File name: Pandora103s1_Downsview_20240218_L2Fit_fwvt1c6d20230525p1-8.txt
File generation date: 20240829T221537.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c6p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 103
Spectrometer number: 1
Processing software version used: BlickP v1.8.59
Instrument operation file used: Pandora103_OF_v3d20221207.txt
Instrument calibration file used: Pandora103s1_CF_v6d20230525.txt
Level 1 file used: Pandora103s1_Downsview_20240218_L1_smca1c6d20230525p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20240218
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1770
Nominal wavelengths inside fitting window [nm]: 492.1005 492.2217 492.3429 492.4641 492.5853 492.7064 492.8276 492.9487 493.0698 493.1909 493.3119 493.4330 493.5540 493.6750 493.7960 493.9170 494.0380 494.1590 494.2799 494.4008 494.5217 494.6426 494.7635 494.8843 495.0052 495.1260 495.2468 495.3676 495.4883 495.6091 495.7298 495.8505 495.9712 496.0919 496.2126 496.3332 496.4538 496.5745 496.6951 496.8156 496.9362 497.0568 497.1773 497.2978 497.4183 497.5388 497.6592 497.7797 497.9001 498.0205 498.1409 498.2613 498.3816 498.5020 498.6223 498.7426 498.8629 498.9832 499.1034 499.2237 499.3439 499.4641 499.5843 499.7045 499.8246 499.9448 500.0649 500.1850 500.3051 500.4251 500.5452 500.6652 500.7852 500.9052 501.0252 501.1452 501.2651 501.3851 501.5050 501.6249 501.7447 501.8646 501.9845 502.1043 502.2241 502.3439 502.4637 502.5834 502.7032 502.8229 502.9426 503.0623 503.1819 503.3016 503.4212 503.5408 503.6604 503.7800 503.8996 504.0191 504.1387 504.2582 504.3777 504.4972 504.6166 504.7361 504.8555 504.9749 505.0943 505.2137 505.3330 505.4524 505.5717 505.6910 505.8103 505.9296 506.0488 506.1680 506.2873 506.4065 506.5256 506.6448 506.7639 506.8831 507.0022 507.1213 507.2404 507.3594 507.4785 507.5975 507.7165 507.8355 507.9544 508.0734 508.1923 508.3112 508.4301 508.5490 508.6679 508.7867 508.9056 509.0244 509.1432 509.2619 509.3807 509.4994 509.6181 509.7369 509.8555 509.9742
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20240218T143800.3Z 8814.609726 321 1 8.59 2 68.08 133.44 105.37 23.31 0.00 1 0.00 1 0 15 4.405e-03 4.382e-03 1.595e-03 1.592e-03 6.608296e+02 8.097723e+01 5.094193e+01 -6.000000e+00 2.218957e+02 272.07 -2.00 20.00 -2.00 505.27 0.00e+00 7.760082e-04 4.164221e-05 4.266243e-05 -6.000000e+00 1.180467e-04 272.07 -2.00 20.00 -2.00 500.51 0.00e+00 4.391238e-01 3.038325e-02 8.757911e-03 -6.000000e+00 8.489472e-02 224.76 -2.00 3.57 -2.00 502.09 0.00e+00 2.656 0.000 489.00 513.00 1 7.3501e+00 2.3166e-03 3.9056e-03 -6.0000e+00 6.4715e-03 6.9941e-03 6.0958e-04 2.5744e-04 -6.0000e+00 1.7044e-03 8.3428e-04 8.1397e-04 1.2216e-04 1.2902e-05 -6.0000e+00 3.4450e-04 6.9579e-03 2.5052e-05 12 9 1 12 1 1 99.82 18.38 0.66 0.00696 0.01260 3 14 1 4 0 2145.413 22.40 14.22 18.38 0.79 2.9 920.56 -889 -1088 -122 71 462 557 663 859 723 164 124 26 -161 -319 -585 -579 -398 212 471 202 472 444 192 459 444 228 38 273 -152 -929 -605 -694 -245 271 105 117 208 247 -104 205 -351 186 76 297 484 445 214 -154 -25 -273 -671 -986 -889 -498 -322 -5 285 207 232 359 655 147 404 593 150 101 -27 -232 -209 -771 -567 -20 -370 67 -79 -547 -304 -844 -323 -730 -447 -390 -364 -168 204 -74 -242 214 -35 -60 51 368 329 511 343 205 -95 -296 -561 -1158 -631 -657 -246 320 -380 -533 -346 -582 -221 -239 -102 560 489 439 468 799 957 817 270 428 419 135 305 378 235 399 417 177 320 -4 103 -365 -252 -396 -196 273 -10 -123 128 282 255 219 279 255 -39 105 -323 -887 -643 -368 -869 -1055 -122 73 466 575 695 901 756 168 126 26 -165 -324 -590 -590 -399 219 497 213 497 467 202 487 457 242 40 284 -154 -937 -606 -703 -248 277 109 120 218 256 -106 209 -361 193 79 304 497 457 217 -160 -25 -269 -667 -961 -859 -492 -320 -5 295 213 238 366 671 153 419 612 153 101 -27 -227 -202 -764 -558 -20 -359 67 -79 -534 -299 -824 -314 -711 -439 -372 -349 -163 199 -73 -239 210 -34 -59 51 363 329 506 346 204 -92 -282 -542 -1101 -604 -622 -243 316 -378 -523 -344 -568 -216 -238 -100 554 489 443 473 810 973 828 270 420 404 134 294 368 229 387 404 170 309 -4 99 -353 -240 -374 -186 267 -10 -120 127 281 254 219 281 258 -40 105 -313 -837 -620 -358
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SQ 20240218T144717.5Z 8814.616175 327 1 30.09 2 66.88 135.54 104.70 25.23 0.00 1 0.00 1 0 15 3.812e-03 3.777e-03 9.181e-04 9.160e-04 6.319289e+02 4.670784e+01 5.047126e+01 -6.000000e+00 1.920008e+02 272.07 -2.00 20.00 -2.00 505.26 0.00e+00 7.037494e-04 2.394835e-05 3.979802e-05 -6.000000e+00 1.021414e-04 272.07 -2.00 20.00 -2.00 500.46 0.00e+00 3.977130e-01 1.753815e-02 7.898331e-03 -6.000000e+00 7.347426e-02 224.76 -2.00 3.57 -2.00 502.05 0.00e+00 2.527 0.000 489.00 513.00 1 7.7399e+00 1.3348e-03 3.7050e-03 -6.0000e+00 5.6008e-03 1.3335e-02 3.5336e-04 2.4059e-04 -6.0000e+00 1.4754e-03 5.7753e-04 1.0888e-03 7.0311e-05 1.2104e-05 -6.0000e+00 2.9806e-04 8.4058e-03 1.7256e-06 10 0 0 10 0 0 99.94 18.62 0.62 0.00841 0.01596 11 11 1 4 0 2735.030 22.40 14.09 18.62 1.15 2.9 921.74 -792 -778 -98 256 296 651 670 515 630 72 153 60 -244 9 -512 -131 -434 145 439 156 291 198 433 47 278 274 80 76 53 -780 -510 -550 -162 1 270 181 41 -77 -188 173 22 195 75 273 377 280 189 22 -43 -511 -649 -853 -919 -427 -351 -149 182 146 287 309 326 380 251 418 311 143 -131 -223 -365 -348 -386 -417 -383 221 84 -301 -474 -564 -215 -512 -421 -287 -246 -51 -126 -209 255 -18 -186 -158 71 137 324 521 219 278 -154 -627 -270 -841 -550 -602 -155 104 -205 -312 -375 -536 -360 -120 -27 401 365 589 720 624 828 595 221 388 252 -207 399 409 214 288 263 -12 246 243 -68 -311 -449 -508 -241 -102 155 185 370 255 373 322 404 421 79 -164 -229 -594 -669 -463 -756 -763 -99 267 299 673 703 543 660 74 155 60 -253 9 -523 -135 -435 150 464 164 306 209 456 50 297 290 84 79 53 -794 -517 -563 -163 1 290 192 43 -80 -192 176 22 201 78 288 401 297 198 22 -44 -504 -650 -837 -895 -425 -347 -151 187 150 293 313 333 391 259 429 315 142 -128 -217 -352 -329 -382 -397 -370 218 83 -291 -447 -552 -210 -500 -396 -271 -234 -49 -123 -205 249 -18 -182 -155 71 139 332 531 220 275 -149 -593 -261 -800 -527 -565 -152 105 -208 -314 -370 -519 -349 -119 -27 407 358 580 709 620 825 591 216 389 250 -203 394 408 213 286 262 -12 243 242 -66 -297 -423 -474 -226 -98 152 176 357 248 362 314 396 415 78 -159 -216 -570 -635 -444
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