File name: Pandora104s1_Downsview_20200301_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T040435.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v6d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20200301_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200301 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200301T122212.9Z 7365.515427 462 1 49.78 2 85.78 104.30 114.53 32.60 0.00 1 0.00 1 0 41 6.939e-01 1.066e-01 5.419e-01 9.228e-02 1.151662e+00 5.716932e-02 1.404835e-02 -6.000000e+00 4.360838e-01 225.24 -2.00 3.57 -2.00 321.65 0.00e+00 1.095631e-03 1.515859e-02 1.333544e-02 -6.000000e+00 2.043625e-02 272.93 -2.00 20.00 -2.00 321.04 0.00e+00 11.104 0.027 302.00 328.00 3 -5.4106e-01 1.7192e-01 1.4219e-01 -6.0000e+00 1.0903e+00 3.2198e+00 2.0194e-01 1.0380e-01 -6.0000e+00 1.2047e+00 -2.4817e+00 1.2041e-01 3.9180e-02 -6.0000e+00 7.0579e-01 6.9906e-01 6.7536e-02 9.2163e-03 -6.0000e+00 2.8769e-01 2.6530e-06 1.7473e-03 2.3092e-03 1.5624e-04 -6.0000e+00 2.1382e-02 1.2098e-02 0.0000e+00 12 8 8 10 0 0 -57.23 24.35 2.95 0.01210 0.02523 13 3 1 5 0 3829.130 24.35 14.99 21.15 900000 42818 41998 900000 135147 900000 100410 900000 118391 900000 -70965 14353 42464 900000 900000 900000 900000 -6865 900000 -26093 900000 -50666 900000 150685 28829 6603 900000 -27500 900000 36120 900000 900000 900000 66067 900000 139558 -15748 900000 308633 96613 -30991 156183 -20409 900000 -66940 1596 -21897 79962 55817 116606 -1085 97676 332710 175447 900000 900000 -9133 -31020 46338 3003 900000 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9294 16577 -18299 -3608 -20484 3168 2556 8528 11060 8560 9529 13606 9099 -2101 -279 -17617 -3560 762 -3048 -19259 -1129 -16340 2192 4800 3290 -448 3043 6768 10182 -3279 11338 -17263 10539 11271 7967 11207 4810 13113 5320 -7362 -17944 15177 3194 -3812 -12512 809 -12716 -21456 -4901 10600 7365 10859 8392 -7405 -14877 3744 16978 SS 20200301T122551.6Z 7365.517958 465 1 49.17 2 85.15 104.94 114.18 33.44 0.00 1 0.00 1 0 33 6.285e-01 7.936e-02 4.832e-01 5.921e-02 1.150413e+00 3.473052e-02 1.285294e-02 -6.000000e+00 3.642064e-01 225.24 -2.00 3.57 -2.00 321.94 0.00e+00 -7.259301e-03 1.154066e-02 1.503976e-02 -6.000000e+00 1.738025e-02 272.93 -2.00 20.00 -2.00 321.39 0.00e+00 10.062 0.020 302.00 328.00 3 1.0182e-03 1.1106e-01 1.4695e-01 -6.0000e+00 9.0527e-01 2.9095e+00 1.2837e-01 1.2722e-01 -6.0000e+00 9.9029e-01 -2.5608e+00 7.4035e-02 3.6215e-02 -6.0000e+00 5.8505e-01 7.6262e-01 4.1359e-02 1.4870e-02 -6.0000e+00 2.4689e-01 5.5341e-06 2.6888e-03 1.4117e-03 1.4646e-04 -6.0000e+00 1.7610e-02 1.1219e-02 0.0000e+00 12 8 8 10 0 0 69.33 24.35 1.71 0.01122 0.03142 24 5 1 5 0 2048.530 24.35 15.00 21.15 43780 900000 10903 167997 -119 71663 -45566 -2633 86282 900000 15877 900000 900000 900000 19645 120998 140417 58393 55292 -2412 148239 99092 113380 21679 129854 53085 9269 -42555 -22797 -44114 152522 184539 900000 159398 -50681 -62436 -38536 85709 160150 18545 -4892 169141 -33654 103027 -84940 17047 -19617 254436 57647 900000 -3990 900000 69547 99213 169900 12504 11609 38436 10419 -8621 -8499 -20294 30598 -899 94058 -19704 127453 21509 91898 -17834 79313 38636 23228 -40640 17893 6641 25687 82449 27666 -11764 -16557 19709 -2555 12993 256 31871 -2800 32839 -27550 34364 17631 23634 -7245 9123 -5236 22509 13559 3687 337 4349 -10925 -7250 2321 -19457 10608 -17782 13200 -15475 8727 -6509 13870 8686 7927 -1107 -1238 411 7793 -1578 3515 8156 649 -4378 1707 691 -5133 -505 -12849 18417 -6681 4653 -7402 2503 -4038 5144 -4101 -1075 -800 896 1208 -3532 4154 832 5682 5890 900000 1624 9686 -13 4132 -7224 -278 4974 900000 1373 900000 900000 900000 2737 6976 8095 5611 5047 -359 8546 5713 6537 2386 7487 3895 923 -6245 -2629 -6936 8793 10639 900000 9190 -9563 -12762 -6665 4941 9233 2624 -897 9752 -7585 5940 -27156 1876 -3085 14669 4532 900000 -690 900000 6561 7280 9795 2228 2008 4633 1474 -1355 -1336 -3935 4410 -179 8134 -4751 8083 4216 10067 -5795 10974 7796 4955 -12993 2992 1110 3554 7130 4945 -3730 -6396 6022 -1046 4719 109 10106 -1275 10224 -14930 9312 5286 6540 -2840 3472 -2747 10641 8130 2785 280 3360 -8818 -4849 1285 -13685 5871 -13532 7914 -13651 7094 -7243 14393 10215 9688 -1467 -1606 517 9390 -2175 4782 10392 834 -5477 1949 781 -6037 -553 -16074 19431 -11015 8047 -16346 5468 -10312 13050 -12294 -3228 -2413 2659 3496 -9977 9916 1884 12219 SS 20200301T122807.1Z 7365.519526 467 1 50.13 2 84.75 105.34 113.96 33.95 0.00 1 0.00 1 0 25 5.229e-01 4.531e-02 4.967e-01 4.140e-02 1.172667e+00 2.492239e-02 1.307942e-02 -6.000000e+00 3.027387e-01 225.24 -2.00 3.57 -2.00 322.45 0.00e+00 8.120553e-03 1.071967e-02 3.433727e-03 -6.000000e+00 1.427093e-02 272.93 -2.00 20.00 -2.00 321.99 0.00e+00 9.496 0.017 302.00 328.00 3 1.8969e-01 8.5456e-02 1.1181e-01 -6.0000e+00 7.4983e-01 2.5872e+00 1.0040e-01 6.0804e-02 -6.0000e+00 8.1835e-01 -2.5028e+00 6.9878e-02 3.2406e-02 -6.0000e+00 4.8451e-01 8.2213e-01 3.8791e-02 1.2259e-02 -6.0000e+00 2.0385e-01 8.3377e-06 -1.2580e-03 9.9667e-04 1.9411e-04 -6.0000e+00 1.4845e-02 1.0323e-02 0.0000e+00 12 8 8 10 0 0 45.05 24.35 1.23 0.01032 0.00087 34 7 1 5 0 1474.160 24.35 15.00 21.16 149425 118298 900000 4625 900000 94216 17965 35746 168553 900000 -71867 19185 -9509 900000 -26838 67349 -16412 79911 -10576 50642 -31987 10809 88779 4398 -41409 60598 -11952 900000 -19817 84797 92550 -23997 62162 58100 292945 -77393 -19263 -65199 73340 -34159 105152 30567 -29396 23676 -4093 82151 64915 88313 46920 123690 8468 55976 46740 42647 20667 76861 16278 -9895 12565 -23897 -66512 33529 -35251 16375 31084 36990 40447 175548 28787 2895 62127 38235 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