File name: Pandora104s1_Downsview_20181125_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241126T232251.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20181125_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181125T124014.0Z 6903.527940 378 1 32.00 2 88.45 121.19 70.16 280.01 0.00 1 0.00 1 0 22 2.225e-02 2.203e-02 1.974e-02 1.956e-02 4.531210e+03 1.229885e+03 2.956962e+02 -6.000000e+00 1.176851e+03 276.01 -2.00 20.00 -2.00 505.25 0.00e+00 2.266417e-03 5.243330e-04 8.915559e-05 -6.000000e+00 6.087181e-04 276.01 -2.00 20.00 -2.00 500.07 0.00e+00 1.591211e+00 3.906383e-01 3.905959e-02 -6.000000e+00 4.346248e-01 222.43 -2.00 3.57 -2.00 501.71 0.00e+00 17.358 0.102 489.00 513.00 1 9.0703e+00 2.9865e-02 2.8414e-02 -6.0000e+00 3.3213e-02 1.2088e-01 7.7174e-03 1.7584e-03 -6.0000e+00 8.6887e-03 1.7167e-05 3.2937e-03 1.6694e-03 3.8642e-05 -6.0000e+00 1.9655e-03 6.9083e-03 5.4563e-05 12 8 8 10 0 0 -7.24 21.48 2.71 0.00691 0.02975 8 2 1 4 0 4000.000 21.48 15.00 18.43 -4434 -1164 -1847 1775 -267 3998 -3843 -745 -1338 1580 -2897 540 -1221 175 -495 2506 543 306 1527 -3201 -1162 1886 1655 -2868 278 -383 6616 -765 4787 -2315 2100 -2133 1234 -942 3655 -1733 539 -480 2577 -521 -3372 -1699 -2102 673 887 -1079 -1520 2091 832 881 -1704 1120 -8 678 -4282 4060 552 655 5125 -413 2762 -139 -693 -1616 1235 -90 767 -819 1589 231 3342 -948 -143 -3478 473 -1265 -2009 425 4920 -2308 -2402 2729 446 248 -2389 2928 -439 -259 -2004 4061 -3906 5344 50 2198 3664 2757 -1482 -2433 -1897 -533 -1897 4187 1299 1785 1004 -3379 1513 -190 2101 -1982 179 -1937 -1542 -679 4328 309 561 934 -1331 -178 29 826 -1988 246 -2713 -329 -2537 2457 516 2259 -3134 150 -555 3561 -1915 -3114 -125 -1628 -171 -2721 -1133 1317 3251 -1756 2773 -395 -1084 -701 -2468 -382 3594 -4422 -1144 -1886 1816 -285 4166 -4409 -835 -1510 1708 -3207 573 -1296 181 -510 2511 562 324 1646 -3649 -1295 2044 1797 -3258 309 -428 6872 -847 4925 -2448 2076 -2202 1247 -1010 3884 -1952 588 -522 2693 -555 -3690 -1840 -2309 727 968 -1204 -1694 2222 880 913 -1754 1091 -8 650 -4422 4003 577 691 5173 -438 2830 -147 -741 -1743 1288 -94 777 -828 1554 226 3122 -920 -138 -3520 468 -1270 -1990 402 4406 -2206 -2287 2493 419 234 -2334 2744 -425 -250 -1958 3738 -3887 4901 49 2135 3478 2580 -1413 -2281 -1726 -469 -1654 3459 1128 1605 946 -3348 1418 -178 1907 -1871 168 -1882 -1512 -667 4074 303 552 922 -1344 -175 28 778 -1897 230 -2634 -313 -2462 2275 484 2081 -3049 140 -509 3100 -1743 -2870 -114 -1545 -162 -2672 -1107 1261 3062 -1743 2640 -387 -1058 -667 -2324 -347 3148 SO 20181125T124426.1Z 6903.530857 382 1 32.15 2 87.80 121.93 70.88 280.66 0.00 1 0.00 1 0 15 1.473e-02 1.470e-02 1.474e-02 1.462e-02 3.776107e+03 9.054732e+02 3.427035e+02 -6.000000e+00 7.788082e+02 276.01 -2.00 20.00 -2.00 505.25 0.00e+00 1.832199e-03 3.915925e-04 9.095828e-05 -6.000000e+00 4.028342e-04 276.01 -2.00 20.00 -2.00 500.09 0.00e+00 1.868239e+00 2.918152e-01 1.760198e-02 -6.000000e+00 2.876427e-01 222.43 -2.00 3.57 -2.00 501.73 0.00e+00 15.604 0.074 489.00 513.00 1 8.9965e+00 2.2307e-02 2.4298e-02 -6.0000e+00 2.1981e-02 9.9629e-02 5.7689e-03 1.4107e-03 -6.0000e+00 5.7509e-03 2.3301e-05 1.9149e-03 1.2481e-03 4.4948e-05 -6.0000e+00 1.3007e-03 1.7057e-02 -1.1905e-05 12 8 8 10 0 0 -249.83 21.58 1.50 0.01706 0.03034 8 2 1 4 0 4000.000 21.58 14.99 18.47 -2780 -1421 1241 -3153 1228 -146 112 1644 2811 501 4978 -1081 276 -2318 -2453 -3501 1570 402 -416 -258 -538 -1652 704 -859 -893 1133 395 -2002 347 -405 -501 3031 1261 2168 -447 -468 -118 914 -1266 -923 1250 785 270 1332 704 1501 -1574 2514 -328 -1445 -611 -727 536 476 -1578 -803 -207 1201 -1633 -1183 22 -1373 2674 2414 -796 925 -85 2459 1105 -1261 525 -961 -1428 1413 -779 -494 -1692 -774 -1711 1389 300 -1030 -778 3564 -502 1088 318 -690 1925 -1094 1877 1612 337 -144 -618 4208 1797 303 -2449 -1740 169 -784 2103 -1579 340 -2036 -676 -460 1662 907 350 292 -219 1516 83 170 -37 -713 -2019 119 -419 -1048 -1900 -257 1548 430 304 1708 98 -1167 -580 -1571 -338 393 2215 -861 -1183 -993 338 -219 -915 -3664 1440 536 996 341 -295 2079 1604 -1064 -396 -2720 -1393 1223 -3360 1286 -158 123 1796 3040 547 5106 -1163 289 -2450 -2575 -3709 1604 424 -456 -286 -596 -1851 771 -957 -1003 1248 436 -2242 374 -422 -508 2979 1274 2250 -493 -521 -130 983 -1375 -987 1308 829 290 1427 767 1631 -1752 2660 -351 -1530 -623 -721 516 456 -1579 -826 -217 1256 -1752 -1259 23 -1466 2758 2496 -843 949 -87 2403 1082 -1248 503 -930 -1396 1358 -777 -491 -1669 -740 -1630 1279 278 -973 -737 3248 -480 1036 305 -668 1811 -1057 1768 1531 330 -143 -612 3900 1669 278 -2253 -1556 145 -682 1816 -1467 322 -1996 -649 -434 1519 833 328 278 -212 1459 81 167 -36 -715 -2052 118 -407 -1009 -1816 -241 1445 407 287 1596 92 -1113 -552 -1493 -311 354 1946 -779 -1094 -938 319 -211 -896 -3694 1386 523 970 334 -288 1943 1466 -978 -363 SO 20181125T124829.1Z 6903.533670 386 1 32.15 2 87.18 122.65 71.57 281.29 0.00 1 0.00 1 0 15 1.163e-02 1.146e-02 1.141e-02 1.133e-02 5.372766e+03 7.208701e+02 4.180790e+02 -6.000000e+00 6.153339e+02 276.01 -2.00 20.00 -2.00 505.26 0.00e+00 1.751054e-03 3.033458e-04 8.331744e-05 -6.000000e+00 3.182139e-04 276.01 -2.00 20.00 -2.00 500.14 0.00e+00 1.318029e+00 2.251683e-01 3.257140e-02 -6.000000e+00 2.275745e-01 222.43 -2.00 3.57 -2.00 501.77 0.00e+00 14.024 0.054 489.00 513.00 1 8.9847e+00 1.7201e-02 2.1286e-02 -6.0000e+00 1.7387e-02 8.9227e-02 4.4410e-03 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