File name: Pandora103s1_Downsview_20231207_L2Fit_fsus1c6d20230525p1-8.txt File generation date: 20240829T212653.1Z Data description: Level 2 spectral fitting results file Data file version: fsus1c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora103_OF_v3d20221207.txt Instrument calibration file used: Pandora103s1_CF_v6d20230525.txt Level 1 file used: Pandora103s1_Downsview_20231207_L1_smca1c6d20230525p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 208 353 Nominal wavelengths inside fitting window [nm]: 306.0425 306.1831 306.3237 306.4643 306.6049 306.7454 306.8860 307.0266 307.1671 307.3077 307.4482 307.5887 307.7292 307.8697 308.0102 308.1507 308.2912 308.4316 308.5721 308.7125 308.8530 308.9934 309.1338 309.2742 309.4146 309.5550 309.6954 309.8357 309.9761 310.1164 310.2568 310.3971 310.5374 310.6777 310.8180 310.9583 311.0986 311.2388 311.3791 311.5193 311.6596 311.7998 311.9400 312.0802 312.2204 312.3606 312.5008 312.6410 312.7811 312.9213 313.0614 313.2015 313.3417 313.4818 313.6219 313.7620 313.9020 314.0421 314.1822 314.3222 314.4623 314.6023 314.7423 314.8823 315.0223 315.1623 315.3023 315.4422 315.5822 315.7221 315.8621 316.0020 316.1419 316.2818 316.4217 316.5616 316.7015 316.8413 316.9812 317.1210 317.2609 317.4007 317.5405 317.6803 317.8201 317.9599 318.0997 318.2394 318.3792 318.5189 318.6586 318.7984 318.9381 319.0778 319.2175 319.3571 319.4968 319.6365 319.7761 319.9157 320.0554 320.1950 320.3346 320.4742 320.6138 320.7533 320.8929 321.0324 321.1720 321.3115 321.4510 321.5905 321.7300 321.8695 322.0090 322.1485 322.2879 322.4274 322.5668 322.7062 322.8456 322.9850 323.1244 323.2638 323.4032 323.5425 323.6819 323.8212 323.9606 324.0999 324.2392 324.3785 324.5178 324.6570 324.7963 324.9355 325.0748 325.2140 325.3532 325.4924 325.6316 325.7708 325.9100 326.0491 326.1883 326.3274 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Bromine oxide slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of bromine oxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Bromine oxide effective temperature [K] Column 28: Independent uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective bromine oxide fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for bromine oxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Formaldehyde slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of formaldehyde slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Formaldehyde effective temperature [K] Column 39: Independent uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective formaldehyde fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrous acid slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrous acid slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrous acid effective temperature [K] Column 50: Independent uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrous acid fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrous acid [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Nitrogen dioxide effective temperature [K] Column 61: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: rms-based uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 76: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 77: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 78: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 79: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 80: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 82: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 83: Sulfur dioxide effective temperature [K] Column 84: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 85: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 86: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 87: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 88: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 89: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 90: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 91: Lower limit used for wavelength scaling [nm] Column 92: Upper limit used for wavelength scaling [nm] Column 93: Order of smoothing polynomial Column 94: Smoothing polynomial coefficient, order 0 Column 95: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 99: Smoothing polynomial coefficient, order 1 Column 100: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 104: Smoothing polynomial coefficient, order 2 Column 105: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 109: Smoothing polynomial coefficient, order 3 Column 110: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 114: Smoothing polynomial coefficient, order 4 Column 115: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 119: Mean value of measured data inside fitting window [same units as measurements] Column 120: Offset polynomial coefficient, order 0 Column 121: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 125: Wavelength change polynomial coefficient, order 0 Column 126: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 130: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 131: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 132: Resolution change polynomial coefficient, order 0 Column 133: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 134: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 135: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 136: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 137: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 138: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 139: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 140: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 141: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 142: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 143: Atmospheric variability [%], 999=no atmospheric variability was determined Column 144: Wavelength effective temperature [°C], 999=no effective temperature given Column 145: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 146: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 147: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 148: Number of bright count cycles Column 149: Number of dark count cycles Column 150: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 151: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 152: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 153: Integration time [ms] Column 154: Temperature at electronics board [°C], 999=no temperature signal Column 155: Spectrometer control temperature [°C], 999=no temperature signal Column 156: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 157: Temperature in head sensor [°C], 999=no temperature signal Column 158: Humidity in head sensor [%], -9=no humidity signal Column 159: Pressure in head sensor [hPa], -9=no pressure signal Columns 160-305: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 306-451: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231207T161108.9Z 8741.674409 458 1 29.25 2 67.74 165.50 64.98 235.70 0.00 1 0.00 1 0 33 1.792e-02 4.263e-03 1.555e-02 3.750e-03 7.971834e-07 1.415246e-06 1.539301e-07 3.566237e-07 8.337797e-06 222.28 -2.00 3.57 -2.00 322.25 0.00e+00 8.883985e-04 5.428232e-04 8.112848e-05 1.771439e-05 2.180905e-03 274.64 -2.00 20.00 -2.00 322.29 0.00e+00 1.357993e-03 7.113433e-04 4.259580e-05 2.457517e-05 3.918146e-03 274.64 -2.00 20.00 -2.00 322.00 0.00e+00 -2.128402e-03 1.190957e-03 5.702354e-05 1.569119e-05 4.051027e-03 274.64 -2.00 20.00 -2.00 322.11 0.00e+00 3.068544e-01 6.454709e-03 4.449865e-04 4.369378e-03 2.411139e-02 228.97 4.89 0.00 0.37 40.78 319.09 0.00e+00 7.739784e-04 4.242197e-04 2.703893e-05 1.379063e-05 5.974887e-04 274.64 -2.00 20.00 -2.00 318.11 0.00e+00 2.617 0.000 303.00 329.40 4 5.7063e+00 1.5590e-02 2.4831e-02 1.8707e-03 7.3673e-02 6.6003e-02 2.3945e-02 2.9125e-03 3.8538e-04 8.0025e-02 -1.8706e-02 1.2803e-02 1.2954e-03 2.2737e-04 4.3448e-02 7.1412e-03 6.4935e-03 1.1634e-03 9.2185e-05 1.6977e-02 4.8614e-04 3.7643e-03 1.5565e-04 7.3373e-05 1.1638e-02 1.1980e-04 3.1628e-03 2.7644e-03 2.2162e-04 2.2474e-05 2.8210e-03 -3.1217e-04 1.2409e-04 8.1783e-06 1.7778e-06 5.7692e-04 8.0242e-03 0.0000e+00 2.2906e-02 3.5709e-01 3.7467e-03 4.7046e-04 1.3900e+00 12 8 8 10 0 0 99.99 19.65 0.43 0.00802 0.00564 8 8 1 5 0 3655.203 23.32 15.01 19.65 9.91 2.4 951.15 3685 -7524 -6900 -2224 6743 1951 -1882 3068 991 -1882 -7093 -215 2992 -288 1159 5058 -1070 -355 -2299 6952 -1589 4552 512 -175 -4701 1035 -622 323 2907 -1771 219 -801 -1391 -1244 1189 142 -645 1194 318 -54 -616 737 1530 -1172 817 -191 818 -40 1449 -291 419 682 -1262 -508 -586 8 -28 445 136 -971 -82 -139 635 -342 218 436 -975 -455 -128 112 -200 -285 560 887 -405 290 417 -623 -465 131 53 312 -304 -182 22 114 -737 -973 525 -206 -220 13 18 -320 483 342 -79 -207 272 769 -264 420 433 -124 -61 198 -64 111 -222 574 375 2 -389 -520 37 522 69 217 -714 389 -399 -205 -506 -62 -136 172 126 -43 -273 9 76 164 279 -560 202 -184 109 -187 219 -71 100 64 336 -195 57 -151 208 -529 -510 -160 462 158 -184 327 120 -247 -1023 -30 425 -43 173 733 -174 -61 -420 1166 -278 723 84 -31 -939 214 -137 69 589 -401 56 -242 -484 -471 462 57 -265 484 130 -22 -252 295 618 -506 370 -92 409 -21 762 -158 227 362 -677 -277 -339 5 -18 296 87 -595 -49 -88 438 -257 169 336 -740 -326 -85 69 -120 -177 382 667 -333 251 376 -591 -462 134 56 328 -313 -179 20 100 -633 -879 506 -216 -248 15 21 -365 516 350 -83 -227 312 910 -325 533 576 -172 -86 274 -86 140 -269 690 463 3 -529 -719 50 695 90 274 -880 463 -478 -257 -675 -85 -193 247 186 -65 -434 14 125 269 452 -892 310 -280 168 -303 373 -127 186 124 670 -397 115 -306 SS 20231207T162056.0Z 8741.681204 461 1 30.44 2 67.33 167.90 66.45 237.76 0.00 1 0.00 1 0 33 1.959e-02 3.996e-03 1.490e-02 3.681e-03 -5.202185e-08 1.393110e-06 7.487890e-08 3.566250e-07 9.098733e-06 222.28 -2.00 3.57 -2.00 322.25 0.00e+00 7.949961e-04 5.340567e-04 3.804408e-05 1.769762e-05 2.377489e-03 274.64 -2.00 20.00 -2.00 322.30 0.00e+00 1.372139e-03 6.977913e-04 2.141433e-05 2.458704e-05 4.280888e-03 274.64 -2.00 20.00 -2.00 322.00 0.00e+00 1.715966e-03 1.178606e-03 1.526932e-04 1.572051e-05 4.430755e-03 274.64 -2.00 20.00 -2.00 322.12 0.00e+00 2.928486e-01 6.169486e-03 3.653022e-04 4.369359e-03 2.626450e-02 220.60 4.79 0.00 0.39 44.56 319.05 0.00e+00 3.193061e-04 4.121328e-04 1.646493e-05 1.381749e-05 6.480450e-04 274.64 -2.00 20.00 -2.00 318.09 0.00e+00 2.574 0.000 303.00 329.40 4 5.6951e+00 1.3954e-02 2.4429e-02 1.8710e-03 8.0287e-02 1.6846e-02 2.1960e-02 3.1265e-03 3.8681e-04 8.7301e-02 1.3188e-02 1.2019e-02 7.8074e-04 2.2916e-04 4.7362e-02 -9.0998e-03 6.3348e-03 5.6054e-04 9.3584e-05 1.8543e-02 1.6823e-03 3.7144e-03 1.3718e-04 7.3400e-05 1.2835e-02 1.2523e-04 -2.7701e-03 2.6306e-03 1.5466e-04 2.4426e-05 3.3453e-03 -5.6250e-05 1.2110e-04 4.2266e-06 1.7852e-06 6.3243e-04 6.5205e-03 0.0000e+00 -7.0415e-01 3.5325e-01 1.6073e-03 4.0555e-04 1.4996e+00 12 8 8 10 0 0 99.98 19.53 0.30 0.00652 0.00609 11 11 1 5 0 2766.782 23.32 14.83 19.53 9.82 2.4 950.93 -3019 15203 -4751 -4460 2001 -2189 3401 4545 1751 3730 -1727 -967 -2975 -5643 4674 -3927 3098 -3256 982 -1499 1437 -1766 -764 -1434 357 -473 1087 3437 891 1115 -2141 -891 10 1239 -341 776 -631 1132 -926 1311 -4 631 -1454 946 -896 1303 -864 -211 119 361 197 -409 251 22 379 -247 550 -471 -131 -840 638 904 123 -940 609 -654 1239 -644 -206 -409 330 -897 -477 343 125 132 -108 116 168 320 -377 16 25 377 -1122 25 -907 -185 -884 679 333 -93 -124 -107 19 565 152 -103 128 107 471 146 50 126 132 -163 -90 109 733 -247 -93 -292 -61 -327 14 -102 471 -184 178 -166 -190 171 -296 -85 -189 398 -371 411 -313 -49 -94 14 299 67 -102 -107 -290 309 -79 176 -58 -70 161 -3 -77 -3 -193 915 -363 -344 151 -192 325 491 214 472 -240 -139 -452 -903 679 -629 492 -585 178 -278 249 -303 -128 -255 69 -100 237 715 185 247 -559 -270 4 460 -135 312 -260 458 -384 531 -2 254 -602 400 -410 621 -439 -110 63 195 107 -220 134 12 218 -153 360 -318 -84 -515 380 564 85 -709 469 -510 925 -462 -137 -253 198 -562 -329 259 103 115 -98 110 166 329 -399 17 26 369 -1039 22 -779 -165 -858 705 373 -110 -147 -122 21 574 157 -113 147 127 573 185 66 175 186 -227 -120 138 883 -297 -115 -380 -83 -452 19 -136 611 -233 217 -196 -225 214 -392 -117 -267 567 -549 630 -498 -80 -154 23 485 106 -156 -162 -452 499 -136 315 -109 -137 324 -6 -157 -6 SS 20231207T163059.1Z 8741.688185 468 1 30.09 2 66.99 170.39 68.00 239.83 0.00 1 0.00 1 0 33 8.063e-03 2.124e-03 7.619e-03 2.085e-03 1.292741e-07 7.880386e-07 6.732172e-08 3.566069e-07 3.793241e-06 222.28 -2.00 3.57 -2.00 322.12 0.00e+00 2.616125e-04 2.990151e-04 3.275237e-05 1.759938e-05 9.840417e-04 274.64 -2.00 20.00 -2.00 322.11 0.00e+00 1.000979e-03 3.935503e-04 1.773326e-05 2.458580e-05 1.760899e-03 274.64 -2.00 20.00 -2.00 321.90 0.00e+00 -5.495200e-04 6.390931e-04 8.015051e-05 1.590297e-05 1.823131e-03 274.64 -2.00 20.00 -2.00 321.99 0.00e+00 2.945647e-01 3.491261e-03 3.369695e-04 4.369835e-03 1.084269e-02 229.14 2.77 0.00 0.39 18.40 318.84 0.00e+00 2.690030e-04 2.206310e-04 6.838035e-05 1.388401e-05 2.692379e-04 274.64 -2.00 20.00 -2.00 317.87 0.00e+00 2.538 0.000 303.00 329.40 4 4.7674e+00 8.6226e-03 2.4067e-02 1.8705e-03 3.3263e-02 3.0929e-02 1.2910e-02 3.1795e-03 3.8794e-04 3.6064e-02 -7.7782e-03 6.9310e-03 5.3655e-04 2.2611e-04 1.9605e-02 -2.7671e-03 3.5156e-03 2.7343e-04 8.6274e-05 7.9625e-03 4.6496e-03 2.0586e-03 9.0530e-05 7.2880e-05 5.3688e-03 3.3488e-04 -1.5821e-03 1.4601e-03 8.8183e-05 2.2046e-05 1.6031e-03 -1.4959e-04 6.7444e-05 2.9937e-06 1.7688e-06 2.5938e-04 7.8254e-03 0.0000e+00 -9.9784e-01 2.0073e-01 1.9511e-03 4.5092e-04 6.3553e-01 12 8 8 10 0 0 99.97 19.75 0.19 0.00783 0.00668 29 29 1 5 0 1037.193 23.32 14.83 19.75 9.98 2.4 951.83 -4471 3792 -135 668 -4030 1539 -1307 -208 29 -43 197 1689 2260 -881 -1059 493 229 520 1144 -9 -931 -1867 1237 -669 270 -1573 317 -1365 106 -749 185 120 -52 214 247 -285 242 75 -7 -10 -470 79 765 462 306 449 -751 513 327 -106 -23 -18 38 -131 -451 -26 -5 -178 -303 465 517 125 -5 -290 -116 -97 245 -723 77 -72 672 -61 196 -89 49 -12 110 -263 -308 35 204 -42 20 -90 234 434 -290 10 -246 -402 -184 147 -7 34 -101 167 444 102 282 -39 -122 38 118 119 -200 -98 -98 150 296 50 -50 -81 78 -457 272 -220 91 125 -49 -127 215 -90 -75 -176 -72 20 154 60 -86 193 35 -103 2 138 -221 -257 -20 185 -98 -4 103 120 63 -28 -136 31 -323 281 -11 54 -355 144 -145 -26 4 -6 29 262 360 -148 -179 83 41 99 225 -2 -180 -349 223 -129 57 -364 75 -320 24 -182 51 39 -19 85 103 -124 106 33 -3 -4 -203 34 327 207 147 227 -401 278 182 -60 -13 -10 22 -75 -272 -17 -3 -123 -202 292 321 81 -4 -224 -93 -77 190 -535 53 -46 417 -39 139 -69 41 -11 102 -253 -309 37 218 -45 21 -89 220 383 -254 9 -241 -425 -209 174 -8 39 -109 173 464 113 326 -46 -150 49 158 164 -281 -135 -131 188 358 60 -62 -105 105 -628 370 -294 119 159 -60 -152 256 -112 -100 -242 -101 28 225 91 -136 308 56 -167 4 216 -338 -388 -30 297 -165 -7 190 231 122 -56 -271 61 SS 20231207T163601.4Z 8741.691683 471 1 1.80 2 66.85 171.65 68.79 240.84 0.00 1 0.00 1 0 33 5.277e-03 2.324e-03 5.277e-03 2.256e-03 1.500339e-06 8.643828e-07 3.421767e-08 3.565902e-07 2.485530e-06 222.28 -2.00 3.57 -2.00 321.55 0.00e+00 4.673813e-04 3.118336e-04 1.801343e-05 1.709807e-05 6.465737e-04 274.64 -2.00 20.00 -2.00 321.31 0.00e+00 8.775135e-04 4.196901e-04 7.712035e-06 2.456935e-05 1.151957e-03 274.64 -2.00 20.00 -2.00 321.48 0.00e+00 -8.624017e-04 6.111987e-04 5.863744e-05 1.652568e-05 1.193320e-03 274.64 -2.00 20.00 -2.00 321.43 0.00e+00 2.899274e-01 3.447659e-03 1.352557e-04 4.371419e-03 7.098333e-03 228.82 2.81 0.00 0.39 12.04 317.74 0.00e+00 -5.301001e-05 1.791252e-04 1.775357e-05 1.408389e-05 1.747142e-04 274.64 -2.00 20.00 -2.00 316.80 0.00e+00 2.524 0.000 303.00 329.40 4 2.4228e+00 9.0675e-03 2.3931e-02 1.8678e-03 2.1763e-02 -3.8909e-03 1.2471e-02 2.5684e-03 3.8707e-04 2.3634e-02 -5.1690e-04 6.7476e-03 3.5254e-04 2.0377e-04 1.2870e-02 1.4350e-03 3.2454e-03 9.4264e-05 5.3105e-05 5.2212e-03 -7.7863e-04 2.0118e-03 5.2768e-05 7.0000e-05 3.4703e-03 3.6416e-03 -2.0448e-03 1.1851e-03 3.6795e-05 1.0537e-05 1.0524e-03 -1.7452e-04 6.9697e-05 2.2229e-06 1.6713e-06 1.6985e-04 7.9951e-03 0.0000e+00 -1.6028e+00 2.0897e-01 1.9819e-03 9.3537e-04 4.1978e-01 12 9 9 12 1 1 99.38 19.54 0.25 0.00800 0.00666 7 134 1 5 0 224.148 23.32 14.83 19.54 10.21 2.5 953.27 -373 579 -1275 -3692 1075 -1787 814 51 1119 -202 13 1186 241 -146 453 -433 1056 328 -294 -521 -73 238 751 -489 -804 -912 340 -97 -389 224 -776 -189 -25 713 -30 826 196 -364 -63 322 -140 -280 6 689 528 -425 -245 -273 -359 127 292 -178 -269 -423 -61 261 -526 -328 326 224 745 -24 -13 -69 149 243 -79 -639 -15 346 152 657 97 90 -37 -243 38 -126 -499 6 -103 182 -11 30 66 101 311 238 24 59 -212 -274 -159 -85 -6 -107 -15 -105 322 60 58 -27 100 -120 152 -282 -347 38 320 9 170 -55 469 -63 226 -177 83 323 -330 -294 29 -155 -147 179 265 78 -19 -65 -27 -270 -80 224 -19 -34 -107 92 4 167 -58 -274 -33 58 -58 53 65 55 -47 80 -188 -516 161 -283 145 10 252 -45 3 281 60 -37 114 -112 285 96 -90 -160 -21 66 202 -141 -257 -317 114 -34 -133 75 -306 -83 -12 368 -16 461 105 -207 -36 181 -78 -155 3 398 311 -268 -153 -177 -239 86 197 -119 -178 -286 -44 193 -399 -254 250 160 549 -18 -11 -57 129 210 -66 -528 -12 262 112 500 79 78 -34 -229 37 -125 -530 7 -113 200 -11 31 65 98 293 227 25 63 -239 -331 -193 -97 -6 -115 -17 -120 372 72 71 -34 131 -160 207 -374 -450 47 390 10 206 -71 618 -85 301 -229 108 401 -410 -349 35 -197 -194 240 365 107 -27 -94 -42 -408 -122 345 -30 -51 -156 135 6 252 -91 -452 -57 101 -103 96 117 99 SS 20231207T164133.8Z 8741.695530 474 1 30.05 2 66.72 173.03 69.67 241.94 0.00 1 0.00 1 0 49 2.266e-03 1.033e-03 1.453e-03 4.916e-04 1.523054e-06 1.867372e-07 6.221066e-08 3.565990e-07 1.066742e-06 222.28 -2.00 3.57 -2.00 321.86 0.00e+00 1.414758e-04 6.940440e-05 3.300169e-05 1.735454e-05 2.773102e-04 274.64 -2.00 20.00 -2.00 321.73 0.00e+00 4.463325e-04 9.210289e-05 9.008924e-06 2.458999e-05 4.944531e-04 274.64 -2.00 20.00 -2.00 321.70 0.00e+00 -3.817728e-04 1.405102e-04 1.942663e-05 1.624601e-05 5.123967e-04 274.64 -2.00 20.00 -2.00 321.73 0.00e+00 2.872131e-01 7.862732e-04 3.176732e-05 4.370494e-03 3.049678e-03 230.63 0.65 0.00 0.40 5.18 318.34 0.00e+00 3.002530e-04 4.562631e-05 5.426555e-06 1.397840e-05 7.531837e-05 274.64 -2.00 20.00 -2.00 317.39 0.00e+00 2.511 0.000 303.00 329.40 4 2.1612e+00 2.0418e-03 2.3799e-02 1.8692e-03 9.3502e-03 -2.9127e-03 2.9042e-03 2.5030e-03 3.8834e-04 1.0154e-02 -3.4399e-03 1.5651e-03 3.0832e-04 2.1700e-04 5.5256e-03 5.0482e-03 7.6309e-04 3.7453e-04 6.8154e-05 2.2359e-03 -2.2426e-03 4.5665e-04 6.4611e-05 7.1299e-05 1.4894e-03 4.7599e-03 -4.4691e-04 3.0991e-04 6.5421e-05 1.5618e-05 4.5007e-04 -8.3488e-05 1.5434e-05 3.1460e-06 1.7277e-06 7.2911e-05 7.7553e-03 0.0000e+00 -1.4409e+00 4.6770e-02 1.7028e-03 6.4496e-04 1.8056e-01 11 9 0 11 8 0 99.98 19.70 0.18 0.00776 0.00712 271 271 1 5 0 110.834 23.32 14.96 19.70 10.70 2.4 955.71 -190 -528 -88 -1002 -193 -827 533 -259 346 -191 576 188 536 320 345 -38 297 309 36 -398 -463 -315 -904 -542 -226 -72 -256 29 -143 -317 -66 92 -83 37 186 87 133 221 -43 103 87 -127 200 -77 17 83 -19 -24 155 25 -77 -130 25 -119 90 -66 -73 -99 81 122 133 230 33 -87 53 17 -27 -313 -137 93 318 186 60 -13 -113 -60 77 19 -195 2 -38 35 -93 -37 22 185 169 12 21 -10 -167 -270 -116 32 -71 32 21 47 146 96 -80 31 49 -27 -131 -78 -51 72 130 135 107 120 19 -59 -87 -77 166 252 20 -23 16 1 -17 -61 -46 4 86 37 -30 -46 -39 -47 41 27 -168 -73 72 30 -23 -13 -79 -80 12 -26 47 128 -17 -52 -9 -105 -21 -100 74 -41 61 -36 110 38 111 68 73 -8 68 69 9 -93 -113 -73 -206 -130 -60 -19 -71 8 -40 -88 -21 35 -34 16 88 42 65 109 -21 50 42 -61 96 -39 9 48 -12 -14 93 15 -47 -78 15 -72 59 -47 -55 -72 59 83 88 162 24 -71 45 15 -22 -241 -102 64 209 128 47 -11 -101 -54 73 19 -196 2 -41 38 -97 -39 21 175 156 11 21 -10 -194 -316 -136 37 -76 34 24 52 174 113 -98 40 63 -37 -183 -106 -69 90 154 167 131 156 25 -79 -114 -104 217 316 25 -28 19 1 -22 -81 -63 5 125 53 -46 -72 -63 -75 65 41 -247 -111 106 48 -38 -23 -140 -145 22 -50 90 243