File name: Pandora104s1_Downsview_20181111_L2Fit_fout2c21d20180627p1-8.txt File generation date: 20241126T225244.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20181111_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181111 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1061 305.2467 305.3872 305.5277 305.6683 305.8088 305.9493 306.0898 306.2302 306.3707 306.5112 306.6516 306.7920 306.9325 307.0729 307.2133 307.3537 307.4940 307.6344 307.7748 307.9151 308.0554 308.1958 308.3361 308.4764 308.6167 308.7569 308.8972 309.0375 309.1777 309.3179 309.4582 309.5984 309.7386 309.8788 310.0189 310.1591 310.2993 310.4394 310.5795 310.7196 310.8598 310.9999 311.1399 311.2800 311.4201 311.5601 311.7002 311.8402 311.9802 312.1202 312.2602 312.4002 312.5402 312.6801 312.8201 312.9600 313.1000 313.2399 313.3798 313.5197 313.6595 313.7994 313.9393 314.0791 314.2190 314.3588 314.4986 314.6384 314.7782 314.9180 315.0577 315.1975 315.3372 315.4770 315.6167 315.7564 315.8961 316.0358 316.1755 316.3151 316.4548 316.5944 316.7341 316.8737 317.0133 317.1529 317.2925 317.4321 317.5716 317.7112 317.8507 317.9902 318.1298 318.2693 318.4088 318.5482 318.6877 318.8272 318.9666 319.1061 319.2455 319.3849 319.5243 319.6637 319.8031 319.9424 320.0818 320.2211 320.3605 320.4998 320.6391 320.7784 320.9177 321.0569 321.1962 321.3355 321.4747 321.6139 321.7531 321.8924 322.0315 322.1707 322.3099 322.4491 322.5882 322.7273 322.8665 323.0056 323.1447 323.2838 323.4228 323.5619 323.7010 323.8400 323.9790 324.1181 324.2571 324.3961 324.5350 324.6740 324.8130 324.9519 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20181111T121539.0Z 6889.510868 497 1 32.01 2 89.44 115.19 126.37 86.04 0.00 1 0.00 1 0 81 1.039e+00 8.727e-01 9.109e-01 7.798e-01 -1.944889e+00 6.124412e-01 4.392300e-02 -6.000000e+00 7.967409e-01 222.93 -2.00 3.57 -2.00 312.52 0.00e+00 -1.760645e-02 3.479876e-02 5.785388e-03 -6.000000e+00 4.135281e-02 277.66 -2.00 20.00 -2.00 312.38 0.00e+00 19.733 0.150 302.00 328.00 3 8.2569e-02 1.5375e+00 2.5726e-01 -6.0000e+00 1.9361e+00 -4.3425e+00 1.6964e+00 1.0961e-01 -6.0000e+00 2.1799e+00 3.6050e+00 9.9026e-01 5.9498e-02 -6.0000e+00 1.2769e+00 -7.3058e-01 3.6910e-01 1.5677e-02 -6.0000e+00 5.0747e-01 2.0259e-07 8.6652e-02 1.0585e-02 2.4435e-04 -6.0000e+00 3.7873e-02 1.4398e-02 0.0000e+00 12 12 8 10 0 0 88.92 21.88 19.29 0.01440 0.66554 8 2 1 5 0 4000.000 21.88 15.00 18.75 -114904 900000 900000 900000 52164 900000 20322 900000 26800 146962 900000 900000 900000 -187911 900000 377685 -49443 29385 -26433 -78764 900000 -20554 900000 -86296 900000 900000 900000 84223 43598 900000 900000 900000 158693 900000 900000 25003 5337 52505 -20761 900000 -9885 900000 -4232 900000 900000 67614 34325 900000 900000 900000 900000 900000 900000 -6864 900000 37243 48961 46642 900000 -78676 -40666 900000 900000 900000 -43183 900000 52235 900000 900000 900000 900000 900000 -40504 900000 -14999 -3767 166613 -22405 -24384 9526 3057 75502 -6146 900000 53450 900000 900000 900000 900000 900000 133215 185843 900000 -67139 95497 38506 20007 -5986 900000 331141 194571 65298 21796 900000 900000 900000 900000 900000 73926 900000 900000 900000 900000 -47645 -93183 -46653 900000 900000 37328 900000 -17946 87762 -49196 900000 64347 32203 900000 232012 232286 -49207 900000 900000 -61461 31392 -46630 -4386 143265 -13827 36758 -47490 157769 85239 -2781 -85485 900000 900000 900000 38809 900000 15119 900000 19939 109336 900000 900000 900000 -175813 900000 280988 -36784 21862 -19666 -74800 900000 -15292 900000 -97130 900000 900000 900000 62660 32436 900000 900000 900000 118063 900000 900000 18602 3971 39062 -19423 900000 -9656 900000 -3210 900000 900000 50303 25537 900000 900000 900000 900000 900000 900000 -6300 900000 32253 41365 39604 900000 -164954 -48121 900000 900000 900000 -38134 900000 38862 900000 900000 900000 900000 900000 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-6.0000e+00 1.4247e+00 6.9909e-01 3.4215e-01 1.8024e-02 -6.0000e+00 5.8279e-01 1.3167e-07 9.6703e-03 2.1017e-02 1.9049e-04 -6.0000e+00 4.6257e-02 6.7488e-02 0.0000e+00 12 8 8 10 0 0 77.76 21.88 26.80 0.06749 0.14015 8 2 1 5 0 4000.000 21.88 15.00 18.76 900000 22177 900000 900000 84526 900000 900000 -22441 900000 302935 900000 900000 900000 900000 900000 900000 900000 900000 -54533 900000 900000 59832 -49505 900000 12251 900000 -69055 900000 -56032 900000 -27658 900000 900000 900000 -25151 900000 900000 23334 900000 -62654 900000 -106140 900000 900000 -5645 900000 900000 900000 900000 -22250 900000 900000 101812 900000 900000 -24825 157230 900000 138172 900000 82120 900000 -38879 900000 -101938 900000 -62593 900000 900000 900000 900000 900000 900000 208853 54228 900000 900000 85876 900000 222028 113947 51000 -38277 -82012 900000 239216 900000 900000 900000 900000 900000 53764 211954 42100 -1471 -20251 -32115 -19223 168913 900000 -5805 900000 900000 900000 40392 900000 -68950 900000 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