File name: Pandora103s1_Downsview_20231106_L2Fit_fout2c3d20230309p1-8.txt File generation date: 20231107T060927.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora103_OF_v3d20221207.txt Instrument calibration file used: Pandora103s1_CF_v3d20230309.txt Level 1 file used: Pandora103s1_Downsview_20231106_L1_smca1c3d20230309p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 2 "Initial 1.8 calibration for delrin-free head sensor, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0640 305.2047 305.3453 305.4860 305.6266 305.7672 305.9079 306.0485 306.1891 306.3296 306.4702 306.6108 306.7513 306.8919 307.0324 307.1730 307.3135 307.4540 307.5945 307.7350 307.8755 308.0160 308.1564 308.2969 308.4373 308.5778 308.7182 308.8586 308.9991 309.1395 309.2798 309.4202 309.5606 309.7010 309.8413 309.9817 310.1220 310.2623 310.4027 310.5430 310.6833 310.8236 310.9638 311.1041 311.2444 311.3846 311.5249 311.6651 311.8053 311.9455 312.0857 312.2259 312.3661 312.5063 312.6464 312.7866 312.9267 313.0669 313.2070 313.3471 313.4872 313.6273 313.7674 313.9075 314.0475 314.1876 314.3276 314.4677 314.6077 314.7477 314.8877 315.0277 315.1677 315.3077 315.4477 315.5876 315.7276 315.8675 316.0074 316.1473 316.2872 316.4271 316.5670 316.7069 316.8468 316.9866 317.1265 317.2663 317.4061 317.5459 317.6857 317.8255 317.9653 318.1051 318.2449 318.3846 318.5244 318.6641 318.8038 318.9435 319.0832 319.2229 319.3626 319.5023 319.6419 319.7816 319.9212 320.0609 320.2005 320.3401 320.4797 320.6193 320.7588 320.8984 321.0380 321.1775 321.3170 321.4566 321.5961 321.7356 321.8751 322.0146 322.1540 322.2935 322.4329 322.5724 322.7118 322.8512 322.9906 323.1300 323.2694 323.4088 323.5482 323.6875 323.8269 323.9662 324.1055 324.2448 324.3841 324.5234 324.6627 324.8020 324.9412 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231106T144339.6Z 8710.613653 467 1 9.96 2 67.59 143.96 41.25 239.06 0.00 1 0.00 1 0 17 1.938e-02 7.516e-03 8.553e-03 2.064e-03 3.211267e-01 1.039888e-03 3.910275e-03 -6.000000e+00 1.114141e-02 223.38 -2.00 3.57 -2.00 317.76 0.00e+00 1.161585e-03 1.723918e-04 3.780840e-04 -6.000000e+00 4.934381e-04 278.29 -2.00 20.00 -2.00 317.11 0.00e+00 2.602 0.000 302.00 328.00 3 3.3621e+00 2.7452e-03 3.0154e-02 -6.0000e+00 2.7435e-02 -1.4669e-02 3.1062e-03 1.6419e-02 -6.0000e+00 2.9884e-02 -3.1130e-03 1.9548e-03 8.2219e-03 -6.0000e+00 1.7819e-02 -3.8296e-03 9.9429e-04 2.4610e-03 -6.0000e+00 7.5484e-03 1.0040e-03 -3.3876e-04 6.1292e-05 2.7115e-05 -6.0000e+00 5.5399e-04 2.8236e-03 -2.6613e-05 12 9 1 12 5 5 99.52 19.56 0.23 0.00282 0.00028 14 45 1 5 0 663.503 23.22 14.95 19.56 14.74 2.2 969.48 -1679 -5699 -4350 -4266 -9890 -993 -7531 -3735 -1907 -2717 -4736 -5236 -6435 2221 -590 -362 1062 2531 1242 2034 1900 1581 1508 1664 264 -1325 -1097 -3253 -914 -2659 935 -1020 732 -3500 -2002 -2452 -3120 -574 758 -1196 -165 -890 1391 -423 750 88 -369 450 267 691 972 1301 1071 1795 770 1728 597 261 154 648 1825 2112 2008 1363 65 245 7 -228 1285 352 -303 89 -71 -168 -824 -1767 -1228 -2772 -1703 -2081 -1498 -1791 -1802 -1352 95 -74 569 204 681 625 666 -125 -300 -165 -463 -313 395 361 -234 -470 -943 -922 55 251 -1349 -850 -175 560 934 1427 1255 670 625 526 409 408 144 192 -152 -239 86 300 440 -131 -17 -757 -474 143 -757 -214 -426 -518 -35 -97 -264 -51 431 357 215 35 48 -322 -95 -124 -485 -373 -348 -784 -69 -587 -318 -177 -266 -481 -563 -796 298 -87 -59 182 450 234 396 379 317 308 358 62 -327 -267 -777 -205 -602 218 -270 208 -1065 -581 -703 -969 -190 297 -552 -77 -445 702 -220 389 46 -192 230 136 357 529 763 630 1103 495 1134 403 176 103 428 1228 1526 1488 1087 53 189 5 -173 972 302 -269 82 -66 -149 -732 -1435 -963 -2125 -1362 -1765 -1348 -1789 -1827 -1444 101 -84 682 241 796 745 744 -135 -302 -163 -485 -344 482 462 -306 -619 -1229 -1155 65 303 -1682 -1123 -229 763 1346 2100 1876 1030 937 774 585 551 194 269 -218 -363 133 459 649 -188 -24 -1043 -654 197 -1073 -313 -662 -831 -55 -159 -440 -89 744 628 380 61 84 -539 -162 SS 20231106T145846.1Z 8710.624145 474 1 30.47 2 66.06 147.54 43.63 242.98 0.00 1 0.00 1 0 17 2.060e-02 7.466e-03 1.202e-02 2.454e-03 3.061447e-01 1.234780e-03 3.739287e-03 -6.000000e+00 1.184308e-02 223.38 -2.00 3.57 -2.00 318.20 0.00e+00 1.066464e-03 2.288506e-04 4.871982e-04 -6.000000e+00 5.244328e-04 278.29 -2.00 20.00 -2.00 317.54 0.00e+00 2.447 0.000 302.00 328.00 3 4.6745e+00 3.2937e-03 2.8521e-02 -6.0000e+00 2.9162e-02 1.0856e-02 3.7443e-03 1.5740e-02 -6.0000e+00 3.1764e-02 -8.0357e-04 2.4322e-03 7.9176e-03 -6.0000e+00 1.8940e-02 -6.1075e-03 1.2522e-03 2.3690e-03 -6.0000e+00 8.0249e-03 3.1489e-04 -2.1575e-04 7.4313e-05 2.6564e-05 -6.0000e+00 5.8872e-04 2.2645e-03 5.8904e-06 12 9 1 12 4 4 99.94 19.75 0.17 0.00226 0.00064 27 27 1 5 0 1128.095 23.32 14.83 19.75 15.69 2.2 973.15 -6119 -5474 -718 -7650 -4085 -5332 -9005 -1334 -4113 -5942 -4986 -1500 -5268 1470 -4773 -606 637 5388 2357 2215 -241 2374 1656 936 -1112 -2501 -2983 -1532 -2274 -769 890 1622 231 -3686 -1275 -2509 -1684 -1196 -139 -2848 506 448 1163 119 536 88 -481 373 -445 735 1665 662 1620 1141 770 1318 175 176 715 1372 1504 1791 1352 1553 -437 489 234 -54 1726 18 215 -220 132 -15 -881 -1542 -2296 -2288 -1279 -2455 -1697 -1756 -1974 -1132 -115 -38 521 678 725 638 565 -469 -669 -308 -502 -140 152 537 -432 -176 -730 -917 -38 89 -1226 -862 -280 277 1370 1574 845 1143 685 241 -71 680 -73 -37 51 -378 16 191 308 23 -21 -587 -495 -19 -645 -566 -457 -673 27 120 -234 -328 777 198 154 64 -80 -366 257 -394 -387 -49 -536 -257 -328 -596 -93 -326 -501 -422 -128 -529 160 -637 -86 95 804 379 370 -42 406 289 174 -222 -524 -630 -306 -437 -146 177 350 55 -933 -305 -595 -426 -350 -47 -1137 215 199 528 55 249 41 -224 172 -205 341 806 343 878 652 457 800 108 108 436 825 932 1172 956 1151 -334 355 161 -36 1228 14 183 -193 115 -13 -718 -1179 -1630 -1558 -906 -1920 -1469 -1635 -1950 -1157 -122 -42 607 813 865 748 629 -495 -660 -300 -512 -153 180 681 -575 -237 -939 -1108 -44 106 -1529 -1126 -377 383 1959 2379 1329 1827 1071 363 -101 935 -100 -53 75 -583 25 297 469 34 -31 -822 -669 -25 -912 -857 -715 -1070 44 201 -405 -591 1413 368 289 117 -144 -644 442 SS 20231106T151802.5Z 8710.637529 488 1 30.14 2 64.32 152.27 46.78 247.59 0.00 1 0.00 1 0 17 2.108e-02 7.726e-03 1.095e-02 2.728e-03 2.865011e-01 1.372658e-03 3.487204e-03 -6.000000e+00 1.212323e-02 223.38 -2.00 3.57 -2.00 317.82 0.00e+00 1.347349e-03 2.293825e-04 3.140028e-04 -6.000000e+00 5.367886e-04 278.28 -2.00 20.00 -2.00 317.16 0.00e+00 2.293 0.000 302.00 328.00 3 5.1342e+00 3.6273e-03 2.6678e-02 -6.0000e+00 2.9852e-02 1.3609e-02 4.1070e-03 1.4635e-02 -6.0000e+00 3.2514e-02 -2.1521e-03 2.5767e-03 7.3546e-03 -6.0000e+00 1.9387e-02 -5.8373e-03 1.3060e-03 2.3058e-03 -6.0000e+00 8.2152e-03 2.3647e-04 -5.6633e-05 8.2225e-05 2.5240e-05 -6.0000e+00 6.0257e-04 2.1225e-03 2.7275e-05 12 9 1 12 4 4 99.89 19.58 0.17 0.00212 0.00170 11 11 1 5 0 2739.261 23.32 14.90 19.58 15.57 2.2 972.32 -3478 -3716 2705 -52 -8705 -13486 -4853 -4831 -5138 -5273 -4821 -2572 -3743 343 1097 -113 4487 1117 2000 405 477 717 3779 1104 551 -578 -2266 -1533 -1690 -525 -2323 -1303 -2527 -1856 -2779 -1117 -2838 -249 -330 -60 -181 -327 -192 925 624 166 529 703 0 726 1658 1348 1462 849 352 1661 776 466 -61 -126 1727 2034 1715 1068 467 103 -127 -256 783 102 -152 85 -316 -381 -1303 -1395 -2307 -2113 -1590 -2530 -1867 -1776 -1912 -633 -382 -79 672 795 911 1062 739 329 -450 -240 -588 -269 335 449 -118 -139 -1085 -1358 -323 41 -1075 -972 -198 105 1456 1244 1341 813 639 574 102 72 161 56 -236 -254 -108 357 426 -57 -36 -627 -668 -30 -875 -285 -648 -343 -417 229 -37 186 369 570 146 143 -164 -369 -120 -277 -327 228 -4 -719 -1108 -386 -434 -508 -544 -503 -274 -449 46 168 -19 769 207 383 81 98 147 768 240 128 -140 -554 -359 -381 -115 -549 -334 -706 -525 -772 -299 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