File name: Pandora104s1_Downsview_20190515_L2Fit_fwvt1c21d20180627p1-8.txt File generation date: 20241127T005543.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c21p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v5d20171009.txt Instrument calibration file used: Pandora104s1_CF_v21d20180627.txt Level 1 file used: Pandora104s1_Downsview_20190515_L1_smca1c21d20180627p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190515 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based on session 12 to revisit NO2 and SO2 First and last pixel inside fitting window: 1633 1783 Nominal wavelengths inside fitting window [nm]: 492.0163 492.1368 492.2573 492.3778 492.4983 492.6187 492.7391 492.8596 492.9800 493.1003 493.2207 493.3411 493.4614 493.5817 493.7020 493.8223 493.9425 494.0628 494.1830 494.3032 494.4234 494.5436 494.6637 494.7839 494.9040 495.0241 495.1442 495.2643 495.3843 495.5044 495.6244 495.7444 495.8644 495.9844 496.1043 496.2242 496.3442 496.4641 496.5840 496.7038 496.8237 496.9435 497.0633 497.1831 497.3029 497.4227 497.5424 497.6621 497.7818 497.9015 498.0212 498.1409 498.2605 498.3801 498.4997 498.6193 498.7389 498.8585 498.9780 499.0975 499.2170 499.3365 499.4560 499.5754 499.6949 499.8143 499.9337 500.0531 500.1724 500.2918 500.4111 500.5304 500.6497 500.7690 500.8882 501.0075 501.1267 501.2459 501.3651 501.4843 501.6034 501.7226 501.8417 501.9608 502.0799 502.1989 502.3180 502.4370 502.5560 502.6750 502.7940 502.9130 503.0319 503.1509 503.2698 503.3887 503.5075 503.6264 503.7452 503.8641 503.9829 504.1017 504.2204 504.3392 504.4579 504.5766 504.6953 504.8140 504.9327 505.0513 505.1700 505.2886 505.4072 505.5258 505.6443 505.7629 505.8814 505.9999 506.1184 506.2368 506.3553 506.4737 506.5922 506.7106 506.8289 506.9473 507.0657 507.1840 507.3023 507.4206 507.5389 507.6571 507.7754 507.8936 508.0118 508.1300 508.2482 508.3663 508.4845 508.6026 508.7207 508.8388 508.9569 509.0749 509.1929 509.3109 509.4289 509.5469 509.6649 509.7828 509.9007 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190515T095913.0Z 7074.416123 236 1 32.00 2 89.79 63.65 106.55 287.06 0.00 1 0.00 1 0 15 1.267e-01 1.165e-01 1.091e-01 1.047e-01 -1.713739e+04 5.726844e+03 1.050165e+03 -6.000000e+00 6.839505e+03 280.81 -2.00 20.00 -2.00 505.15 0.00e+00 7.231177e-03 2.872818e-03 3.196132e-04 -6.000000e+00 3.508860e-03 280.81 -2.00 20.00 -2.00 499.89 0.00e+00 7.481427e+00 2.168890e+00 1.912881e-01 -6.000000e+00 2.508937e+00 230.87 -2.00 3.57 -2.00 501.55 0.00e+00 20.197 0.161 489.00 513.00 1 9.8872e+00 1.6731e-01 4.0006e-02 -6.0000e+00 1.9161e-01 8.7059e-02 4.3126e-02 4.3794e-03 -6.0000e+00 5.0630e-02 3.1332e-06 3.8636e-03 8.0841e-03 1.3537e-04 -6.0000e+00 1.1225e-02 -1.3572e-03 -1.3499e-04 12 9 8 11 8 0 89.39 21.69 13.21 -0.00136 0.02544 8 2 1 4 0 4000.000 21.69 15.00 18.73 900000 20906 -17501 14945 -7007 -2606 12889 -8411 760 24379 -15269 -4219 2923 3969 22752 10719 -10916 924 6481 -4169 5113 -9984 5806 608 -2149 25193 155 1226 3374 521 1932 -2951 10848 2293 -12924 12798 -14902 -1787 -2490 -10855 -4089 2018 -4291 8310 -12114 10276 15943 26832 -4292 9608 17894 745 4471 -2624 -1340 -1430 17774 -6434 10269 -13960 -6682 8881 12484 -5845 15796 5969 1565 -8611 36361 12374 -9796 7848 -6128 -19108 5358 1533 -21761 -30653 -7115 15988 1260 5208 2668 98 -506 9925 25034 -9515 18667 18406 2057 -9888 21700 -4013 1597 12440 7026 -297 58 -11194 -11889 12996 -13534 -9274 17268 -1328 17013 -4041 16860 649 -11787 4816 9446 16608 749 -6591 -3867 24506 -8984 -6164 -5416 5185 2472 -12277 1017 17589 2700 28579 -4684 9785 32481 -14236 35744 -6316 22810 -11889 5027 -5939 16454 -7917 8636 -9141 970 -14989 -9037 -8704 1862 11685 11917 20484 -8012 900000 17087 -21297 13848 -8245 -2988 13018 -10522 871 22004 -19711 -4838 3080 4076 19343 10183 -12874 989 6767 -4896 5473 -12350 6180 681 -2499 22646 177 1375 3648 558 1970 -3145 10204 2415 -16387 12848 -19332 -2019 -2803 -13099 -4618 2165 -4953 8598 -15469 10660 15625 23430 -4965 9543 15950 759 4309 -2684 -1377 -1521 16125 -7469 10151 -17335 -7693 8823 12028 -6700 14617 5975 1602 -9518 25776 10876 -10425 6978 -6237 -22152 4972 1478 -25759 -38590 -7040 12632 1141 4569 2409 90 -468 8325 18150 -9581 14342 14244 1874 -10150 16840 -4087 1580 11274 6814 -312 59 -12231 -12640 10715 -14362 -9491 13812 -1240 12856 -3637 12228 548 -11414 4074 7896 13450 726 -6946 -3987 19046 -9426 -6148 -5276 4566 2239 -12928 958 14183 2510 20838 -4676 8543 22988 -15671 24074 -6215 16609 -11900 4313 -5804 13266 -8145 7609 -9512 911 -16506 -9498 -9176 1764 9819 9646 14870 -7611 SO 20190515T100314.0Z 7074.418912 240 1 32.01 2 89.13 64.35 107.23 287.78 0.00 1 0.00 1 0 15 2.482e-01 8.781e-02 1.106e-01 7.163e-02 1.041073e+04 5.121869e+03 8.549617e+02 -6.000000e+00 1.339795e+04 280.81 -2.00 20.00 -2.00 505.23 0.00e+00 1.199013e-03 1.944601e-03 2.927048e-05 -6.000000e+00 6.862300e-03 280.81 -2.00 20.00 -2.00 499.88 0.00e+00 1.388239e-01 1.463740e+00 3.776425e-02 -6.000000e+00 4.880899e+00 230.87 -2.00 3.57 -2.00 501.54 0.00e+00 18.984 0.133 489.00 513.00 1 1.0242e+01 1.1159e-01 3.2724e-02 -6.0000e+00 3.7340e-01 1.7229e-01 2.8997e-02 2.2068e-03 -6.0000e+00 9.7542e-02 4.6451e-06 1.8442e-03 5.9118e-03 6.5550e-05 -6.0000e+00 2.1952e-02 1.3741e-02 1.5347e-04 12 9 8 11 8 0 99.71 21.69 2.95 0.01374 0.02653 8 2 1 4 0 4000.000 21.69 14.99 18.75 2869 -415 5249 -7552 7950 -8244 -2462 -8932 -9543 3088 6716 -610 7074 -5806 300 14276 -3209 10272 -8772 3386 2807 -5385 -3657 8323 789 3774 -11846 5123 -7974 8264 13674 -2250 3697 1638 -1736 -3011 8099 -2293 10203 -5656 6061 -1720 -1779 -1117 6694 8172 3264 259 -7066 8046 6916 -863 -10197 -9257 1987 5320 -3911 -7690 4414 4095 69 19917 -6192 6602 -159 10932 903 7233 -6421 -9572 9610 9264 11091 3955 13472 -5350 12144 -35518 12602 -869 -1743 6399 3806 9959 -3761 9908 4355 10107 -12973 6291 -7514 -1037 3076 8699 3265 5919 13 12175 5155 -2585 -10698 21009 -14634 19445 -8274 -1863 -11601 5157 1903 8560 14833 -3308 -5113 3005 21390 -8516 4764 -6994 11673 1941 7293 -863 2559 -15979 -3007 17075 -186 -1980 -6030 4279 -6907 -4867 15334 10464 -684 -2040 -11157 1949 -6582 4717 -8575 16916 -64 1181 -11074 -4739 -3069 -3052 280241 10609 8186 2751 -417 5170 -8713 8068 -9953 -2869 -11143 -11972 3375 6959 -672 7104 -6514 315 13111 -3531 10161 -10741 3717 3089 -6421 -4283 8701 894 4139 -15002 5463 -9438 8024 12334 -2373 3729 1755 -1985 -3499 8350 -2587 10074 -6439 6159 -1893 -1978 -1246 7001 8450 3515 283 -8148 7847 6602 -864 -10990 -9884 1958 5248 -4318 -8882 4529 4196 73 17595 -7051 6647 -169 10314 921 6832 -6850 -10382 8544 8257 9784 3783 11944 -5658 10622 -48083 10608 -828 -1667 5704 3498 8667 -3783 8829 4096 8970 -14274 5730 -7826 -1022 2961 7959 3086 5283 12 9620 4262 -2255 -9923 14522 -14653 14744 -8563 -1837 -12510 4675 1757 7417 12270 -3296 -5224 2848 17011 -9016 4474 -7446 10423 1879 6572 -824 2318 -17264 -2894 13576 -174 -1887 -5930 3804 -6848 -4649 11805 8363 -605 -1836 -11217 1761 -6517 4247 -8869 13758 -61 1123 -11837 -4747 -2989 -2909 19670 8526 6758 SO 20190515T100709.0Z 7074.421632 244 1 32.01 2 88.49 65.02 107.88 288.49 0.00 1 0.00 1 0 15 5.990e-02 5.815e-02 4.832e-02 4.742e-02 1.088518e+04 3.415977e+03 7.607525e+02 -6.000000e+00 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