File name: Pandora104s1_Downsview_20200721_L2Fit_fout2c20d20191115p1-8.txt File generation date: 20241127T054652.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c20p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 104 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora104_OF_v10d20171009.txt Instrument calibration file used: Pandora104s1_CF_v20d20191115.txt Level 1 file used: Pandora104s1_Downsview_20200721_L1_smca1c20d20191115p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20200721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Based session 15 to update SO2 in VP 20191115" First and last pixel inside fitting window: 209 351 Nominal wavelengths inside fitting window [nm]: 305.1185 305.2591 305.3997 305.5402 305.6807 305.8212 305.9617 306.1022 306.2427 306.3832 306.5237 306.6641 306.8045 306.9450 307.0854 307.2258 307.3662 307.5066 307.6469 307.7873 307.9276 308.0680 308.2083 308.3486 308.4889 308.6292 308.7695 308.9098 309.0500 309.1903 309.3305 309.4707 309.6109 309.7511 309.8913 310.0315 310.1717 310.3118 310.4520 310.5921 310.7322 310.8724 311.0125 311.1526 311.2926 311.4327 311.5728 311.7128 311.8528 311.9928 312.1329 312.2729 312.4128 312.5528 312.6928 312.8327 312.9727 313.1126 313.2525 313.3924 313.5323 313.6722 313.8121 313.9520 314.0918 314.2316 314.3715 314.5113 314.6511 314.7909 314.9307 315.0704 315.2102 315.3500 315.4897 315.6294 315.7691 315.9088 316.0485 316.1882 316.3279 316.4675 316.6072 316.7468 316.8864 317.0260 317.1656 317.3052 317.4448 317.5844 317.7239 317.8635 318.0030 318.1425 318.2820 318.4215 318.5610 318.7005 318.8399 318.9794 319.1188 319.2583 319.3977 319.5371 319.6765 319.8159 319.9552 320.0946 320.2339 320.3733 320.5126 320.6519 320.7912 320.9305 321.0698 321.2090 321.3483 321.4875 321.6268 321.7660 321.9052 322.0444 322.1836 322.3227 322.4619 322.6011 322.7402 322.8793 323.0184 323.1575 323.2966 323.4357 323.5748 323.7138 323.8529 323.9919 324.1309 324.2699 324.4089 324.5479 324.6869 324.8259 324.9648 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200721T103117.8Z 7507.438400 50 1 49.51 2 85.12 66.35 91.88 58.59 0.00 1 0.00 1 0 25 6.591e-01 6.799e-02 4.862e-01 5.460e-02 9.446849e-01 3.240535e-02 1.035830e-02 -6.000000e+00 3.946264e-01 232.81 -2.00 3.57 -2.00 321.97 0.00e+00 -1.645207e-02 1.298005e-02 1.353510e-02 -6.000000e+00 1.996135e-02 286.97 -2.00 20.00 -2.00 321.36 0.00e+00 9.980 0.019 302.00 328.00 3 4.4368e-01 1.1196e-01 1.4354e-01 -6.0000e+00 9.9076e-01 2.0811e+00 1.3040e-01 1.3099e-01 -6.0000e+00 1.0730e+00 -2.1661e+00 7.0712e-02 3.0039e-02 -6.0000e+00 6.3637e-01 7.5475e-01 3.8763e-02 2.1462e-02 -6.0000e+00 2.6787e-01 6.4537e-06 1.5112e-03 1.4887e-03 1.1891e-04 -6.0000e+00 1.9459e-02 -2.9779e-03 0.0000e+00 12 8 8 10 0 0 70.49 25.39 1.61 -0.00298 0.00838 25 5 1 5 0 1979.930 25.39 15.00 22.33 13223 900000 61740 900000 -7259 -1761 -66252 69105 900000 93617 -26164 120842 66551 900000 60553 340313 24436 226503 -52514 -12161 900000 900000 8515 9189 900000 39233 900000 900000 63894 -62183 47934 64651 -7202 111124 184409 -21749 121139 206933 900000 36469 110513 210379 95389 21718 78912 -27833 -22102 -2986 -61247 1888 42822 -3881 5300 17885 -4893 170253 64839 58969 118408 132596 30017 41911 136346 15680 -15687 -2697 -8316 88120 34384 26434 15123 13394 11607 -31579 100411 -4417 12521 2993 6827 24083 85743 25656 60387 12433 10983 19284 -5686 12984 -23057 -21068 -30602 2085 -35488 -12471 -8670 14428 6707 14827 9506 6030 -9503 -1766 19602 -6625 -5113 8496 -31 -9896 10559 1505 6139 -7961 1361 -6814 1938 -3762 -4306 361 3644 9855 1446 5321 1669 5360 -830 4883 378 9731 -2559 -5870 -1127 787 -3204 2986 -1468 56 -6 2551 -1745 6 2153 -999 -1270 1874 900000 4374 900000 -675 -148 -11442 3672 900000 4975 -3360 6422 3831 900000 4290 18084 2489 12036 -10697 -1562 900000 900000 864 1021 900000 3222 900000 900000 3395 -9613 2779 3436 -835 5905 9800 -2417 6437 10996 900000 3876 5873 11180 5530 2413 4575 -4437 -3203 -361 -13610 237 3931 -619 819 2592 -922 9047 6891 6267 6292 7046 3509 4677 7245 2750 -3835 -559 -1856 7961 6030 5619 3777 3416 2837 -10740 8004 -892 2063 573 1451 5119 11391 7089 12836 4493 4260 7173 -2810 5313 -13110 -11084 -16587 787 -19613 -6031 -4699 7284 4206 9770 7122 4614 -7827 -1192 9896 -4471 -3668 5553 -24 -8992 8922 1607 7079 -11337 1808 -9704 2451 -4938 -5835 489 5035 12988 1998 6673 2103 6380 -1027 5579 444 11479 -4025 -11043 -2258 1674 -7644 7268 -4034 158 -16 7200 -5081 15 5286 -2346 -2929 SS 20200721T104311.9Z 7507.446665 53 1 49.73 2 83.14 68.32 90.12 60.59 0.00 1 0.00 1 0 17 5.343e-01 2.178e-02 3.603e-01 1.129e-02 8.313592e-01 6.679574e-03 9.754395e-03 -6.000000e+00 3.225877e-01 232.81 -2.00 3.57 -2.00 322.20 0.00e+00 4.826450e-03 4.186335e-03 7.888222e-03 -6.000000e+00 1.503726e-02 286.97 -2.00 20.00 -2.00 321.68 0.00e+00 7.650 0.009 302.00 328.00 3 1.0215e+00 2.7954e-02 9.6985e-02 -6.0000e+00 8.1036e-01 8.3602e-01 3.8584e-02 6.9878e-02 -6.0000e+00 8.7721e-01 -1.1130e+00 3.2888e-02 3.3144e-02 -6.0000e+00 5.1780e-01 4.4147e-01 1.4680e-02 8.0069e-03 -6.0000e+00 2.1564e-01 4.7323e-05 -8.5922e-04 3.1874e-04 1.8871e-04 -6.0000e+00 1.5385e-02 -2.6664e-03 0.0000e+00 12 8 8 10 0 0 97.17 25.39 0.54 -0.00267 -0.00912 82 17 1 5 0 606.400 25.39 15.00 22.35 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-478 1325 1058 -1765 1096 -1642 1475 629 2130 394 2441 -470 2322 1000 2072 -843 2478 1075 2353 1490 3096 2851 2955 2446 1309 2143 1115 3026 770 2408 927 4460 2625 3214 2379 2479 1476 4374 1803 4270 2947 1958 335 1746 -206 585 -1234 -495 2572 -1194 1322 -1032 984 -526 2549 -263 1564 1415 520 -1915 -253 -2927 442 -1700 -1352 -1101 -2786 -990 -3564 -2322 -2914 -1254 -4126 -191 -4264 1022 -2512 821 -2320 815 -1821 524 -939 -727 -368 -411 894 1364 1742 -5 4453 1761 3969 1939 1945 -1744 3023 -722 1317 428 687 -1385 860 -283 1854 -197 906 68 -684 257 -2000 -3492 SS 20200721T105316.9Z 7507.453667 56 1 25.72 2 81.44 69.98 88.59 62.26 0.00 1 0.00 1 0 33 4.944e-01 1.173e-02 3.382e-01 7.539e-03 7.368817e-01 4.353797e-03 8.546542e-03 -6.000000e+00 2.953208e-01 232.81 -2.00 3.57 -2.00 321.77 0.00e+00 -2.619703e-04 2.555251e-03 6.628995e-03 -6.000000e+00 1.443266e-02 286.97 -2.00 20.00 -2.00 321.20 0.00e+00 6.329 0.005 302.00 328.00 3 1.8976e+00 1.6876e-02 8.2153e-02 -6.0000e+00 7.4057e-01 1.9857e-01 2.4682e-02 6.2798e-02 -6.0000e+00 8.0154e-01 -2.6043e-01 2.4791e-02 2.7423e-02 -6.0000e+00 4.7624e-01 9.7562e-02 1.1224e-02 6.4249e-03 -6.0000e+00 2.0297e-01 8.1088e-05 -1.1531e-07 2.0480e-04 1.1053e-04 -6.0000e+00 1.3859e-02 -2.7554e-03 0.0000e+00 12 9 9 12 1 1 95.67 25.39 0.52 -0.00276 -0.00276 31 13 1 5 0 798.360 25.39 14.99 22.36 900000 900000 900000 -104748 900000 -56405 -112740 -250872 -204985 -160514 110751 19549 -178829 -104172 -29405 38316 -80823 -24506 6250 900000 -29142 900000 -62799 205383 -59873 -29586 -67334 -75278 10553 -62783 24518 -78292 56208 90990 -15760 -17083 -15253 -14352 79626 5254 27035 22750 28806 3777 12455 7000 7347 -13637 -5728 -7548 -1140 -73 3447 10568 12479 8342 3522 6797 -4737 12230 6487 18793 6781 8564 6348 -2741 3926 1209 8537 5152 1515 3726 1380 -2984 3363 -1162 -3279 -4540 556 -1100 -2599 -1378 1971 -2027 2740 1244 980 247 126 86 -1454 -2037 -4334 -1608 284 759 -310 972 -719 -784 -1459 -353 920 -244 -1854 -2172 -1941 -523 379 559 345 -524 -420 -318 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