File name: Pandora104s1_Downsview_20200701_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T054356.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v9d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20200701_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200701T102459.8Z 7487.434026 107 1 49.62 2 83.81 63.79 127.57 285.78 0.00 1 0.00 1 0 17 5.811e-01 3.075e-02 4.487e-01 2.360e-02 8.913726e-01 1.413417e-02 9.772022e-03 -6.000000e+00 3.488548e-01 232.98 -2.00 3.57 -2.00 322.41 0.00e+00 -1.957292e-05 8.763526e-03 6.943698e-03 -6.000000e+00 1.779829e-02 285.60 -2.00 20.00 -2.00 321.93 0.00e+00 8.322 0.011 302.00 328.00 3 1.2729e+00 6.0265e-02 1.0332e-01 -6.0000e+00 8.8176e-01 1.2195e+00 7.5934e-02 6.9779e-02 -6.0000e+00 9.5628e-01 -1.5784e+00 5.6111e-02 2.9079e-02 -6.0000e+00 5.6129e-01 6.0305e-01 2.6621e-02 7.2299e-03 -6.0000e+00 2.3601e-01 1.8017e-05 6.1987e-04 6.6777e-04 1.3008e-04 -6.0000e+00 1.6828e-02 -1.2865e-04 0.0000e+00 12 9 8 11 8 0 24.67 26.00 0.93 -0.00013 0.00453 45 9 1 5 0 1102.600 26.00 15.00 23.07 -41699 -66630 -44620 160020 -12393 900000 -79600 212191 900000 900000 900000 -31119 -59480 48471 -29140 119988 -12643 47227 91074 -40005 18260 -68187 -46444 -31090 15859 -65521 140588 71790 900000 -9571 900000 114955 312105 -70865 228554 -55497 900000 -77708 -27850 -65 72231 44256 43440 -15737 61572 39654 25331 61407 15084 106587 26999 900000 66864 170536 12729 25036 19955 89572 34319 13464 -3191 45077 14643 13328 26771 12659 57626 39072 67183 14039 50782 17294 26113 5321 40817 -19092 26843 -33108 -5651 -19194 6451 -5261 -1324 4794 8391 -6303 -3310 8867 863 4118 4522 -145 -2191 13300 -1973 1493 -146 3553 -1369 -455 -4462 -2240 -1662 619 -9407 -7105 -4892 -4543 758 -47 -304 -1087 281 -1127 2301 -1859 56 -3657 3099 -417 1157 1895 3300 1580 1448 2427 -1032 1045 355 1643 534 702 -1984 1519 43 55 -1052 1592 -756 -271 -1090 541 -708 -1184 -2438 -1250 3677 -285 900000 -2231 4876 900000 900000 900000 -715 -2090 1114 -1064 2757 -453 1085 2093 -1892 462 -3770 -2117 -1289 424 -3788 3231 1650 900000 -299 900000 2642 7172 -5970 5252 -3655 900000 -8118 -2113 -4 2487 2060 2041 -1279 2311 1838 1359 2407 973 3037 1861 900000 3696 3919 1314 2360 1984 4361 2701 1252 -357 3499 1718 1764 3245 1717 5193 4461 6650 2600 7039 3339 4435 1016 4990 -3757 3322 -7768 -1187 -5499 1679 -1743 -461 1665 2995 -2725 -1452 3497 361 1599 1656 -54 -831 4756 -954 821 -94 2532 -1111 -364 -3458 -1517 -1043 391 -7088 -5488 -3950 -3959 716 -51 -375 -1439 377 -1510 2895 -2393 73 -5209 4366 -622 1651 2551 4254 2038 1825 2979 -1286 1398 558 2930 1069 1511 -4691 3754 116 155 -3043 4534 -2186 -745 -2825 1286 -1665 SS 20200701T103516.8Z 7487.441167 110 1 49.62 2 82.14 65.47 129.28 287.86 0.00 1 0.00 1 0 25 6.098e-01 1.476e-02 2.682e-01 6.660e-03 8.108353e-01 3.920220e-03 1.086346e-02 -6.000000e+00 3.661431e-01 232.98 -2.00 3.57 -2.00 322.14 0.00e+00 1.438206e-02 2.490018e-03 1.032592e-02 -6.000000e+00 1.753876e-02 285.60 -2.00 20.00 -2.00 321.64 0.00e+00 6.813 0.006 302.00 328.00 3 1.0902e+00 1.6280e-02 9.1553e-02 -6.0000e+00 9.2183e-01 4.8381e-01 2.3869e-02 6.8338e-02 -6.0000e+00 9.9882e-01 -6.4343e-01 2.3344e-02 3.8679e-02 -6.0000e+00 5.9085e-01 2.5212e-01 1.0339e-02 1.3845e-02 -6.0000e+00 2.4711e-01 1.0036e-04 -3.2111e-04 1.8703e-04 3.2220e-04 -6.0000e+00 1.7059e-02 -1.3856e-04 0.0000e+00 12 8 8 10 0 0 19.04 26.11 0.43 -0.00014 -0.00255 130 27 1 5 0 381.610 26.11 15.00 23.08 -179823 900000 -215579 -150750 -218154 900000 -255690 -148433 -251435 900000 -176591 900000 -176976 196679 -67401 900000 -77319 -25609 -30730 -82850 -81373 -36869 -64368 -45740 54215 -77881 -8770 -107364 25542 -85257 706 -36803 -1987 -46516 20079 -32714 70234 20547 1702 892 13095 19697 12774 51252 14527 29763 3046 45875 10915 35239 4251 37080 19199 24326 11830 32776 2961 3901 13843 15870 13307 12937 15304 16111 18567 7780 14354 6145 12142 5976 8638 2895 10526 3964 7212 -4706 1489 -4032 -833 -931 510 1260 -1310 -1956 -99 892 138 3979 -1779 1814 -2045 1352 -2530 -592 -2737 -1178 -2227 812 -1245 -2056 -2221 -2245 -594 -1775 -2944 -2875 -798 -1565 216 326 1497 -470 471 -902 -450 -927 680 -252 1185 516 978 1061 1269 1329 850 261 -479 779 -289 162 -44 -122 -116 293 -208 249 -76 479 114 -208 68 -245 -1036 -1697 900000 -3433 -1156 -2960 900000 -4977 -1051 -5191 900000 -1875 900000 -3236 1276 -716 900000 -1231 -299 -399 -1710 -1632 -502 -1063 -712 352 -1562 -97 -2913 215 -2313 11 -955 -46 -1591 365 -1019 866 493 59 35 501 754 505 1563 660 1217 155 1786 586 1783 301 2122 1427 1851 1054 2436 299 382 1192 1348 1232 1366 1814 2157 2563 1179 2074 1019 2156 1290 1941 705 2291 856 1366 -911 264 -809 -190 -258 163 458 -534 -848 -45 424 69 1967 -921 871 -960 586 -1125 -279 -1535 -771 -1711 696 -1189 -1970 -1979 -1780 -428 -1323 -2398 -2454 -713 -1522 232 401 2032 -692 694 -1318 -630 -1271 941 -370 1816 818 1502 1548 1781 1820 1134 342 -614 1065 -464 297 -89 -265 -269 727 -556 636 -197 1255 299 -571 174 -585 -2431 SS 20200701T104618.7Z 7487.448827 113 1 49.31 2 80.31 67.26 131.10 290.18 0.00 1 0.00 1 0 17 5.332e-01 7.710e-03 1.674e-01 2.717e-03 7.185971e-01 1.531104e-03 8.866822e-03 -6.000000e+00 3.169539e-01 232.98 -2.00 3.57 -2.00 321.67 0.00e+00 6.864518e-03 8.737888e-04 6.895852e-03 -6.000000e+00 1.399890e-02 285.61 -2.00 20.00 -2.00 321.13 0.00e+00 5.668 0.003 302.00 328.00 3 9.2763e-01 5.8271e-03 7.4850e-02 -6.0000e+00 7.9685e-01 1.2628e-01 8.5849e-03 5.6554e-02 -6.0000e+00 8.6185e-01 -1.6946e-01 8.7831e-03 3.1200e-02 -6.0000e+00 5.1188e-01 5.9166e-02 3.9747e-03 9.6607e-03 -6.0000e+00 2.1341e-01 3.9597e-04 -9.3533e-05 7.6599e-05 1.9170e-04 -6.0000e+00 1.4809e-02 -5.7646e-04 0.0000e+00 11 8 0 10 0 0 2.69 26.11 0.35 -0.00058 -0.00128 291 60 1 5 0 169.430 26.11 15.00 23.10 -154485 -146838 -122628 -168375 -86971 -229019 -158911 -210766 -183479 -186524 -168766 -160244 -113250 -85166 -42308 -36788 -53312 -21011 -56017 7846 -34017 -7863 -26020 -13142 -30199 -29629 -57831 -44125 -50325 -37272 -30265 -6386 -10381 -8914 -16058 -18831 -4326 2881 -1954 -1110 9288 2020 12976 2151 4711 -838 8239 5665 8057 608 4459 3730 8953 4624 5471 1723 2371 985 -1867 3058 4664 4226 5503 7828 4040 2671 4055 3625 5528 3253 1099 1447 -468 706 -718 -918 -1720 -2386 -1547 -1055 -936 -1342 -1878 -951 40 -51 746 306 543 554 848 -890 -1524 -949 -815 -563 -340 -123 -104 -969 -562 -1200 -427 358 -1069 -1754 -836 -358 654 486 674 292 103 -45 -442 204 635 639 357 68 273 569 885 317 65 92 -812 377 82 -566 -394 -813 -316 -64 354 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