File name: Pandora103s1_Downsview_20240528_L2Fit_fout2c6d20230525p1-8.txt File generation date: 20240830T001234.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora103_OF_v3d20221207.txt Instrument calibration file used: Pandora103s1_CF_v6d20230525.txt Level 1 file used: Pandora103s1_Downsview_20240528_L1_smca1c6d20230525p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.0579 305.1986 305.3393 305.4799 305.6206 305.7612 305.9018 306.0425 306.1831 306.3237 306.4643 306.6049 306.7454 306.8860 307.0266 307.1671 307.3077 307.4482 307.5887 307.7292 307.8697 308.0102 308.1507 308.2912 308.4316 308.5721 308.7125 308.8530 308.9934 309.1338 309.2742 309.4146 309.5550 309.6954 309.8357 309.9761 310.1164 310.2568 310.3971 310.5374 310.6777 310.8180 310.9583 311.0986 311.2388 311.3791 311.5193 311.6596 311.7998 311.9400 312.0802 312.2204 312.3606 312.5008 312.6410 312.7811 312.9213 313.0614 313.2015 313.3417 313.4818 313.6219 313.7620 313.9020 314.0421 314.1822 314.3222 314.4623 314.6023 314.7423 314.8823 315.0223 315.1623 315.3023 315.4422 315.5822 315.7221 315.8621 316.0020 316.1419 316.2818 316.4217 316.5616 316.7015 316.8413 316.9812 317.1210 317.2609 317.4007 317.5405 317.6803 317.8201 317.9599 318.0997 318.2394 318.3792 318.5189 318.6586 318.7984 318.9381 319.0778 319.2175 319.3571 319.4968 319.6365 319.7761 319.9157 320.0554 320.1950 320.3346 320.4742 320.6138 320.7533 320.8929 321.0324 321.1720 321.3115 321.4510 321.5905 321.7300 321.8695 322.0090 322.1485 322.2879 322.4274 322.5668 322.7062 322.8456 322.9850 323.1244 323.2638 323.4032 323.5425 323.6819 323.8212 323.9606 324.0999 324.2392 324.3785 324.5178 324.6570 324.7963 324.9355 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240528T102203.1Z 8914.431981 302 1 30.24 2 84.27 65.45 68.26 190.93 0.00 1 0.00 1 0 25 5.461e-01 2.972e-02 4.350e-01 2.584e-02 1.056067e+00 1.625101e-02 1.158102e-02 -6.000000e+00 3.392716e-01 231.78 -2.00 3.57 -2.00 322.54 0.00e+00 -6.749607e-04 9.642380e-03 2.047005e-03 -6.000000e+00 1.725712e-02 282.28 -2.00 20.00 -2.00 322.10 0.00e+00 8.846 0.013 302.00 328.00 3 1.1706e+00 6.7643e-02 1.0615e-01 -6.0000e+00 8.5464e-01 1.6808e+00 8.0332e-02 6.1065e-02 -6.0000e+00 9.2708e-01 -2.2497e+00 5.3703e-02 2.9415e-02 -6.0000e+00 5.4237e-01 8.8504e-01 2.7098e-02 8.6367e-03 -6.0000e+00 2.2598e-01 9.8402e-06 -2.0124e-03 7.2973e-04 1.3607e-04 -6.0000e+00 1.6718e-02 -4.6839e-03 0.0000e+00 12 8 8 10 0 0 99.58 19.75 0.44 -0.00468 -0.01981 17 17 1 5 0 1778.172 23.32 14.83 19.75 20.70 2.8 999.94 174709 -55909 900000 -48948 900000 900000 180350 -44055 900000 900000 68120 900000 -36999 215474 -13478 27543 2197 316790 59132 900000 -10303 131258 -31313 93189 59390 -50266 30929 50250 -45735 -81485 900000 38703 -27992 -8228 -47990 45421 133766 -3631 900000 -302 900000 49201 900000 31025 5476 27808 13144 62605 33579 -5269 96862 133871 900000 20188 15 2297 39444 39416 20402 -7275 36790 88515 24919 34625 46608 -1149 22312 79619 18173 80257 6836 27750 -4891 -1133 2568 15390 -15729 -16035 -11122 13354 -7209 3536 13910 -12920 11092 -7302 3023 10764 14215 -9412 25338 -16462 -755 -13605 -8825 -11835 8054 -1148 5651 -5226 -4244 937 550 -5831 -825 -2426 -9717 1021 -418 378 -1532 4029 2517 3662 -1047 1246 -3794 1227 -1163 383 -929 3408 -409 3047 -390 -26 -456 -2282 948 2059 1343 -831 169 -1364 38 -897 835 -299 1651 -1146 -98 -393 72 4392 -4433 900000 -2934 900000 900000 4534 -1753 900000 900000 1712 900000 -1628 5417 -649 981 106 7963 1610 900000 -496 3300 -1574 2343 1493 -3054 848 1263 -2108 -5462 900000 1150 -1642 -451 -3318 1246 3363 -183 900000 -19 900000 2136 900000 1560 338 1335 721 2146 1611 -397 2878 3365 900000 1661 2 241 2884 2792 1632 -715 2270 3439 2050 2928 3834 -155 2397 5095 2367 6419 1234 4185 -995 -205 399 1864 -2444 -2602 -1957 2228 -1763 905 3624 -4330 3090 -2570 1000 3382 4258 -3450 6775 -5897 -252 -5073 -3660 -6074 4016 -729 3788 -4072 -3147 593 313 -3420 -487 -1550 -7063 727 -340 359 -1720 4785 3206 4703 -1390 1595 -5150 1660 -1691 569 -1362 4533 -535 3791 -492 -32 -555 -2992 1407 3601 2710 -1751 382 -3415 100 -2566 2388 -870 4687 -3227 -252 -933 174 SS 20240528T103246.8Z 8914.439430 305 1 29.70 2 82.49 67.21 68.62 193.48 0.00 1 0.00 1 0 17 5.089e-01 1.878e-02 2.744e-01 7.849e-03 9.488486e-01 4.657161e-03 1.085101e-02 -6.000000e+00 3.110403e-01 231.78 -2.00 3.57 -2.00 322.22 0.00e+00 1.177874e-02 2.874995e-03 2.875842e-03 -6.000000e+00 1.360165e-02 282.28 -2.00 20.00 -2.00 321.77 0.00e+00 7.093 0.007 302.00 328.00 3 1.3081e+00 1.9041e-02 8.8558e-02 -6.0000e+00 7.8023e-01 9.0920e-01 2.5963e-02 5.6051e-02 -6.0000e+00 8.4286e-01 -1.3456e+00 2.3214e-02 2.9757e-02 -6.0000e+00 5.0057e-01 5.5417e-01 1.0456e-02 1.3423e-02 -6.0000e+00 2.0782e-01 5.2708e-05 -1.9212e-03 2.1415e-04 2.4774e-04 -6.0000e+00 1.4981e-02 -3.1973e-03 0.0000e+00 12 8 8 10 0 0 99.98 19.74 0.34 -0.00320 -0.01763 40 40 1 5 0 742.403 23.32 14.83 19.74 21.03 2.7 1000.61 -140267 -124848 -128123 -134403 -146344 -88959 -142525 -10044 -127445 -200925 -149155 -134574 -76059 -32202 -46531 4928 -30829 -81534 41295 14282 -12647 -26986 -27385 -43343 197414 -63355 141751 -21823 -12183 -65964 65688 -22543 28854 4711 105008 -9617 1030 18668 26455 11718 30728 32502 40579 53603 20450 31327 27158 37909 26585 43701 24294 37441 22366 43192 14975 49019 21668 14055 15419 26410 19744 20685 22496 25832 22465 26381 29552 23393 16307 26141 15889 14924 7358 3377 1572 -2863 -353 -5005 232 -2054 3664 1243 5243 333 3413 1274 3895 1627 1702 -202 -623 -5227 -2261 -7090 -3324 -2636 -3128 -3211 -1038 -1997 -2544 -2782 -3916 -2562 -2684 -2251 -2116 -1850 -332 547 72 1068 461 -168 -385 -1382 -1071 -793 -29 893 804 1446 2602 1633 1037 1271 811 -720 88 679 797 410 -121 -363 -8 626 -88 479 222 -9 -95 -302 -2146 -2863 -2693 -2942 -3087 -3259 -991 -2579 -77 -2040 -6712 -3010 -2622 -1059 -381 -810 62 -622 -2950 460 209 -238 -545 -534 -995 1511 -1764 1085 -418 -214 -1974 704 -659 641 144 1125 -309 31 529 810 432 1129 1244 1491 1764 939 1319 1227 1625 1363 2041 1386 2110 1603 2705 1303 3415 1825 1252 1298 1930 1566 1771 2160 2750 2736 3158 3455 3061 2519 4202 3085 3033 1582 705 303 -518 -59 -913 46 -505 1015 410 1868 134 1406 567 1770 780 810 -96 -280 -2357 -977 -3404 -1776 -1532 -2159 -2571 -916 -1850 -2272 -2239 -2863 -1800 -1999 -1775 -1760 -1668 -330 626 95 1532 693 -256 -574 -2038 -1586 -1226 -46 1481 1307 2223 3748 2332 1451 1744 1086 -1028 145 1199 1591 901 -285 -933 -20 1684 -244 1322 612 -23 -254 -748 -5134 SS 20240528T111929.3Z 8914.471867 329 1 28.27 2 74.52 74.74 71.14 204.27 0.00 1 0.00 1 0 17 3.236e-01 1.255e-02 2.360e-01 8.573e-03 5.578837e-01 4.755362e-03 7.016505e-03 -6.000000e+00 1.979583e-01 231.79 -2.00 3.57 -2.00 320.58 0.00e+00 5.829975e-03 1.875219e-03 3.718921e-03 -6.000000e+00 8.646914e-03 282.28 -2.00 20.00 -2.00 319.97 0.00e+00 3.679 0.001 302.00 328.00 3 5.2243e+00 1.4767e-02 4.9062e-02 -6.0000e+00 4.9660e-01 6.4742e-02 1.8536e-02 3.4585e-02 -6.0000e+00 5.3626e-01 -5.7205e-02 1.6626e-02 1.9787e-02 -6.0000e+00 3.1850e-01 1.9863e-02 8.2116e-03 7.2297e-03 -6.0000e+00 1.3240e-01 3.8655e-05 -1.3047e-04 2.6129e-04 1.1958e-04 -6.0000e+00 9.5247e-03 -1.0339e-02 0.0000e+00 12 9 8 11 8 0 99.98 19.81 0.16 -0.01034 -0.01132 8 8 1 5 0 3533.135 23.32 14.83 19.81 21.53 2.7 1003.14 -135295 -64240 -87514 -96894 -136018 -129755 -105132 -41375 128084 -1024 -53301 -77487 107068 -47145 10744 -10745 -40874 -2836 -766 -27783 8295 -22980 49131 -17271 -30605 478 5795 -33120 8747 -28794 41501 25896 47521 -12323 -5053 -18428 11679 11126 -2183 16190 18765 -1224 4488 -474 -12229 6937 -1568 8782 2875 2032 6849 3818 3644 14266 5642 -2618 -3152 809 -723 3973 1020 1679 4294 4783 1073 3038 2479 278 5330 974 -894 334 -349 -273 -1840 -2605 -7 -4387 -3653 37 -2853 -1604 738 -4045 -1139 48 666 1305 1305 -105 2 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