File name: Pandora103s1_Downsview_20241001_L2Fit_fwvt1c6d20230525p1-8.txt
File generation date: 20241002T051333.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c6p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 103
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora103_OF_v3d20221207.txt
Instrument calibration file used: Pandora103s1_CF_v6d20230525.txt
Level 1 file used: Pandora103s1_Downsview_20241001_L1_smca1c6d20230525p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20241001
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1621 1770
Nominal wavelengths inside fitting window [nm]: 492.1005 492.2217 492.3429 492.4641 492.5853 492.7064 492.8276 492.9487 493.0698 493.1909 493.3119 493.4330 493.5540 493.6750 493.7960 493.9170 494.0380 494.1590 494.2799 494.4008 494.5217 494.6426 494.7635 494.8843 495.0052 495.1260 495.2468 495.3676 495.4883 495.6091 495.7298 495.8505 495.9712 496.0919 496.2126 496.3332 496.4538 496.5745 496.6951 496.8156 496.9362 497.0568 497.1773 497.2978 497.4183 497.5388 497.6592 497.7797 497.9001 498.0205 498.1409 498.2613 498.3816 498.5020 498.6223 498.7426 498.8629 498.9832 499.1034 499.2237 499.3439 499.4641 499.5843 499.7045 499.8246 499.9448 500.0649 500.1850 500.3051 500.4251 500.5452 500.6652 500.7852 500.9052 501.0252 501.1452 501.2651 501.3851 501.5050 501.6249 501.7447 501.8646 501.9845 502.1043 502.2241 502.3439 502.4637 502.5834 502.7032 502.8229 502.9426 503.0623 503.1819 503.3016 503.4212 503.5408 503.6604 503.7800 503.8996 504.0191 504.1387 504.2582 504.3777 504.4972 504.6166 504.7361 504.8555 504.9749 505.0943 505.2137 505.3330 505.4524 505.5717 505.6910 505.8103 505.9296 506.0488 506.1680 506.2873 506.4065 506.5256 506.6448 506.7639 506.8831 507.0022 507.1213 507.2404 507.3594 507.4785 507.5975 507.7165 507.8355 507.9544 508.0734 508.1923 508.3112 508.4301 508.5490 508.6679 508.7867 508.9056 509.0244 509.1432 509.2619 509.3807 509.4994 509.6181 509.7369 509.8555 509.9742
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20241001T135225.5Z 9040.578073 226 1 30.76 2 64.36 123.67 53.45 130.67 0.00 1 0.00 1 0 15 4.248e-03 4.212e-03 1.429e-03 1.424e-03 2.965478e+03 8.180987e+01 2.133700e+02 -6.000000e+00 2.232350e+02 282.74 -2.00 20.00 -2.00 505.24 0.00e+00 8.534247e-04 3.850048e-05 4.980569e-05 -6.000000e+00 1.168955e-04 282.74 -2.00 20.00 -2.00 500.40 0.00e+00 2.073205e-01 2.741550e-02 2.227002e-02 -6.000000e+00 8.166509e-02 227.00 -2.00 3.57 -2.00 502.00 0.00e+00 2.297 0.000 489.00 513.00 1 8.5504e+00 2.1017e-03 3.9076e-03 -6.0000e+00 6.2473e-03 1.0400e-02 5.4905e-04 5.4456e-04 -6.0000e+00 1.6422e-03 2.6676e-04 -2.0211e-04 1.0787e-04 2.8061e-05 -6.0000e+00 3.3230e-04 -1.3213e-02 1.0088e-04 11 8 0 10 0 0 62.13 19.75 0.72 -0.01321 -0.01461 8 8 1 4 0 3844.354 23.43 14.96 19.75 26.94 3.2 1014.30 -1209 -746 -115 152 143 439 763 554 644 397 -23 -61 -204 -55 -449 -392 -50 -218 224 247 522 347 382 169 419 237 126 3 1 -650 -705 -669 137 -32 271 294 -78 -12 -152 4 -402 164 -162 560 437 430 388 177 -114 -259 -731 -557 -908 -752 -477 -256 452 244 457 333 619 619 533 625 99 64 62 -246 -273 -451 -450 -730 -427 -55 53 -422 -412 -418 -388 -475 -526 -657 -184 245 -189 -408 52 245 -313 204 -24 512 204 507 416 223 101 -392 -574 -1136 -776 -557 122 -128 -78 -599 -488 -262 -135 -173 200 341 739 551 597 442 848 581 180 152 288 -256 253 365 269 326 307 130 210 525 49 -132 -478 -504 -349 32 -1 116 179 299 323 284 517 67 21 -227 -240 -625 -617 -490 -1208 -714 -114 156 149 467 824 602 697 421 -24 -63 -208 -55 -450 -395 -52 -232 244 268 566 377 414 174 433 244 129 3 1 -651 -701 -671 142 -33 282 303 -80 -12 -160 4 -425 174 -164 572 450 443 395 178 -120 -264 -725 -538 -871 -736 -486 -268 452 243 454 330 614 620 534 625 99 67 63 -248 -273 -443 -440 -721 -427 -57 54 -425 -403 -404 -374 -457 -511 -645 -180 242 -190 -414 53 247 -316 206 -23 501 203 500 401 224 99 -377 -542 -1053 -722 -530 122 -126 -77 -588 -470 -247 -127 -165 194 336 733 551 597 446 859 590 181 149 278 -244 241 352 260 315 297 124 201 505 46 -122 -438 -487 -319 30 -1 112 176 296 320 283 518 67 21 -226 -232 -588 -572 -458
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SQ 20241001T140142.2Z 9040.584516 232 1 30.42 2 62.98 125.75 52.26 133.10 0.00 1 0.00 1 0 15 3.882e-03 3.852e-03 7.891e-04 7.874e-04 2.610658e+03 4.482484e+01 1.905641e+02 -6.000000e+00 2.039605e+02 282.73 -2.00 20.00 -2.00 505.25 0.00e+00 7.955617e-04 2.131117e-05 4.729626e-05 -6.000000e+00 1.068255e-04 282.73 -2.00 20.00 -2.00 500.44 0.00e+00 1.364478e-01 1.512022e-02 1.941736e-02 -6.000000e+00 7.467784e-02 227.00 -2.00 3.57 -2.00 502.03 0.00e+00 2.189 0.000 489.00 513.00 1 7.4617e+00 1.1581e-03 3.6537e-03 -6.0000e+00 5.7121e-03 1.4411e-02 3.0280e-04 4.8023e-04 -6.0000e+00 1.5026e-03 8.0975e-04 6.1946e-04 5.9661e-05 2.5340e-05 -6.0000e+00 3.0368e-04 -1.1266e-02 4.9449e-05 11 8 0 10 0 0 99.52 19.75 0.56 -0.01127 -0.00697 25 25 1 4 0 1216.551 23.43 15.00 19.75 27.33 3.1 1015.92 -924 -606 -215 162 385 659 679 546 661 268 182 56 -309 -176 -536 -267 -248 -29 345 314 336 44 173 145 521 165 225 61 99 -684 -402 -568 -286 147 242 186 85 132 -340 -15 -15 167 50 279 419 272 207 42 -177 -393 -774 -741 -976 -655 -329 -51 161 159 417 469 363 598 390 533 216 139 -56 -200 -195 -510 -480 -418 -240 4 95 -218 -471 -650 -433 -604 -314 -365 -396 -160 -105 -227 -83 -114 -114 57 -29 277 272 452 347 272 -105 -237 -479 -964 -621 -574 -282 -17 -201 -163 -251 -402 -302 -68 90 318 347 472 730 738 708 679 431 207 61 -121 296 248 275 146 471 38 168 175 56 -255 -295 -519 -155 -34 198 87 378 392 156 289 329 295 231 28 -393 -602 -698 -571 -912 -613 -214 166 400 699 734 593 716 284 191 58 -315 -177 -538 -269 -255 -30 356 324 346 46 179 151 543 171 233 62 103 -685 -399 -569 -295 151 253 193 87 134 -359 -15 -15 168 51 288 435 283 212 42 -185 -400 -765 -715 -934 -639 -334 -54 163 160 417 466 363 602 394 537 216 143 -56 -201 -194 -500 -467 -410 -238 4 97 -218 -460 -627 -416 -580 -303 -357 -388 -159 -105 -229 -84 -115 -114 58 -28 273 272 449 338 274 -104 -227 -451 -890 -576 -546 -281 -16 -200 -160 -243 -382 -286 -65 88 315 347 475 733 746 723 692 433 204 59 -116 284 241 267 141 456 36 162 170 53 -238 -285 -498 -149 -32 190 84 372 389 155 288 330 298 233 28 -381 -567 -649 -535
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