File name: Pandora103s1_Downsview_20231011_L2Fit_fout2c6d20230525p1-8.txt File generation date: 20240829T205018.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora103_OF_v3d20221207.txt Instrument calibration file used: Pandora103s1_CF_v6d20230525.txt Level 1 file used: Pandora103s1_Downsview_20231011_L1_smca1c6d20230525p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231011 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0579 305.1986 305.3393 305.4799 305.6206 305.7612 305.9018 306.0425 306.1831 306.3237 306.4643 306.6049 306.7454 306.8860 307.0266 307.1671 307.3077 307.4482 307.5887 307.7292 307.8697 308.0102 308.1507 308.2912 308.4316 308.5721 308.7125 308.8530 308.9934 309.1338 309.2742 309.4146 309.5550 309.6954 309.8357 309.9761 310.1164 310.2568 310.3971 310.5374 310.6777 310.8180 310.9583 311.0986 311.2388 311.3791 311.5193 311.6596 311.7998 311.9400 312.0802 312.2204 312.3606 312.5008 312.6410 312.7811 312.9213 313.0614 313.2015 313.3417 313.4818 313.6219 313.7620 313.9020 314.0421 314.1822 314.3222 314.4623 314.6023 314.7423 314.8823 315.0223 315.1623 315.3023 315.4422 315.5822 315.7221 315.8621 316.0020 316.1419 316.2818 316.4217 316.5616 316.7015 316.8413 316.9812 317.1210 317.2609 317.4007 317.5405 317.6803 317.8201 317.9599 318.0997 318.2394 318.3792 318.5189 318.6586 318.7984 318.9381 319.0778 319.2175 319.3571 319.4968 319.6365 319.7761 319.9157 320.0554 320.1950 320.3346 320.4742 320.6138 320.7533 320.8929 321.0324 321.1720 321.3115 321.4510 321.5905 321.7300 321.8695 322.0090 322.1485 322.2879 322.4274 322.5668 322.7062 322.8456 322.9850 323.1244 323.2638 323.4032 323.5425 323.6819 323.8212 323.9606 324.0999 324.2392 324.3785 324.5178 324.6570 324.7963 324.9355 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231011T124922.3Z 8684.534286 258 1 29.35 2 76.63 113.72 44.28 130.31 0.00 1 0.00 1 0 17 3.586e-01 9.668e-03 2.554e-01 6.804e-03 5.712391e-01 3.704123e-03 6.766379e-03 -6.000000e+00 2.142934e-01 225.92 -2.00 3.57 -2.00 320.55 0.00e+00 4.530480e-03 1.466631e-03 1.326790e-03 -6.000000e+00 9.560780e-03 281.61 -2.00 20.00 -2.00 319.94 0.00e+00 4.220 0.001 302.00 328.00 3 4.3938e+00 1.1407e-02 5.1157e-02 -6.0000e+00 5.3015e-01 1.4195e-01 1.4443e-02 3.0636e-02 -6.0000e+00 5.7543e-01 -7.7180e-02 1.3247e-02 1.7044e-02 -6.0000e+00 3.4321e-01 1.7060e-02 6.5788e-03 6.7976e-03 -6.0000e+00 1.4394e-01 5.2439e-05 -1.1123e-03 2.0436e-04 8.3706e-05 -6.0000e+00 1.0550e-02 3.8230e-03 0.0000e+00 12 8 8 10 0 0 99.42 19.70 0.20 0.00382 -0.00454 12 12 1 5 0 2444.979 23.22 14.71 19.70 13.99 2.2 965.87 -168250 58523 -116695 -23310 -5915 -10168 -99623 238402 159684 -47554 -74888 -53655 105912 16280 -35708 39072 59028 1642 16618 -11100 18595 11085 66291 -15810 17150 -10603 -14968 7 2991 -34642 12708 1318 -630 1137 -9166 -8708 1465 6551 1948 -1341 -3832 3075 -4598 2233 -4548 2910 -2529 1207 98 5053 4709 7315 2986 5060 2348 3063 -726 237 3563 -188 1371 3701 5669 887 910 -206 3787 622 3455 1311 -1004 -1262 -1069 -3202 -2088 -2168 619 -588 -2330 -698 -939 213 -1674 -2334 777 922 270 -186 702 -512 -1293 553 -215 1275 -1042 1386 -1652 -446 -533 -35 -414 -398 -22 213 -174 -655 -1221 450 930 734 596 -835 989 49 942 213 1686 792 105 -1066 -265 -178 170 -650 -294 996 262 217 -42 -109 -511 180 -653 409 -332 422 -449 -108 -704 263 -12 653 89 -4277 388 -2290 -195 -40 -69 -1619 1582 1060 -645 -1375 -895 703 218 -944 612 857 44 419 -379 507 322 1200 -646 555 -463 -693 0 117 -2013 543 73 -40 78 -669 -635 105 523 193 -160 -520 420 -711 335 -741 453 -423 201 17 884 900 1508 694 1240 621 833 -211 68 981 -53 395 1124 1883 340 367 -82 1435 246 1439 629 -533 -700 -588 -1729 -1043 -996 260 -248 -1081 -368 -564 142 -1232 -1819 625 782 242 -171 639 -461 -1112 444 -166 980 -888 1295 -1767 -521 -668 -45 -502 -446 -23 222 -194 -766 -1495 572 1252 1076 941 -1390 1624 80 1438 317 2462 1204 167 -1784 -439 -289 266 -1005 -438 1441 366 310 -65 -186 -928 338 -1282 834 -711 938 -1020 -247 -1627 591 -27 1356 181 SS 20231011T125949.2Z 8684.541542 261 1 30.08 2 74.92 115.73 42.93 133.42 0.00 1 0.00 1 0 25 8.708e-02 6.260e-03 1.285e-02 6.309e-04 5.130022e-01 3.377386e-04 6.112785e-03 -6.000000e+00 5.202990e-02 225.92 -2.00 3.57 -2.00 319.85 0.00e+00 3.991959e-03 1.083728e-04 8.721394e-04 -6.000000e+00 2.321299e-03 281.61 -2.00 20.00 -2.00 319.22 0.00e+00 3.770 0.001 302.00 328.00 3 7.3096e-01 9.7210e-04 4.5621e-02 -6.0000e+00 1.2872e-01 5.2363e-02 1.1707e-03 2.7047e-02 -6.0000e+00 1.3971e-01 -3.0336e-02 9.8468e-04 1.4519e-02 -6.0000e+00 8.3331e-02 1.0215e-03 5.0620e-04 5.7875e-03 -6.0000e+00 3.4949e-02 3.4632e-03 -7.6374e-04 1.8935e-05 6.4083e-05 -6.0000e+00 2.5615e-03 3.7318e-03 0.0000e+00 10 0 0 10 0 0 99.85 19.58 0.18 0.00373 -0.00201 560 560 1 5 0 53.598 23.32 14.93 19.58 14.91 2.1 970.02 -17730 -31966 -18592 -35120 -22069 -31055 -27206 -33104 -30367 -25571 -33812 -19321 -21225 -6297 -9289 671 -3999 2566 -857 3536 -2050 2375 -2817 -2175 -7001 -5221 -8947 -5556 -6740 -3362 -2853 -931 -1874 -1507 -2973 -3091 -1327 -286 558 -1713 -571 -1701 -141 -171 1119 939 1987 1915 2147 1639 2373 2364 2185 1821 1073 620 -38 -460 -340 862 1480 2379 1610 1632 803 931 1148 1476 1174 1272 -469 -678 -1421 -1219 -1249 -1163 -1209 -1266 -1194 -839 -1393 -1479 -1559 -1392 -460 -387 77 -125 -90 273 336 713 629 602 933 557 96 -499 -547 -1052 -474 -275 418 355 -79 -687 -282 512 736 1038 439 412 57 519 707 1212 1089 787 -376 -397 -779 -319 -506 -164 -597 180 -269 134 -162 -380 -618 -328 -262 227 -87 160 -201 -36 -240 -20 29 494 466 -213 -461 -252 -554 -312 -468 -417 -554 -554 -478 -717 -391 -535 -171 -319 24 -170 111 -42 173 -111 122 -157 -129 -468 -358 -645 -381 -466 -234 -224 -84 -176 -152 -295 -334 -140 -35 82 -303 -111 -361 -31 -39 254 219 465 459 528 424 660 729 731 605 376 226 -14 -175 -127 316 557 963 729 812 424 478 568 735 634 783 -297 -448 -942 -773 -795 -672 -650 -673 -684 -554 -983 -1176 -1356 -1278 -416 -372 78 -130 -94 275 318 674 561 539 909 575 112 -612 -730 -1424 -604 -318 477 409 -92 -848 -363 693 1004 1552 714 662 91 842 1078 1757 1573 1185 -601 -631 -1248 -526 -803 -253 -888 258 -391 197 -248 -647 -1074 -597 -493 428 -174 321 -412 -74 -502 -41 59 956 876 SS 20231011T130950.8Z 8684.548504 264 1 29.92 2 73.31 117.70 41.70 136.53 0.00 1 0.00 1 0 17 8.305e-02 7.226e-03 7.533e-02 3.876e-03 4.728043e-01 2.073198e-03 5.645036e-03 -6.000000e+00 4.962247e-02 225.92 -2.00 3.57 -2.00 319.92 0.00e+00 2.710057e-03 6.681906e-04 9.944193e-04 -6.000000e+00 2.213858e-03 281.61 -2.00 20.00 -2.00 319.28 0.00e+00 3.427 0.001 302.00 328.00 3 4.2445e+00 6.0214e-03 4.1750e-02 -6.0000e+00 1.2276e-01 5.8579e-02 7.2481e-03 2.5084e-02 -6.0000e+00 1.3325e-01 -4.9011e-03 5.9904e-03 1.3182e-02 -6.0000e+00 7.9475e-02 -1.0129e-02 3.0652e-03 4.5145e-03 -6.0000e+00 3.3332e-02 1.4714e-04 -7.5951e-04 1.2011e-04 5.5210e-05 -6.0000e+00 2.4429e-03 3.6362e-03 0.0000e+00 11 8 0 10 0 0 99.95 19.58 0.14 0.00364 -0.00207 43 43 1 5 0 695.518 23.32 14.77 19.58 15.79 2.1 972.97 -3656 -12016 -32159 30190 -37165 -30106 -32771 -6187 -20289 26157 -16502 115 -30103 3088 -27211 -2578 -18643 431 1747 9233 -1869 7480 5935 2322 -5794 -2862 -2806 -834 1719 631 368 -1948 4111 -2513 407 5618 5570 -1640 -1863 -3325 -2922 -3564 2192 687 2007 -1221 2316 2380 3262 1816 2594 2572 2679 1858 -413 604 -1285 -698 -856 693 739 1101 1316 3061 747 279 8 139 1988 930 101 -758 -462 -435 -1684 -438 -1262 -752 -1621 -1440 -1385 -1267 -1891 -1717 -56 -414 883 -412 -714 28 179 630 486 61 2289 836 -95 -511 -780 -471 -814 -120 239 1233 -393 -726 -473 872 334 1333 713 393 -39 27 1112 1002 960 933 -400 -444 -733 104 -635 -231 -703 485 -428 -313 -358 -463 -521 -692 -220 224 -159 547 -215 -168 -244 -90 72 642 466 -46 -182 -620 332 -699 -518 -613 -103 -424 386 -371 2 -976 90 -1233 -108 -985 21 89 458 -107 394 326 140 -406 -203 -201 -58 116 44 29 -175 391 -272 42 548 585 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