File name: Pandora103s1_Downsview_20240330_L2Fit_fwvt1c3d20230309p1-8.txt File generation date: 20240331T053254.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora103_OF_v3d20221207.txt Instrument calibration file used: Pandora103s1_CF_v3d20230309.txt Level 1 file used: Pandora103s1_Downsview_20240330_L1_smca1c3d20230309p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240330 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 2 "Initial 1.8 calibration for delrin-free head sensor, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1166 492.2379 492.3591 492.4803 492.6015 492.7226 492.8438 492.9649 493.0860 493.2071 493.3282 493.4493 493.5703 493.6914 493.8124 493.9334 494.0544 494.1753 494.2963 494.4172 494.5381 494.6590 494.7799 494.9008 495.0216 495.1424 495.2633 495.3841 495.5048 495.6256 495.7463 495.8671 495.9878 496.1085 496.2292 496.3498 496.4705 496.5911 496.7117 496.8323 496.9529 497.0734 497.1940 497.3145 497.4350 497.5555 497.6760 497.7964 497.9169 498.0373 498.1577 498.2781 498.3984 498.5188 498.6391 498.7595 498.8798 499.0000 499.1203 499.2406 499.3608 499.4810 499.6012 499.7214 499.8416 499.9617 500.0818 500.2020 500.3221 500.4421 500.5622 500.6822 500.8023 500.9223 501.0423 501.1622 501.2822 501.4021 501.5221 501.6420 501.7619 501.8817 502.0016 502.1214 502.2413 502.3611 502.4808 502.6006 502.7204 502.8401 502.9598 503.0795 503.1992 503.3189 503.4385 503.5581 503.6777 503.7973 503.9169 504.0365 504.1560 504.2755 504.3950 504.5145 504.6340 504.7535 504.8729 504.9923 505.1117 505.2311 505.3505 505.4698 505.5892 505.7085 505.8278 505.9470 506.0663 506.1856 506.3048 506.4240 506.5432 506.6624 506.7815 506.9007 507.0198 507.1389 507.2580 507.3770 507.4961 507.6151 507.7341 507.8531 507.9721 508.0911 508.2100 508.3289 508.4478 508.5667 508.6856 508.8045 508.9233 509.0421 509.1609 509.2797 509.3985 509.5172 509.6360 509.7547 509.8734 509.9921 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240330T110818.9Z 8855.464108 289 1 30.02 2 89.70 84.67 75.88 208.23 0.00 1 0.00 1 0 15 1.181e-02 1.163e-02 3.095e-04 3.078e-04 8.619978e+03 1.832353e+01 6.018641e+02 -6.000000e+00 5.932368e+02 275.67 -2.00 20.00 -2.00 505.46 0.00e+00 6.722416e-03 8.186407e-06 3.607375e-04 -6.000000e+00 3.171574e-04 275.67 -2.00 20.00 -2.00 501.22 0.00e+00 1.992145e+00 5.726050e-03 8.719283e-02 -6.000000e+00 2.259922e-01 226.98 -2.00 3.57 -2.00 502.69 0.00e+00 20.225 0.161 489.00 513.00 1 2.7237e+00 4.3556e-04 3.7960e-02 -6.0000e+00 1.7230e-02 -5.1901e-02 1.1181e-04 2.6416e-03 -6.0000e+00 4.5571e-03 5.9717e-03 8.4296e-04 2.2304e-05 1.2034e-04 -6.0000e+00 8.9855e-04 1.3205e-03 -1.9704e-06 12 9 9 12 4 4 86.60 19.30 4.03 0.00132 0.00717 135 135 1 4 0 222.334 22.90 15.05 19.30 3.04 3.1 932.83 -3477 -2274 -863 255 810 1315 1705 1706 1169 586 86 -445 -942 -1357 -1351 -1174 -560 326 898 931 733 605 798 1019 1319 1207 1121 426 -963 -2058 -2175 -1693 -406 808 1249 941 440 -5 -406 -224 -3 471 857 1372 1544 1431 1153 715 -12 -868 -1899 -2543 -2471 -1672 -340 607 945 921 743 673 955 1219 1352 1149 783 114 -280 -481 -1017 -1377 -1389 -1075 -361 -17 59 -627 -1351 -1646 -1803 -1593 -1233 -1120 -969 -674 -304 -247 -392 -558 -453 -304 163 876 1333 1371 1046 702 -26 -1038 -2139 -2620 -2321 -1512 -133 584 447 -286 -983 -1379 -1089 -392 367 976 1456 1683 1955 2238 2188 1721 1100 589 96 26 451 751 758 796 664 613 742 463 -84 -769 -1264 -1490 -1140 -348 253 583 693 720 534 540 803 953 748 -7 -1048 -1907 -2087 -1651 -3023 -2030 -766 232 749 1241 1632 1577 1119 553 81 -413 -866 -1242 -1234 -1081 -526 302 848 878 692 574 760 984 1284 1179 1095 413 -908 -1890 -1996 -1574 -389 777 1219 913 424 -4 -388 -215 -2 463 857 1393 1528 1421 1139 726 -12 -856 -1836 -2429 -2360 -1637 -344 608 959 936 754 684 978 1261 1403 1192 804 115 -281 -480 -1010 -1350 -1359 -1060 -360 -17 60 -626 -1326 -1603 -1753 -1546 -1203 -1099 -953 -671 -305 -248 -392 -555 -448 -302 164 870 1340 1360 1049 687 -25 -982 -2072 -2503 -2225 -1435 -132 582 451 -288 -980 -1364 -1086 -400 381 1027 1492 1733 2022 2343 2335 1854 1176 620 100 27 467 790 803 849 711 655 799 486 -90 -810 -1327 -1565 -1213 -367 272 631 763 776 580 590 882 1050 824 -7 -1125 -2076 -2267 -1818 SQ 20240330T111109.1Z 8855.466077 293 1 29.99 2 89.19 85.16 76.12 208.81 0.00 1 0.00 1 0 22 9.681e-03 9.524e-03 1.641e-04 1.634e-04 7.228828e+03 9.556780e+00 5.133813e+02 -6.000000e+00 4.861637e+02 275.67 -2.00 20.00 -2.00 505.43 0.00e+00 5.840706e-03 4.336424e-06 3.150389e-04 -6.000000e+00 2.599293e-04 275.67 -2.00 20.00 -2.00 501.13 0.00e+00 1.968132e+00 3.047490e-03 7.396927e-02 -6.000000e+00 1.852389e-01 226.98 -2.00 3.57 -2.00 502.61 0.00e+00 19.239 0.139 489.00 513.00 1 1.6369e+00 2.3189e-04 3.4635e-02 -6.0000e+00 1.4123e-02 -3.8583e-02 5.9762e-05 2.3347e-03 -6.0000e+00 3.7360e-03 2.0624e-02 7.5509e-04 1.1931e-05 1.0527e-04 -6.0000e+00 7.3655e-04 2.3213e-03 -1.8648e-05 12 9 9 12 4 4 23.85 19.23 2.90 0.00232 0.00756 388 388 1 4 0 77.265 23.01 14.83 19.23 3.21 3.1 933.09 -2699 -1716 -553 307 792 1176 1548 1517 1045 583 143 -251 -690 -1087 -1104 -984 -426 298 743 788 541 498 608 791 1042 1032 936 321 -764 -1647 -1786 -1433 -387 562 1034 728 264 -114 -301 -291 -85 300 624 993 1194 1099 808 513 -59 -792 -1602 -2151 -2065 -1388 -363 418 746 750 629 532 761 965 1039 875 579 128 -189 -439 -829 -1103 -1154 -810 -321 9 32 -453 -1033 -1385 -1472 -1310 -1009 -896 -804 -555 -258 -203 -347 -435 -336 -308 71 675 1083 1074 863 533 -10 -907 -1769 -2178 -1972 -1238 -191 395 370 -180 -890 -1175 -963 -332 302 799 1198 1436 1618 1803 1784 1475 965 476 118 63 356 566 648 693 629 518 724 435 -20 -544 -971 -1234 -892 -303 233 443 567 568 500 485 705 827 625 47 -863 -1596 -1767 -1367 -2349 -1535 -514 283 742 1125 1453 1431 981 557 135 -235 -641 -1004 -1018 -915 -404 281 714 757 521 481 590 778 1032 1024 928 316 -730 -1527 -1653 -1345 -376 550 1028 719 258 -111 -292 -283 -83 298 631 989 1201 1108 810 509 -60 -784 -1551 -2053 -1969 -1356 -356 421 763 767 642 543 784 1002 1051 884 597 130 -189 -438 -822 -1079 -1127 -796 -319 9 33 -452 -1011 -1345 -1426 -1267 -982 -878 -790 -552 -259 -204 -347 -432 -333 -307 72 676 1098 1077 872 526 -9 -863 -1710 -2075 -1887 -1178 -191 397 376 -182 -890 -1163 -960 -338 305 817 1236 1489 1684 1900 1857 1545 1002 502 122 65 369 596 686 715 651 536 753 456 -20 -568 -1010 -1282 -938 -318 249 478 604 612 541 529 774 910 688 51 -922 -1673 -1897 -1446 SQ 20240330T111358.2Z 8855.468035 297 1 30.04 2 88.68 85.64 76.37 209.39 0.00 1 0.00 1 0 15 8.223e-03 8.137e-03 1.217e-04 1.214e-04 6.111638e+03 6.992232e+00 4.380016e+02 -6.000000e+00 4.129826e+02 275.67 -2.00 20.00 -2.00 505.40 0.00e+00 4.793119e-03 3.214984e-06 2.605181e-04 -6.000000e+00 2.207897e-04 275.67 -2.00 20.00 -2.00 501.03 0.00e+00 1.967421e+00 2.268501e-03 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