File name: Pandora103s1_Downsview_20230827_L2Fit_fout2c6d20230525p1-8.txt File generation date: 20240829T195504.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora103_OF_v3d20221207.txt Instrument calibration file used: Pandora103s1_CF_v6d20230525.txt Level 1 file used: Pandora103s1_Downsview_20230827_L1_smca1c6d20230525p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0579 305.1986 305.3393 305.4799 305.6206 305.7612 305.9018 306.0425 306.1831 306.3237 306.4643 306.6049 306.7454 306.8860 307.0266 307.1671 307.3077 307.4482 307.5887 307.7292 307.8697 308.0102 308.1507 308.2912 308.4316 308.5721 308.7125 308.8530 308.9934 309.1338 309.2742 309.4146 309.5550 309.6954 309.8357 309.9761 310.1164 310.2568 310.3971 310.5374 310.6777 310.8180 310.9583 311.0986 311.2388 311.3791 311.5193 311.6596 311.7998 311.9400 312.0802 312.2204 312.3606 312.5008 312.6410 312.7811 312.9213 313.0614 313.2015 313.3417 313.4818 313.6219 313.7620 313.9020 314.0421 314.1822 314.3222 314.4623 314.6023 314.7423 314.8823 315.0223 315.1623 315.3023 315.4422 315.5822 315.7221 315.8621 316.0020 316.1419 316.2818 316.4217 316.5616 316.7015 316.8413 316.9812 317.1210 317.2609 317.4007 317.5405 317.6803 317.8201 317.9599 318.0997 318.2394 318.3792 318.5189 318.6586 318.7984 318.9381 319.0778 319.2175 319.3571 319.4968 319.6365 319.7761 319.9157 320.0554 320.1950 320.3346 320.4742 320.6138 320.7533 320.8929 321.0324 321.1720 321.3115 321.4510 321.5905 321.7300 321.8695 322.0090 322.1485 322.2879 322.4274 322.5668 322.7062 322.8456 322.9850 323.1244 323.2638 323.4032 323.5425 323.6819 323.8212 323.9606 324.0999 324.2392 324.3785 324.5178 324.6570 324.7963 324.9355 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230827T110806.2Z 8639.463960 122 1 29.36 2 85.10 80.76 143.51 281.45 0.00 1 0.00 1 0 25 4.415e-01 5.449e-02 4.095e-01 5.101e-02 1.013420e+00 3.003214e-02 1.096686e-02 -6.000000e+00 2.723835e-01 230.82 -2.00 3.57 -2.00 321.85 0.00e+00 -2.319406e-02 1.043891e-02 9.972864e-03 -6.000000e+00 1.356557e-02 286.48 -2.00 20.00 -2.00 321.19 0.00e+00 9.945 0.019 302.00 328.00 3 6.3060e-01 9.8238e-02 1.3677e-01 -6.0000e+00 6.8029e-01 2.1722e+00 1.1465e-01 1.2548e-01 -6.0000e+00 7.3583e-01 -2.2238e+00 6.3826e-02 2.7670e-02 -6.0000e+00 4.3609e-01 7.4684e-01 3.5251e-02 2.6991e-02 -6.0000e+00 1.8164e-01 5.2415e-06 2.3042e-03 1.3780e-03 3.0402e-04 -6.0000e+00 1.3143e-02 -7.8376e-03 0.0000e+00 12 8 8 10 0 0 -79.46 19.76 1.25 -0.00784 0.00948 15 15 1 5 0 1956.521 23.43 14.92 19.76 18.78 1.9 987.39 168405 -4900 -22216 150979 -45228 900000 49124 12140 900000 -34776 44823 900000 -13634 -20556 -1699 74512 48055 8729 220332 -12677 17716 -23671 54802 128084 900000 -28854 900000 -28786 10772 -24518 -8171 -31031 -21360 -34079 46623 41458 123672 28767 2700 142764 59067 33656 37125 75760 -26840 25408 2701 40819 -3023 -48528 51738 56368 48900 -11185 23430 34227 39363 72844 30033 35322 34372 121276 7664 65455 70778 -6858 -4156 -683 38039 22453 48377 16252 18135 -17723 9674 6780 -4098 -30384 15623 1789 24960 15375 4306 -14806 3383 4157 -15147 1925 11127 24086 -7076 -9707 -5077 -11515 -26425 -1729 -4011 17567 -12862 -259 -6896 4296 -7428 16972 -7666 11441 -6994 -3114 -2385 15198 -2624 4257 -1285 3139 2685 -3234 3806 -766 -517 -973 230 321 13382 2597 -733 -3095 -1022 -6980 6052 1439 -391 -3763 637 1164 187 64 85 -2548 3421 776 -2118 630 -978 8370 -649 -3129 7504 -5432 900000 2442 905 900000 -4753 2785 900000 -1638 -2810 -204 4713 3908 1026 10951 -1661 1601 -2995 3219 6366 900000 -4824 900000 -3772 827 -2548 -775 -4066 -2702 -4927 2739 2435 6147 2340 342 7096 5338 3954 4026 5648 -4608 2411 305 3449 -369 -9867 4629 5323 5347 -2173 3726 5104 5674 7241 4180 4213 3929 6028 1295 6832 7387 -1534 -909 -153 6428 5022 8896 4200 4417 -5637 2067 1314 -835 -8306 3028 471 6079 4738 1648 -7285 1463 1860 -8507 919 4701 8500 -3201 -4342 -2170 -5666 -17468 -1048 -2871 11525 -11449 -206 -6066 3011 -5317 9448 -5830 7563 -5874 -2724 -2335 14503 -3107 5156 -1712 4028 3385 -4238 4695 -1032 -727 -1407 318 420 16095 3434 -980 -4168 -1321 -10303 9204 2445 -765 -8349 1463 2904 509 185 250 -7726 9693 2164 -5628 1507 -2290 SS 20230827T111754.3Z 8639.470767 125 1 30.19 2 83.35 82.43 145.14 283.58 0.00 1 0.00 1 0 17 4.354e-01 1.915e-02 3.050e-01 1.027e-02 9.111236e-01 6.194752e-03 1.062899e-02 -6.000000e+00 2.677741e-01 230.82 -2.00 3.57 -2.00 322.25 0.00e+00 1.037707e-02 3.981917e-03 5.101126e-03 -6.000000e+00 1.220878e-02 286.48 -2.00 20.00 -2.00 321.77 0.00e+00 7.847 0.009 302.00 328.00 3 9.0891e-01 2.6576e-02 9.4448e-02 -6.0000e+00 6.7198e-01 9.2649e-01 3.6194e-02 5.5842e-02 -6.0000e+00 7.2755e-01 -1.3017e+00 3.0718e-02 3.1081e-02 -6.0000e+00 4.3133e-01 5.3038e-01 1.3779e-02 1.1883e-02 -6.0000e+00 1.7909e-01 4.0762e-05 -1.8585e-03 2.9248e-04 2.5525e-04 -6.0000e+00 1.2938e-02 -8.0427e-03 0.0000e+00 12 8 8 10 0 0 -16.92 19.58 0.42 -0.00804 -0.02201 51 51 1 5 0 591.697 23.43 14.90 19.58 19.38 1.9 989.86 77696 -133557 -115298 -92518 -37993 -170097 4578 -161959 900000 -93333 -145893 -167942 900000 -77748 900000 -70684 13479 -7973 900000 13512 945 -54791 45155 -27629 16838 -35439 -49463 -28417 -95117 -29320 -43202 9506 -19725 119276 -1435 35876 -53514 361 2829 24375 -9472 78882 2115 32806 35163 90524 3007 1350 19251 35882 45712 18882 53533 39219 41294 25310 45199 11384 25537 10104 27176 7748 11858 20956 31632 19847 28341 12071 21261 17257 18053 11737 15578 15230 4788 4871 2781 -6037 -7120 4702 -227 221 3338 -1117 -2101 1038 1626 2899 -1642 1942 -3076 4407 -1910 -4393 -5267 -1383 -3182 -1655 -932 -2604 -2439 -4183 -2375 -4136 -595 -3580 -260 -1569 -190 -999 1374 293 319 -1080 -943 39 10 -82 -435 549 709 2285 2388 1924 290 2298 -755 -267 -740 879 952 276 -504 266 -521 986 -319 393 34 619 -1104 -39 -1481 777 -3401 -2517 -1515 -380 -4641 46 -3977 900000 -1188 -3185 -5041 900000 -1556 900000 -1993 184 -145 900000 209 16 -1545 497 -578 253 -806 -1260 -625 -3720 -704 -1297 228 -664 1193 -46 754 -2580 13 113 902 -491 1973 119 1379 1442 2174 178 85 1079 1831 2332 1417 3106 2825 3057 2049 3346 1056 2172 970 2230 761 1273 2344 3510 2527 3325 1746 3075 2982 3382 2434 3060 2812 893 815 448 -1098 -1483 1052 -64 72 1178 -442 -890 451 738 1342 -791 879 -1391 1768 -803 -1990 -2764 -830 -2292 -1245 -784 -2319 -2085 -3282 -1797 -3103 -457 -3015 -224 -1361 -181 -1111 1700 403 457 -1580 -1343 53 14 -119 -666 869 1102 3341 3311 2633 393 2998 -987 -362 -1159 1587 1941 620 -1127 638 -1353 2683 -896 1106 96 1686 -2852 -92 -3657 SS 20230827T112844.7Z 8639.478295 128 1 29.84 2 81.41 84.28 146.92 286.09 0.00 1 0.00 1 0 17 5.993e-01 1.007e-02 1.973e-01 3.209e-03 7.829397e-01 1.858481e-03 9.958310e-03 -6.000000e+00 3.652777e-01 230.82 -2.00 3.57 -2.00 321.72 0.00e+00 9.157647e-03 1.094606e-03 8.232458e-03 -6.000000e+00 1.629838e-02 286.48 -2.00 20.00 -2.00 321.18 0.00e+00 6.306 0.005 302.00 328.00 3 7.9744e-01 7.2397e-03 8.4253e-02 -6.0000e+00 9.1284e-01 2.1839e-01 1.0523e-02 6.4664e-02 -6.0000e+00 9.8587e-01 -3.4709e-01 1.0475e-02 3.4275e-02 -6.0000e+00 5.8748e-01 1.4181e-01 4.7281e-03 1.0144e-02 -6.0000e+00 2.4560e-01 2.3569e-04 -9.2469e-04 9.0972e-05 2.4864e-04 -6.0000e+00 1.7636e-02 -7.5903e-03 0.0000e+00 12 8 8 10 0 0 -7.39 19.61 0.28 -0.00759 -0.01454 134 134 1 5 0 222.598 23.43 14.97 19.61 20.18 1.8 992.58 -130575 -246231 137315 -225514 -76844 -225257 -163588 -184905 -138244 -188498 -148643 -198762 -133248 -121728 -133411 -36435 -99711 -58384 -79719 -42702 -62228 -48784 -73940 -31498 -67755 -20935 -46519 -52733 -70641 -22276 -34052 -14782 -15654 8162 -22928 2140 -8643 -11539 6700 35 15808 2452 478 12472 13414 2658 17411 346 20471 5512 23535 7104 18284 4155 16657 6415 7986 7769 4225 3318 7856 4475 8954 7707 8776 6174 4999 3440 2911 7827 1624 4198 19 396 -1889 -1990 -3331 -1648 -4092 1363 -672 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