File name: Pandora103s1_Downsview_20240509_L2Fit_fout2c3d20230309p1-8.txt File generation date: 20240511T125535.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora103_OF_v3d20221207.txt Instrument calibration file used: Pandora103s1_CF_v3d20230309.txt Level 1 file used: Pandora103s1_Downsview_20240509_L1_smca1c3d20230309p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 2 "Initial 1.8 calibration for delrin-free head sensor, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0640 305.2047 305.3453 305.4860 305.6266 305.7672 305.9079 306.0485 306.1891 306.3296 306.4702 306.6108 306.7513 306.8919 307.0324 307.1730 307.3135 307.4540 307.5945 307.7350 307.8755 308.0160 308.1564 308.2969 308.4373 308.5778 308.7182 308.8586 308.9991 309.1395 309.2798 309.4202 309.5606 309.7010 309.8413 309.9817 310.1220 310.2623 310.4027 310.5430 310.6833 310.8236 310.9638 311.1041 311.2444 311.3846 311.5249 311.6651 311.8053 311.9455 312.0857 312.2259 312.3661 312.5063 312.6464 312.7866 312.9267 313.0669 313.2070 313.3471 313.4872 313.6273 313.7674 313.9075 314.0475 314.1876 314.3276 314.4677 314.6077 314.7477 314.8877 315.0277 315.1677 315.3077 315.4477 315.5876 315.7276 315.8675 316.0074 316.1473 316.2872 316.4271 316.5670 316.7069 316.8468 316.9866 317.1265 317.2663 317.4061 317.5459 317.6857 317.8255 317.9653 318.1051 318.2449 318.3846 318.5244 318.6641 318.8038 318.9435 319.0832 319.2229 319.3626 319.5023 319.6419 319.7816 319.9212 320.0609 320.2005 320.3401 320.4797 320.6193 320.7588 320.8984 321.0380 321.1775 321.3170 321.4566 321.5961 321.7356 321.8751 322.0146 322.1540 322.2935 322.4329 322.5724 322.7118 322.8512 322.9906 323.1300 323.2694 323.4088 323.5482 323.6875 323.8269 323.9662 324.1055 324.2448 324.3841 324.5234 324.6627 324.8020 324.9412 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240509T103317.8Z 8895.439789 135 1 29.21 2 85.07 70.34 91.19 53.26 0.00 1 0.00 1 0 25 6.821e-01 7.320e-02 4.656e-01 6.666e-02 1.047809e+00 3.853191e-02 1.203277e-02 -6.000000e+00 4.068943e-01 230.41 -2.00 3.57 -2.00 321.56 0.00e+00 -3.254242e-02 9.819326e-03 4.655391e-03 -6.000000e+00 1.919164e-02 280.24 -2.00 20.00 -2.00 320.82 0.00e+00 9.920 0.019 302.00 328.00 3 7.1561e-01 1.1613e-01 1.2402e-01 -6.0000e+00 1.0220e+00 2.3888e+00 1.3647e-01 1.0108e-01 -6.0000e+00 1.1114e+00 -2.4141e+00 7.6630e-02 2.6256e-02 -6.0000e+00 6.5549e-01 7.9032e-01 4.1405e-02 2.7027e-02 -6.0000e+00 2.7346e-01 4.6045e-06 2.8927e-03 1.6994e-03 4.2007e-04 -6.0000e+00 2.0027e-02 -3.9046e-03 -4.8427e-05 12 9 9 12 4 4 99.25 19.53 1.32 -0.00390 0.01783 11 11 1 5 0 2654.969 23.22 14.83 19.53 14.13 2.8 975.54 140670 34711 900000 -35977 42007 7323 318465 -20385 207590 -49657 900000 94964 94829 -16161 244634 36346 143024 32506 68667 900000 183463 -19588 323025 177401 41957 74294 -1404 900000 60662 73290 -78023 12286 16517 900000 -62607 15357 -10161 60164 59543 81656 23740 65355 -14170 57228 50950 47079 11699 -43349 -21573 47002 27317 -16222 900000 -27017 68815 58854 185768 13287 71254 -19746 -14235 38013 52493 130275 -22536 5820 2963 -23427 107781 -7904 11580 38525 49434 -2942 28107 18293 -41356 8610 -37279 24953 -31187 -1557 23323 -875 -21924 3464 -3057 3442 -16780 27342 24581 -13390 6705 14109 -5100 8903 1905 11921 14806 11919 -5388 -10616 6333 -2096 -296 -5961 -1115 -14941 14973 6179 8144 4393 5200 -2085 -3237 -4797 477 -3990 2263 3050 -9118 10189 3184 -347 -522 -2107 -5332 116 -3106 3763 2508 -1755 -3159 563 -2573 1116 744 915 -269 1197 833 1029 -1725 9135 5447 900000 -7788 3410 793 20680 -3861 13480 -14779 900000 6681 6671 -3498 15886 4720 9288 4046 6081 900000 11914 -3353 20977 11520 5449 7017 -249 900000 3939 4759 -19806 1378 1853 900000 -13675 1451 -1320 4617 5624 7231 4064 7331 -3262 5743 4812 4169 1381 -8701 -3566 4578 3225 -3256 900000 -7018 8044 8026 12063 2510 7403 -4080 -2605 4690 6136 8460 -5721 1209 635 -6362 9799 -2333 3309 8506 9309 -841 5111 3207 -12354 1621 -12588 5347 -12519 -586 7573 -386 -11390 1597 -1408 1632 -8519 9233 7981 -6086 2525 5406 -2749 4914 1192 7671 10052 8373 -4167 -7646 3866 -1388 -204 -4607 -869 -13231 12348 5909 8750 5368 6569 -2830 -4337 -6400 611 -5582 3112 4213 -13726 11909 3816 -422 -623 -2475 -6452 145 -4731 6308 4826 -3864 -7683 1441 -7351 3236 2214 2728 -798 3329 2135 2418 -4064 SS 20240509T104248.0Z 8895.446389 138 1 29.82 2 83.44 71.93 89.84 54.81 0.00 1 0.00 1 0 25 4.267e-01 1.993e-02 4.062e-01 1.315e-02 1.026424e+00 7.795744e-03 1.099851e-02 -6.000000e+00 2.523818e-01 230.41 -2.00 3.57 -2.00 322.48 0.00e+00 1.688479e-03 4.963496e-03 1.878835e-03 -6.000000e+00 1.128440e-02 280.24 -2.00 20.00 -2.00 322.06 0.00e+00 7.949 0.010 302.00 328.00 3 8.7564e-01 3.3127e-02 9.8983e-02 -6.0000e+00 6.3091e-01 1.1573e+00 4.5360e-02 6.4048e-02 -6.0000e+00 6.8338e-01 -1.6412e+00 4.1973e-02 3.2780e-02 -6.0000e+00 4.0547e-01 6.5127e-01 1.9260e-02 1.1703e-02 -6.0000e+00 1.6999e-01 3.4498e-05 -1.1154e-03 3.5722e-04 1.7613e-04 -6.0000e+00 1.2346e-02 -4.0184e-03 -2.5091e-05 12 9 9 12 4 4 99.27 19.44 0.32 -0.00402 -0.01240 39 39 1 5 0 764.454 23.22 14.86 19.44 14.42 2.8 976.78 -31980 -67649 -69802 -36733 900000 -93150 -85961 -49123 -137256 -85548 -74251 -106616 900000 -78044 22369 -51958 -32803 64495 34740 -56729 88711 100812 -83584 -94604 89040 -36427 193431 -57453 -50695 -61013 -92281 -9632 -20188 -44482 2695 -7224 115088 -1976 -5109 19288 -7917 71589 14409 67111 51634 7438 -19243 48249 16835 -3925 44668 59301 48163 12076 14585 41789 46799 56635 20269 -4836 -3837 8573 18126 12934 22833 10576 29082 20868 26048 22635 22426 20049 7471 -1378 4588 -1811 -920 -6207 5258 7158 5154 -1459 3063 4231 -2209 4768 5728 6355 2579 3018 3759 781 -8217 -3804 -7989 -4512 -5497 -1888 -2094 893 -3599 -2997 -2457 -1544 -4272 -1018 -60 -2050 3228 2466 -325 762 463 -2177 -2051 -2039 89 -2010 432 1210 332 4173 2311 523 366 248 -184 -456 -168 -199 927 261 76 -1216 -174 334 791 1944 -5 511 -651 -1514 -1888 -410 -1104 -1139 -471 900000 -1302 -1102 -630 -3199 -1196 -952 -2112 900000 -1819 287 -1332 -764 827 445 -1785 1137 1292 -3019 -3968 1141 -891 2479 -1540 -1241 -1777 -4409 -247 -659 -1918 76 -213 1475 -66 -190 717 -387 1835 604 1806 1588 353 -1099 1608 820 -233 2004 2584 2593 915 1139 2581 3059 3267 1441 -417 -326 699 1542 1326 2315 1245 2880 2383 3187 3271 3554 3364 1384 -257 716 -268 -128 -955 839 1368 1213 -428 964 1420 -767 1772 2209 2496 1040 1164 1362 279 -3198 -1534 -3601 -2371 -3494 -1353 -1682 721 -2879 -2119 -1551 -941 -2816 -693 -43 -1636 2786 2518 -396 1016 652 -3162 -2914 -2842 123 -2974 658 1875 507 5786 3101 696 479 315 -231 -617 -266 -373 1815 566 178 -3156 -481 972 2345 5728 -16 1447 -1722 -3681 -4398 SS 20240509T105317.4Z 8895.453674 141 1 30.07 2 81.63 73.67 88.32 56.51 0.00 1 0.00 1 0 17 7.050e-01 1.600e-02 2.416e-01 4.121e-03 8.808280e-01 2.344578e-03 1.068860e-02 -6.000000e+00 4.165360e-01 230.41 -2.00 3.57 -2.00 322.06 0.00e+00 1.099764e-02 1.401136e-03 7.942158e-03 -6.000000e+00 1.809857e-02 280.24 -2.00 20.00 -2.00 321.60 0.00e+00 6.460 0.005 302.00 328.00 3 7.3537e-01 9.2317e-03 8.6784e-02 -6.0000e+00 1.0419e+00 3.7427e-01 1.4053e-02 6.2811e-02 -6.0000e+00 1.1284e+00 -6.6356e-01 1.4849e-02 3.6868e-02 -6.0000e+00 6.6993e-01 2.8355e-01 6.6174e-03 1.3919e-02 -6.0000e+00 2.8054e-01 1.9805e-04 -1.0349e-03 1.1321e-04 2.9282e-04 -6.0000e+00 2.0185e-02 -4.6080e-03 -7.7272e-06 12 9 9 12 4 4 92.42 19.68 0.25 -0.00461 -0.01238 113 113 1 5 0 266.024 23.22 14.93 19.68 15.13 2.8 979.72 -165925 -252782 -154150 -240515 -67057 -305832 -164507 -264910 -229752 -252455 -203309 -136851 -154535 -151019 -117131 8802 -107466 -24134 -40050 8553 -65452 66300 -72167 30082 -74750 -38283 -70554 -5798 -83083 -28156 -52178 4491 -22961 -15687 -21707 23092 -11489 -5034 23431 3223 24689 23278 49652 7228 35577 -3742 47480 3730 49229 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