File name: Pandora103s1_Downsview_20220820_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T204117.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20220521.txt Level 1 file used: Pandora103s1_Downsview_20220820_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220820T104002.3Z 8267.444471 191 1 50.71 2 88.75 73.99 25.96 133.39 0.00 1 0.00 1 0 36 2.040e-02 2.006e-02 1.216e-03 1.204e-03 1.456898e+04 8.091577e+01 9.373321e+02 -6.000000e+00 1.076319e+03 287.07 -2.00 20.00 -2.00 505.56 0.00e+00 3.891438e-03 3.302985e-05 1.972153e-04 -6.000000e+00 5.642866e-04 287.07 -2.00 20.00 -2.00 501.38 0.00e+00 1.601024e+00 2.209820e-02 1.085326e-01 -6.000000e+00 3.908301e-01 231.47 -2.00 3.57 -2.00 502.83 0.00e+00 17.922 0.112 489.00 513.00 1 5.7294e+00 1.6859e-03 3.1375e-02 -6.0000e+00 2.9917e-02 -7.5194e-02 4.2617e-04 3.0114e-03 -6.0000e+00 7.8866e-03 4.3122e-04 2.6509e-03 8.5936e-05 1.1055e-04 -6.0000e+00 1.5839e-03 -6.1536e-04 1.1465e-05 12 8 8 10 0 0 99.95 15.00 8.86 -0.00062 0.01777 24 4 1 4 0 2112.510 21.98 15.00 18.88 -7036 -5121 -2291 -846 130 1305 1795 1689 1073 -188 -746 -1649 -2525 -2957 -2958 -2339 -767 771 1542 1603 1132 1217 1436 1875 2321 2325 1937 472 -2198 -3611 -3158 -2206 61 1998 2529 1600 570 229 -175 10 561 1467 1998 2798 3349 2946 2154 1485 493 -1352 -3015 -4020 -3564 -1836 269 1471 1888 1981 1652 2050 2272 2534 2462 2287 1134 346 -471 -654 -1776 -2391 -2271 -1413 -508 222 -65 -1264 -2405 -2762 -2985 -2287 -1600 -1227 -1362 -694 -617 -606 -620 -556 -22 5 1105 2441 2608 2212 1621 1081 -74 -2041 -3711 -4426 -3580 -1828 618 1446 1197 -184 -1244 -1926 -1595 -438 368 1025 1912 2582 3126 3559 3510 2656 821 104 -600 -618 651 1332 1147 1239 691 373 720 429 -935 -1572 -2355 -2891 -2171 -918 261 897 1157 949 744 883 1233 1786 1193 187 -1892 -3495 -3732 -2988 -6225 -4618 -1945 -732 114 1160 1616 1529 967 -169 -665 -1466 -2233 -2606 -2612 -2081 -690 709 1438 1494 1062 1144 1356 1787 2220 2223 1858 452 -2069 -3345 -2920 -2060 59 1967 2515 1589 566 226 -172 10 556 1465 2022 2860 3440 3037 2217 1519 500 -1353 -2980 -3948 -3497 -1832 275 1535 1848 1939 1616 2000 2236 2515 2456 2277 1127 340 -461 -637 -1726 -2306 -2192 -1369 -498 220 -64 -1241 -2334 -2660 -2867 -2181 -1531 -1180 -1322 -682 -614 -605 -616 -546 -22 4 1090 2437 2612 2169 1540 995 -67 -1844 -3346 -3975 -3240 -1700 599 1468 1242 -192 -1295 -1993 -1662 -463 395 1103 2051 2759 3338 3859 3902 2801 870 108 -659 -670 704 1456 1179 1282 721 390 756 452 -975 -1621 -2443 -3019 -2298 -993 285 985 1293 1078 854 1022 1430 2064 1383 216 -2176 -3998 -4274 -3457 SQ 20220820T104347.9Z 8267.447082 195 1 50.79 2 88.09 74.64 25.48 134.98 0.00 1 0.00 1 0 29 1.723e-02 1.681e-02 7.579e-04 7.520e-04 1.517757e+04 5.014758e+01 9.858567e+02 -6.000000e+00 9.090821e+02 287.07 -2.00 20.00 -2.00 505.50 0.00e+00 3.733372e-03 2.064448e-05 1.988428e-04 -6.000000e+00 4.766036e-04 287.07 -2.00 20.00 -2.00 501.30 0.00e+00 1.523047e+00 1.394754e-02 1.056607e-01 -6.000000e+00 3.300887e-01 231.47 -2.00 3.57 -2.00 502.76 0.00e+00 16.221 0.083 489.00 513.00 1 5.2766e+00 1.0680e-03 2.7491e-02 -6.0000e+00 2.5268e-02 -8.6120e-02 2.7033e-04 2.8710e-03 -6.0000e+00 6.6606e-03 8.6549e-04 1.4227e-03 5.3553e-05 1.1955e-04 -6.0000e+00 1.3377e-03 -3.5989e-03 3.2225e-05 12 8 8 10 0 0 99.86 15.00 7.06 -0.00360 0.00627 42 8 1 4 0 1208.940 21.98 15.00 18.88 -5823 -4145 -1820 -651 333 1172 1949 1820 1078 271 -475 -1229 -2104 -2569 -2358 -1679 -770 698 1199 1024 989 1134 1317 1682 1955 1792 1618 578 -1727 -2902 -2795 -2133 -253 1571 1980 1290 722 244 -450 -277 173 951 1784 2356 2715 2340 1920 1232 294 -1324 -2632 -3396 -3216 -1771 16 1235 1594 1602 1460 1403 1622 2136 1960 1921 1058 177 -375 -683 -1551 -2118 -1926 -1191 -539 -19 -86 -1078 -1845 -2382 -2443 -2311 -1271 -1013 -1233 -699 -352 -411 -532 -589 -263 -107 730 1793 2308 1976 1562 1039 -75 -1572 -3231 -3591 -3083 -1809 106 1202 926 32 -1094 -1724 -1404 -373 188 914 1627 2213 2496 3163 3092 2199 873 229 -356 -258 591 1153 1053 1156 706 517 700 532 -642 -1317 -1854 -2431 -1820 -755 255 707 1177 834 653 594 1171 1496 1178 218 -1512 -2882 -3127 -2617 -4812 -3495 -1574 -576 298 1068 1796 1689 998 248 -434 -1118 -1903 -2315 -2123 -1520 -709 658 1150 985 953 1095 1276 1645 1924 1767 1597 568 -1665 -2740 -2639 -2036 -247 1482 1894 1231 685 230 -425 -262 164 911 1727 2309 2681 2321 1895 1209 286 -1269 -2480 -3169 -3000 -1682 16 1231 1610 1620 1473 1416 1651 2188 2021 1975 1083 180 -377 -685 -1548 -2095 -1905 -1183 -542 -19 -88 -1089 -1833 -2351 -2400 -2266 -1245 -999 -1228 -705 -360 -421 -543 -596 -264 -108 742 1848 2385 1997 1525 982 -70 -1450 -2974 -3277 -2840 -1717 106 1176 928 32 -1098 -1718 -1407 -380 194 948 1685 2284 2579 3307 3319 2405 956 247 -376 -269 614 1213 1117 1233 760 556 756 578 -689 -1396 -1972 -2605 -1976 -789 270 755 1274 921 729 669 1318 1682 1327 244 -1685 -3185 -3456 -2924 SQ 20220820T110129.7Z 8267.459371 204 1 36.91 2 85.00 77.66 23.39 143.12 0.00 1 0.00 1 0 22 7.684e-03 7.562e-03 1.543e-04 1.539e-04 1.332634e+04 1.013111e+01 8.881996e+02 -6.000000e+00 4.053978e+02 287.07 -2.00 20.00 -2.00 505.39 0.00e+00 2.683336e-03 4.182312e-06 1.570025e-04 -6.000000e+00 2.125592e-04 287.07 -2.00 20.00 -2.00 500.92 0.00e+00 1.015181e+00 2.893824e-03 8.638822e-02 -6.000000e+00 1.473096e-01 231.47 -2.00 3.57 -2.00 502.43 0.00e+00 9.795 0.018 489.00 513.00 1 3.0619e+00 2.2094e-04 1.6210e-02 -6.0000e+00 1.1275e-02 -6.7805e-02 5.6990e-05 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