File name: Pandora103s1_Downsview_20220924_L2Fit_fout2c10d20181123p1-8.txt File generation date: 20241101T211218.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v10d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20220912.txt Level 1 file used: Pandora103s1_Downsview_20220924_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1310 305.2711 305.4113 305.5515 305.6916 305.8318 305.9719 306.1121 306.2522 306.3924 306.5325 306.6726 306.8128 306.9529 307.0930 307.2331 307.3733 307.5134 307.6535 307.7936 307.9337 308.0738 308.2139 308.3540 308.4941 308.6341 308.7742 308.9143 309.0544 309.1944 309.3345 309.4746 309.6146 309.7546 309.8947 310.0347 310.1748 310.3148 310.4548 310.5948 310.7348 310.8749 311.0149 311.1549 311.2948 311.4348 311.5748 311.7148 311.8548 311.9947 312.1347 312.2746 312.4146 312.5545 312.6945 312.8344 312.9743 313.1142 313.2541 313.3940 313.5339 313.6738 313.8137 313.9536 314.0935 314.2333 314.3732 314.5131 314.6529 314.7927 314.9326 315.0724 315.2122 315.3520 315.4918 315.6316 315.7714 315.9112 316.0510 316.1908 316.3305 316.4703 316.6100 316.7498 316.8895 317.0292 317.1689 317.3086 317.4483 317.5880 317.7277 317.8674 318.0071 318.1467 318.2864 318.4260 318.5657 318.7053 318.8449 318.9845 319.1242 319.2638 319.4033 319.5429 319.6825 319.8221 319.9616 320.1012 320.2407 320.3802 320.5198 320.6593 320.7988 320.9383 321.0778 321.2172 321.3567 321.4962 321.6356 321.7751 321.9145 322.0539 322.1933 322.3327 322.4721 322.6115 322.7509 322.8903 323.0296 323.1690 323.3083 323.4477 323.5870 323.7263 323.8656 324.0049 324.1442 324.2834 324.4227 324.5620 324.7012 324.8404 324.9797 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220924T114031.4Z 8302.486474 84 1 51.16 2 84.88 95.72 68.35 97.56 0.00 1 0.00 1 0 25 6.492e-01 5.239e-02 4.659e-01 4.286e-02 9.425234e-01 2.561472e-02 1.062292e-02 -6.000000e+00 3.944873e-01 227.98 -2.00 3.57 -2.00 322.21 0.00e+00 -1.868778e-02 1.055710e-02 9.493258e-03 -6.000000e+00 1.835297e-02 283.75 -2.00 20.00 -2.00 321.65 0.00e+00 9.640 0.017 302.00 328.00 3 4.3526e-01 8.9411e-02 1.3095e-01 -6.0000e+00 9.7836e-01 1.7342e+00 1.0591e-01 1.1872e-01 -6.0000e+00 1.0625e+00 -2.1030e+00 6.2685e-02 2.9805e-02 -6.0000e+00 6.3311e-01 7.8042e-01 3.3463e-02 2.1254e-02 -6.0000e+00 2.6343e-01 1.1331e-05 -7.7223e-04 1.2571e-03 2.3086e-04 -6.0000e+00 2.0167e-02 -3.7778e-02 0.0000e+00 12 8 8 10 0 0 -22.34 15.00 0.68 -0.03778 -0.04358 38 7 1 5 0 1345.890 21.79 15.00 18.58 -5386 76270 36408 44490 -50354 275111 31979 220937 -64672 68015 -53517 107734 52341 -1362 92645 26580 900000 -45025 180900 -4700 900000 70171 31697 40427 900000 23488 900000 -14691 144096 -56740 287337 -16251 32143 24101 45983 -62800 -22581 33043 -30564 231890 85829 42188 21787 179599 14805 48784 -65051 91131 19690 260785 5503 108257 30369 -6092 54788 22858 -6952 40588 44590 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-7100 933 -4039 -6810 -5950 -10081 -764 -6372 3614 -28 5279 -1474 10922 753 -1256 3625 5344 -4654 1707 -863 7323 -2068 3962 -6167 7034 1078 -2282 8763 -2639 4242 1101 -2233 -7263 -69 -1777 5066 -3374 3836 -4206 3006 -8143 4301 2106 SS 20220924T115357.2Z 8302.495801 87 1 25.75 2 82.47 98.08 66.05 100.01 0.00 1 0.00 1 0 25 4.707e-01 1.710e-02 3.169e-01 1.083e-02 8.166374e-01 6.389061e-03 9.285395e-03 -6.000000e+00 2.905344e-01 227.98 -2.00 3.57 -2.00 322.04 0.00e+00 3.816844e-03 3.828199e-03 4.385862e-03 -6.000000e+00 1.282320e-02 283.75 -2.00 20.00 -2.00 321.54 0.00e+00 7.078 0.007 302.00 328.00 3 1.3693e+00 2.5512e-02 8.5431e-02 -6.0000e+00 7.2335e-01 6.1826e-01 3.5116e-02 5.3849e-02 -6.0000e+00 7.8616e-01 -9.2179e-01 3.1687e-02 2.7372e-02 -6.0000e+00 4.6286e-01 3.8948e-01 1.4364e-02 7.7072e-03 -6.0000e+00 1.9071e-01 6.1606e-05 -1.5638e-03 3.3031e-04 1.5634e-04 -6.0000e+00 1.4958e-02 -3.7527e-02 0.0000e+00 12 9 9 12 9 1 92.32 15.00 0.13 -0.03753 -0.04928 29 11 1 5 0 852.200 21.79 15.00 18.58 -164007 -170430 -101576 -136721 -122566 900000 900000 900000 -24433 -183495 110285 -28027 -122651 -67722 39301 900000 231298 -26812 23222 900000 -55210 40608 -75695 28964 -78943 37500 -69540 -47241 -65922 -25049 20882 6189 7082 19724 46621 94418 1907 47934 43324 -6929 23407 12611 61959 9316 -7958 1608 -603 34618 26032 11074 27178 37401 34734 15321 60008 20756 49818 7773 28593 17432 10933 10236 17087 19160 9992 17146 14323 10286 4702 4269 4524 6577 759 5798 6482 1428 -2682 715 -315 -153 -809 2290 -88 953 -1537 -1299 1026 -1086 2163 -2777 -48 -5035 -3139 -2854 -2246 -3341 -2771 -1499 -1355 -2180 -1019 -951 -10 -1164 -3030 -3440 -2473 664 708 1733 -456 -299 -399 1327 -713 891 641 474 26 -272 -389 2501 786 499 1084 813 621 1453 -454 -72 -62 -190 1131 323 -436 -438 284 256 68 -707 13 -1008 132 -3882 -4687 -1496 -2601 -1864 900000 900000 900000 -258 -5577 1164 -296 -3152 -1313 415 900000 2441 -589 337 900000 -1644 494 -2698 416 -3182 530 -2558 -1382 -2301 -653 418 167 213 549 996 1285 64 1231 1363 -394 1111 701 2270 558 -561 105 -41 1776 1526 802 1868 2593 2699 1527 4175 2149 4006 911 2681 1774 1210 1242 2188 2680 1624 2650 2286 1787 953 977 1124 1662 200 1374 1397 294 -547 146 -73 -42 -262 824 -36 412 -722 -644 522 -579 1113 -1452 -24 -2449 -1479 -1415 -1250 -2190 -2101 -1278 -1260 -2094 -924 -787 -8 -886 -2460 -2980 -2254 633 749 2051 -613 -431 -592 1924 -1023 1234 897 690 41 -430 -612 3703 1137 705 1489 1088 825 2010 -714 -129 -123 -403 2514 771 -1111 -1167 769 699 184 -1879 34 -2392 302 SS 20220924T120451.9Z 8302.503378 90 1 50.58 2 80.53 100.01 64.19 102.05 0.00 1 0.00 1 0 25 4.858e-01 8.767e-03 1.244e-01 2.443e-03 7.072528e-01 1.402316e-03 9.139611e-03 -6.000000e+00 2.922676e-01 227.97 -2.00 3.57 -2.00 321.72 0.00e+00 1.078170e-02 7.895790e-04 6.723200e-03 -6.000000e+00 1.295258e-02 283.75 -2.00 20.00 -2.00 321.17 0.00e+00 5.787 0.004 302.00 328.00 3 4.9594e-01 5.2723e-03 7.3818e-02 -6.0000e+00 7.2542e-01 1.4418e-01 7.5758e-03 5.2232e-02 -6.0000e+00 7.8600e-01 -2.2332e-01 7.7134e-03 3.1720e-02 -6.0000e+00 4.6862e-01 9.0946e-02 3.5328e-03 1.1886e-02 -6.0000e+00 1.9635e-01 5.5685e-04 -1.1922e-03 7.5929e-05 2.5471e-04 -6.0000e+00 1.4938e-02 -3.8808e-02 0.0000e+00 11 8 0 10 0 0 6.99 15.00 0.20 -0.03881 -0.04777 356 66 1 5 0 142.050 21.79 15.00 18.59 -179020 -134897 -175331 -125894 -180140 -166217 -173069 -107415 -159011 -89214 -157135 -103169 -126758 -97227 -84690 -61333 -40863 2002 -14861 -9442 1386 -49161 -21353 -33697 -16029 -32107 -33790 -61815 -32505 -47515 -9011 -5447 8234 -7778 6128 -13311 -1086 -14187 3032 1097 791 3975 3652 4777 10612 9928 8304 7224 5746 8809 7981 12896 5791 10285 4879 7504 1247 990 -1849 620 3045 4922 4480 6119 4354 4955 5421 3766 4738 2482 2996 1419 104 -902 -776 -3418 -1781 -4133 -959 -1527 -767 -1623 -2288 -1798 -802 -1131 -598 -917 -406 -538 -447 -980 -1293 -514 -1544 -298 -30 545 -746 -1209 -1285 -56 500 410 -1961 -1780 -580 441 1535 1743 822 491 456 157 226 1003 1206 370 138 -765 212 525 970 -363 -557 -941 -38 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