File name: Pandora104s1_Downsview_20180907_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T223036.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20180907_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180907T105411.0Z 6824.454294 358 1 32.01 2 89.76 81.92 60.95 93.98 0.00 1 0.00 1 0 36 7.943e-02 7.814e-02 7.255e-02 7.114e-02 7.577711e+03 4.942375e+03 5.321671e+02 -6.000000e+00 4.366614e+03 285.55 -2.00 20.00 -2.00 505.26 0.00e+00 4.244748e-04 1.955889e-03 1.088494e-04 -6.000000e+00 2.224725e-03 285.55 -2.00 20.00 -2.00 500.09 0.00e+00 4.235704e-01 1.434804e+00 8.303616e-02 -6.000000e+00 1.561440e+00 229.80 -2.00 3.57 -2.00 501.73 0.00e+00 20.042 0.157 489.00 513.00 1 1.0090e+01 1.0969e-01 3.6373e-02 -6.0000e+00 1.1960e-01 1.5721e-01 2.8296e-02 2.5897e-03 -6.0000e+00 3.1332e-02 4.6807e-06 -1.0454e-02 5.9166e-03 6.2166e-05 -6.0000e+00 7.0210e-03 -2.2780e-02 1.0174e-04 12 8 8 10 0 0 95.36 21.58 9.92 -0.02278 -0.09529 8 2 1 4 0 4000.000 21.58 15.00 18.78 -7967 -9019 1710 -4329 -4777 -7162 -2600 2498 -715 -9802 -2498 -9479 2232 9716 8005 8440 -8092 6182 14729 3784 2693 -1952 2152 -8339 -9852 13706 4138 5477 -4800 5017 -8212 1802 6356 5051 10232 5223 1516 3993 684 10591 2875 10084 -8853 3935 -16798 4680 -2673 1033 -410 -5643 4703 -1185 -7341 6339 187 -2424 12235 14800 15835 7914 13907 -7344 -5 -11740 -2798 -12825 -8783 7168 11630 8091 -4921 5661 4116 3584 5368 -5325 6279 16155 -1283 16707 -1256 -3104 -174 -7946 4954 -2141 -11898 5806 6984 7856 9599 1829 1924 2633 -272 -8914 11037 -4261 14300 5589 -786 3851 13974 -17304 -948 -15818 6378 -5014 -7264 750 5951 3792 1050 8533 2434 16895 8901 2766 2865 2279 -18 -1742 -9131 9847 -5631 -13700 -13582 7829 -2742 -2980 3115 1121 22617 13200 3823 -10316 4833 2304 -1513 4892 1613 -6733 -5465 2349 3432 -6985 -345 -7675 -12708 3078 6712 -8288 -9408 1637 -4526 -5210 -8162 -2888 2696 -802 -12016 -2815 -11217 2336 9310 7696 8011 -9019 6079 13657 4020 2922 -2209 2347 -10053 -12065 13464 4450 5774 -5545 5169 -9230 1794 6074 4949 9912 5499 1664 4233 741 10296 2977 9718 -10298 4076 -21481 4919 -3022 1121 -445 -6334 4678 -1209 -7722 5748 180 -2450 11107 13423 14384 7744 12792 -8260 -5 -13926 -3040 -15277 -9904 6809 10405 7420 -5057 5171 3810 3361 5009 -5597 5891 13514 -1241 13433 -1193 -2995 -165 -8152 4508 -2112 -13058 5379 6394 7094 8503 1750 1853 2560 -274 -9606 9546 -4160 11346 4704 -689 3175 10555 -18111 -887 -17832 5886 -5142 -7527 709 5334 3514 1013 7730 2353 14234 8102 2686 2810 2253 -18 -1736 -9591 8454 -5596 -14872 -14738 6899 -2677 -2898 2847 1047 16948 10586 3318 -10184 4136 2065 -1438 4423 1525 -6974 -5613 2244 3260 -7341 -339 -8017 -13638 2765 5726 SO 20180907T105819.0Z 6824.457164 362 1 32.01 2 89.03 82.63 60.23 94.71 0.00 1 0.00 1 0 22 4.182e-02 4.054e-02 4.026e-02 3.981e-02 9.237570e+03 2.789116e+03 5.197077e+02 -6.000000e+00 2.298302e+03 285.55 -2.00 20.00 -2.00 505.27 0.00e+00 1.596420e-03 1.091587e-03 1.106527e-04 -6.000000e+00 1.170870e-03 285.55 -2.00 20.00 -2.00 500.15 0.00e+00 1.882983e+00 7.990952e-01 7.523429e-02 -6.000000e+00 8.204938e-01 229.80 -2.00 3.57 -2.00 501.78 0.00e+00 18.634 0.126 489.00 513.00 1 9.5609e+00 6.1243e-02 3.2223e-02 -6.0000e+00 6.2860e-02 1.0309e-01 1.5690e-02 2.3432e-03 -6.0000e+00 1.6437e-02 8.5551e-06 -1.6051e-03 3.2986e-03 5.2328e-05 -6.0000e+00 3.6928e-03 4.9193e-03 3.7927e-05 12 8 8 10 0 0 39.33 21.58 4.41 0.00492 -0.00621 8 2 1 4 0 4000.000 21.58 15.00 18.79 750 101 953 -4533 146 3329 1477 1926 -1662 2368 -842 1643 -2424 3977 -3589 -3882 1279 -2162 4030 -2338 2861 2012 4589 581 -4134 -2836 -973 -1052 4762 3955 -2739 -1238 -2225 -2579 670 -5689 21 -4054 -540 6269 3781 -5760 2514 7692 3064 -824 -1334 5425 3574 3417 -2099 -1713 -8212 -819 147 7479 -6437 -151 3147 4973 7265 -1512 1456 -3684 6519 -4981 1596 -5272 487 -6457 -1572 -3339 1759 2597 -951 -5524 -951 5801 -1140 -1903 -403 -1168 -499 4222 3275 3652 -3604 5537 3686 12649 4821 347 -1775 -1052 -5853 -4670 -978 317 -1729 -5346 3484 552 9153 -3259 -2006 -1172 -4429 211 1165 1149 3935 -3310 -3894 434 -1985 -52 -148 -2055 2985 -2417 -4572 -3289 8453 7849 8612 3997 -573 7050 -2972 4666 -9396 10562 1556 -4140 1861 4891 -5569 9729 500 -4065 -3590 -6917 -1491 -2733 1871 5560 7725 -3642 4135 -2466 -2476 697 95 919 -4786 152 3409 1576 2071 -1857 2522 -907 1710 -2587 3930 -3783 -4089 1294 -2305 4176 -2627 3054 2167 4826 635 -4767 -3238 -1085 -1168 4928 3984 -2842 -1263 -2310 -2768 726 -6670 23 -4589 -585 6278 3863 -6478 2634 7741 3264 -918 -1490 5613 3706 3483 -2192 -1728 -8644 -795 144 7067 -7151 -160 3244 5020 7138 -1622 1527 -4063 6491 -5472 1617 -5603 484 -6787 -1550 -3324 1676 2477 -954 -5823 -944 5267 -1088 -1818 -377 -1105 -473 3833 3026 3407 -3622 5084 3430 10725 4409 332 -1763 -1050 -6069 -4658 -914 284 -1539 -4833 2830 460 7179 -2997 -1918 -1140 -4448 201 1084 1062 3578 -3276 -3921 422 -1985 -51 -146 -2092 2920 -2476 -4701 -3279 7380 6827 7506 3670 -549 6291 -2912 4227 -9795 9016 1418 -3930 1658 4225 -5417 8374 477 -4105 -3661 -7339 -1506 -2808 1843 5280 7142 -3693 3797 -2366 -2370 SO 20180907T110222.0Z 6824.459977 366 1 32.01 2 88.30 83.33 59.53 95.42 0.00 1 0.00 1 0 29 2.502e-02 2.479e-02 2.393e-02 2.372e-02 6.815372e+03 1.602388e+03 5.260555e+02 -6.000000e+00 1.375043e+03 285.55 -2.00 20.00 -2.00 505.26 0.00e+00 2.694706e-03 6.501213e-04 1.295848e-04 -6.000000e+00 7.004531e-04 285.55 -2.00 20.00 -2.00 500.11 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