File name: Pandora103s1_Downsview_20240518_L2Fit_fout2c3d20230309p1-8.txt File generation date: 20240519T052229.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora103_OF_v3d20221207.txt Instrument calibration file used: Pandora103s1_CF_v3d20230309.txt Level 1 file used: Pandora103s1_Downsview_20240518_L1_smca1c3d20230309p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240518 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB-data based on session 2 "Initial 1.8 calibration for delrin-free head sensor, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0640 305.2047 305.3453 305.4860 305.6266 305.7672 305.9079 306.0485 306.1891 306.3296 306.4702 306.6108 306.7513 306.8919 307.0324 307.1730 307.3135 307.4540 307.5945 307.7350 307.8755 308.0160 308.1564 308.2969 308.4373 308.5778 308.7182 308.8586 308.9991 309.1395 309.2798 309.4202 309.5606 309.7010 309.8413 309.9817 310.1220 310.2623 310.4027 310.5430 310.6833 310.8236 310.9638 311.1041 311.2444 311.3846 311.5249 311.6651 311.8053 311.9455 312.0857 312.2259 312.3661 312.5063 312.6464 312.7866 312.9267 313.0669 313.2070 313.3471 313.4872 313.6273 313.7674 313.9075 314.0475 314.1876 314.3276 314.4677 314.6077 314.7477 314.8877 315.0277 315.1677 315.3077 315.4477 315.5876 315.7276 315.8675 316.0074 316.1473 316.2872 316.4271 316.5670 316.7069 316.8468 316.9866 317.1265 317.2663 317.4061 317.5459 317.6857 317.8255 317.9653 318.1051 318.2449 318.3846 318.5244 318.6641 318.8038 318.9435 319.0832 319.2229 319.3626 319.5023 319.6419 319.7816 319.9212 320.0609 320.2005 320.3401 320.4797 320.6193 320.7588 320.8984 321.0380 321.1775 321.3170 321.4566 321.5961 321.7356 321.8751 322.0146 322.1540 322.2935 322.4329 322.5724 322.7118 322.8512 322.9906 323.1300 323.2694 323.4088 323.5482 323.6875 323.8269 323.9662 324.1055 324.2448 324.3841 324.5234 324.6627 324.8020 324.9412 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240518T120200.9Z 8904.501399 285 1 11.55 2 68.05 83.24 131.34 328.17 0.00 1 0.00 1 0 25 7.419e-02 1.322e-02 5.209e-02 5.303e-03 4.094325e-01 2.762533e-03 4.929298e-03 -6.000000e+00 4.409956e-02 231.14 -2.00 3.57 -2.00 318.80 0.00e+00 8.170127e-04 6.196035e-04 1.482834e-03 -6.000000e+00 1.913638e-03 281.24 -2.00 20.00 -2.00 318.12 0.00e+00 2.652 0.000 302.00 328.00 3 4.7688e+00 7.6073e-03 3.4268e-02 -6.0000e+00 1.1049e-01 2.6240e-03 8.7144e-03 2.2367e-02 -6.0000e+00 1.1941e-01 -3.1665e-03 6.2112e-03 1.1091e-02 -6.0000e+00 7.0900e-02 -5.0452e-04 3.2513e-03 3.1600e-03 -6.0000e+00 2.9809e-02 1.9792e-04 2.2601e-03 1.5684e-04 3.5150e-05 -6.0000e+00 2.1220e-03 -2.8441e-02 9.8086e-05 12 9 9 12 5 5 95.09 19.58 0.21 -0.02844 -0.01146 3 10 1 5 0 2886.383 23.43 14.83 19.58 24.34 2.6 1015.44 -4267 -17028 20822 -31906 40739 -29346 -4485 -23020 9349 -12258 22780 -24447 11827 -3999 7369 -2567 -3387 10805 7280 612 -4038 -4942 -7721 4916 -9259 6931 -9375 3235 -6742 1322 -8713 3346 889 -1848 -5178 -5997 -7930 -2068 349 1344 -2223 293 257 -915 2395 466 2674 -471 1593 -902 4078 -323 1870 3367 3957 1776 225 1066 2270 -2181 -1364 3502 2396 2593 917 -448 -1533 -1607 -343 1523 -147 1087 648 1843 7 -1360 -3623 -4244 -3811 -1759 -2598 -1390 -3156 -937 -1031 480 1409 1579 1751 951 1388 -1024 -1032 -3651 -913 -1555 749 649 1221 257 34 -2092 -2426 -1129 -691 -750 -313 -81 1264 2168 2638 1494 967 686 -551 -932 -1335 422 -91 957 110 1173 685 583 -256 55 -1910 -1638 -955 -546 -667 -649 -1027 -83 -226 -150 887 883 532 278 76 -454 -224 -122 -619 554 -1356 825 -1095 -141 -971 329 -558 777 -1377 546 -255 498 -215 -310 923 683 64 -456 -569 -934 562 -1302 877 -1387 414 -923 169 -1313 508 153 -342 -971 -1112 -1592 -459 90 396 -744 102 93 -341 871 174 983 -178 595 -353 1621 -143 870 1639 1990 934 122 576 1207 -1192 -758 1982 1474 1705 624 -300 -989 -1030 -231 1109 -116 889 533 1461 5 -978 -2474 -2830 -2642 -1322 -2177 -1251 -3050 -930 -1072 517 1571 1808 1999 1073 1496 -1062 -1014 -3625 -929 -1714 882 822 1618 346 44 -2600 -2893 -1344 -855 -970 -417 -111 1795 3232 4084 2390 1542 1058 -819 -1338 -1913 614 -139 1489 174 1837 1051 874 -378 78 -2680 -2303 -1398 -845 -1086 -1077 -1744 -144 -409 -280 1674 1687 1020 527 142 -820 -396 SS 20240518T120709.9Z 8904.504975 288 1 7.73 2 67.13 84.09 131.82 329.70 0.00 1 0.00 1 0 25 2.918e-02 1.156e-02 3.998e-03 6.514e-04 3.922075e-01 3.385883e-04 4.698456e-03 -6.000000e+00 1.730139e-02 231.14 -2.00 3.57 -2.00 318.21 0.00e+00 1.729183e-03 6.302266e-05 8.298702e-04 -6.000000e+00 7.518477e-04 281.24 -2.00 20.00 -2.00 317.51 0.00e+00 2.552 0.000 302.00 328.00 3 8.2137e-01 9.1618e-04 3.2713e-02 -6.0000e+00 4.3345e-02 -2.9527e-02 1.0346e-03 2.0763e-02 -6.0000e+00 4.6889e-02 -3.3489e-03 6.7902e-04 1.0279e-02 -6.0000e+00 2.7839e-02 -9.4535e-04 3.5081e-04 3.0431e-03 -6.0000e+00 1.1666e-02 1.1740e-02 -2.3003e-04 1.9085e-05 3.2357e-05 -6.0000e+00 8.3517e-04 -8.9944e-03 1.1848e-04 12 9 9 12 5 5 99.65 19.61 0.18 -0.00899 -0.01072 133 520 1 5 0 57.612 23.43 14.96 19.61 24.83 2.6 1018.81 -5911 -3012 -4010 -7232 -7854 -12216 -10296 -8520 -6415 -9397 -7513 -9092 -5510 -3994 792 -224 1398 1081 2101 582 1594 -36 893 -41 -306 -1018 -2756 -3415 -3951 -3886 -2929 -857 -802 -3387 -5139 -4768 -5222 -1714 73 443 255 1183 1231 1056 1577 1673 765 588 17 433 758 1251 1701 1746 1336 1525 1046 228 191 77 1067 2046 2857 2710 1574 78 -1195 -1878 -103 610 716 649 573 299 -577 -1858 -3186 -4280 -3614 -2595 -1975 -1610 -1806 -1278 -593 183 1179 1442 1295 1409 793 -378 -1908 -1994 -1748 -940 23 831 815 540 -425 -1798 -1524 -854 -766 -561 53 253 1241 1805 2129 1837 1350 515 -448 -984 -906 -652 199 402 868 998 858 259 153 -956 -1662 -1257 -1036 -490 -361 -770 -691 -313 -95 146 589 855 654 591 179 -555 -755 -264 -149 -209 -377 -382 -591 -513 -473 -391 -626 -505 -662 -446 -383 86 -28 187 155 290 86 239 -5 138 -7 -55 -192 -529 -639 -721 -711 -574 -187 -194 -879 -1328 -1204 -1414 -487 25 162 104 512 555 486 730 780 360 277 8 211 365 653 957 976 782 923 651 143 118 47 666 1363 1956 2012 1216 59 -860 -1339 -78 486 594 566 502 253 -485 -1434 -2405 -3146 -2785 -2117 -1735 -1494 -1819 -1295 -634 198 1343 1695 1524 1608 898 -398 -1984 -2037 -1804 -1073 29 1067 1079 726 -545 -2221 -1844 -1039 -949 -740 70 349 1737 2614 3290 2833 2063 781 -664 -1384 -1260 -938 290 619 1360 1540 1282 376 222 -1335 -2329 -1761 -1491 -738 -561 -1247 -1112 -525 -162 264 1055 1553 1196 1062 321 -952 -1310 SS 20240518T121227.9Z 8904.508656 291 1 29.95 2 66.18 84.96 132.29 331.30 0.00 1 0.00 1 0 25 2.539e-02 1.102e-02 3.030e-03 4.115e-04 3.784527e-01 2.140818e-04 4.523243e-03 -6.000000e+00 1.505744e-02 231.14 -2.00 3.57 -2.00 318.60 0.00e+00 1.587584e-03 4.484654e-05 9.609168e-04 -6.000000e+00 6.542190e-04 281.24 -2.00 20.00 -2.00 317.91 0.00e+00 2.458 0.000 302.00 328.00 3 1.1694e+00 5.8508e-04 3.1587e-02 -6.0000e+00 3.7723e-02 -2.5414e-02 6.6577e-04 2.0204e-02 -6.0000e+00 4.0805e-02 4.4336e-03 4.5605e-04 1.0057e-02 -6.0000e+00 2.4227e-02 -5.9478e-03 2.3685e-04 2.9752e-03 -6.0000e+00 1.0154e-02 9.1989e-03 -3.4055e-05 1.2229e-05 3.1596e-05 -6.0000e+00 7.2669e-04 -1.0332e-02 1.1538e-04 12 9 9 12 4 4 99.97 19.85 0.16 -0.01033 -0.01059 659 659 1 5 0 45.434 23.43 14.95 19.85 25.61 2.6 1021.39 -2292 -3087 -1134 -5987 -5683 -10847 -7654 -7702 -4894 -8340 -6802 -8278 -5076 -3191 412 -535 797 396 1574 1989 1188 911 514 187 -495 -526 -2693 -3250 -3687 -2884 -2415 -709 -407 -2879 -5431 -4897 -5047 -2006 -385 59 23 792 744 697 1392 1259 716 297 -359 -106 991 1019 1570 1547 1123 1331 1059 128 102 89 914 1861 2754 2680 1353 48 -1176 -1960 -74 635 702 850 493 493 -435 -1679 -3193 -4202 -3531 -2542 -1912 -1326 -1879 -1276 -476 266 1160 1504 1526 1459 909 -305 -1805 -1871 -1533 -915 112 877 816 499 -363 -1842 -1612 -835 -811 -621 49 147 1096 1813 2021 1775 1355 412 -450 -1057 -1014 -664 28 422 790 861 698 170 101 -991 -1701 -1304 -1112 -496 -287 -788 -751 -306 -60 168 642 866 630 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