 2330 1127 -1990 -3668 -2606 -1639 -726 41 752 -352 -701 648 -435 359 614 -243 -432 -373 -488 1208 998 931 1489 538 790 1144 651 -253 326 609 1448 2128 2239 463 -970 -423 -57 864 1208 302 -129 69 -671 -154 -747 -689 -1985 -885 -1591 -1527 -1699 -2137 -1947 78 -151 452 366 585 674 64 187 -751 -348 -134 -394 -240 460 -235 -657 -395 -508 -523 807 352 -1454 -1076 26 193 1139 927 772 303 396 459 453 1134 196 329 -104 -338 -354 615 209 224 7 -217 57 327 -802 -1121 -1296 -486 62 533 -173 107 501 26 -57 -60 -254 -291 495 210 -162 -258 -390 -663 -297 199 -474 -213 -736 5 276 262 -209 511 -29 69 688 362 396 80 195 257 -510 -155 -238 -1433 -624 -419 822 629 331 -633 -1187 -808 -504 -241 16 335 -178 -384 366 -254 209 358 -142 -247 -208 -268 660 570 564 944 357 536 789 455 -178 225 421 1028 1597 1789 390 -819 -334 -42 623 925 256 -118 65 -634 -140 -640 -540 -1447 -616 -1161 -1224 -1504 -2058 -1985 82 -168 532 452 737 844 78 214 -798 -343 -129 -397 -262 544 -301 -881 -524 -639 -616 914 412 -1828 -1422 35 273 1667 1425 1229 486 615 669 618 1467 254 443 -149 -506 -543 930 309 321 9 -285 72 415 -1077 -1596 -1919 -728 94 839 -286 184 880 47 -102 -106 -437 -488 817 SS 20220419T170221.1Z 8144.709966 412 1 49.95 2 32.60 173.33 139.90 285.89 0.00 1 0.00 1 0 17 1.183e-02 7.073e-03 4.137e-03 1.702e-03 2.121755e-01 8.952197e-04 2.577082e-03 -6.000000e+00 7.110016e-03 228.53 -2.00 3.57 -2.00 316.83 0.00e+00 8.247659e-04 1.118560e-04 1.881684e-04 -6.000000e+00 3.077907e-04 277.86 -2.00 20.00 -2.00 316.18 0.00e+00 1.186 0.000 302.00 328.00 3 5.4784e+00 2.3449e-03 1.6131e-02 -6.0000e+00 1.7704e-02 2.1529e-02 2.6249e-03 1.0959e-02 -6.0000e+00 1.9214e-02 -7.6789e-03 1.5292e-03 5.3959e-03 -6.0000e+00 1.1409e-02 -2.2667e-03 7.0981e-04 1.5474e-03 -6.0000e+00 4.7317e-03 5.3479e-04 -6.8086e-04 5.4908e-05 1.9636e-05 -6.0000e+00 3.6380e-04 -1.8205e-02 0.0000e+00 11 9 0 11 8 0 99.76 15.00 0.18 -0.01820 -0.02332 27 5 1 5 0 1849.620 21.79 15.00 18.54 -1429 -2157 -4111 -3744 -2834 -604 898 42 -575 -3380 -2778 -676 -30 628 339 406 1658 1459 1237 714 1288 2253 1752 31 542 -1550 -2772 -2163 -1319 -536 744 167 -1847 -3953 -2260 39 1251 816 46 -194 -344 23 -221 -175 317 -547 -374 -707 -186 1610 932 734 1366 1189 776 1435 431 120 523 1279 1789 1913 1300 666 -651 -124 100 1077 1479 52 -484 -34 -659 -785 -934 -1590 -1172 -831 -677 -1854 -2014 -1932 -1861 -653 -19 244 229 379 576 141 72 -516 78 360 -120 -137 -177 -99 -708 -690 -566 -203 554 442 -1168 -625 -343 247 1031 1022 665 408 511 363 849 849 755 322 -25 -507 -41 103 309 43 74 -305 392 357 -557 -774 -938 -659 -95 375 -202 -156 438 149 -133 -21 -98 -204 175 -228 -365 -699 -592 -410 -83 130 7 -101 -622 -510 -127 -6 145 87 111 463 421 368 219 399 692 549 10 187 -555 -980 -725 -419 -167 238 57 -677 -1477 -806 14 469 355 24 -110 -209 14 -143 -114 205 -353 -237 -438 -113 968 585 486 942 849 568 1064 325 90 389 950 1364 1540 1114 593 -578 -104 79 827 1196 47 -461 -33 -647 -748 -844 -1333 -906 -619 -521 -1568 -1862 -1916 -1941 -705 -21 290 284 479 724 173 84 -560 79 357 -124 -152 -212 -125 -938 -907 -710 -239 636 521 -1467 -819 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